Material Safety Data Sheet Risalah Data Keselamatan Kimia

Transcription

1 Material Safety Data Sheet Risalah Data Keselamatan Kimia 1. Chemical product and company identification Product name Supplier/Manufacturer Telephone no. Fax no. Use of the substance/mixture Sika Kimia Sdn. Bhd. Lot 689 Nilai Industrial Estate Nilai MY- Neeri Sembilan DK Malaysia Chemical product for construction and industry 1. Penenalpastian produk kimia dan syarikat Nama Produk Pembekal/ Penilan No. Telefon No. Faks Penunaan bahan/persediaan 2. Sika Kimia Sdn. Bhd. Lot 689 Nilai Industrial Estate Nilai MY- Neeri Sembilan DK Malaysia Composition/information on inredients Chemical family/ Characteristics N,N-dibenzyliden polyoxypropylene diamine (polymer) Produk kimia untuk pembinaan dan industri Filled reactive PUR-polymer Occupational exposure limit(s), if available, are listed in section 9. * Toxicoloical information, if available, is listed in section <10 No. No. 2. Komposisi / maklumat bahan Keluara bahan kimia/ Ciri-ciri N,N-dibenzyliden polyoxypropylene diamine (polymer) Had Pendedahan Pekerjaan, jika tersedia, disenaraikan dalam seksyen 9. * Jika tersedia, maklumat toksikoloi disenaraikan dalam seksyen Physical and chemical properties General information Appearance Color Odor Flash point Solubility Filled reactive PUR-polymer Various Characteristic. Important health, safety and environmental information Closed cup >101 C (>213.8 F) 1 - <10 No. No. Insoluble in the followin materials cold water. Date of issue /10 Tarikh keluaran

2 3. 3. Physical and chemical properties Sifat-sifat fizikal dan kimia Maklumat am Rupa Warna Pelbaai Bau Ciri-ciri. Maklumat-maklumat kesihatan, keselamatan dan persekitaran pentin Takat kilat Cawan tertutup >101 C (>213.8 F) Kelarutan Tidak terlarutkan dalam bahan berikut air sejuk. 4. Hazards identification The product is not classified as danerous accordin to Directive 1999/45/EC and its amendments. See Section 11 for more detailed information on health effects and symptoms. 4. Penenalpastian bahaya Produk ini tidak dikelaskan sebaai berbahaya menurut Arahan 1999/45/EC dan pindaannya. Lihat Seksyen 11 untuk maklumat lebih lanjut tentan kesan-kesan dan ejala-ejala kesihatan. 5. First aid measures First aid measures Inhalation Inestion Skin contact Eye contact Protection of first-aiders Remove victim to fresh air and keep at rest in a position comfortable for breathin. Get medical attention if symptoms occur. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathin. If material has been swallowed and the exposed person is conscious, ive small quantities of water to drink. Do not induce vomitin unless directed to do so by medical personnel. Get medical attention if symptoms occur. Flush contaminated skin with plenty of water. Remove contaminated clothin and shoes. Get medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally liftin the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. No action shall be taken involvin any personal risk or without suitable trainin. Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if lare quantities have been inested or inhaled. See Section 11 for more detailed information on health effects and symptoms. 5. Lankah-lankah pertolonan cemas Lankah-lankah pertolonan cemas Penyedutan Peninesan Sentuhan kulit Sentuhan mata Perlindunan untuk pemberi pertolonan cemas Nota kepada doktor Pindahkan mansa ke tempat udara sear dan kekalkan rehat dalam kedudukan yan selesa untuk bernafas. Dapatkan bantuan perubatan jika ejala-ejala berlaku. Basuh mulut denan air. Pindahkan mansa ke tempat udara sear dan kekalkan rehat dalam kedudukan yan selesa untuk bernafas. Jika bahan telah ditelan dan oran yan menalami dedahan sedar, berikan sedikit air untuk minum. Janan paksa muntahan kecuali diarahkan berbuat demikian oleh kakitanan perubatan. Dapatkan bantuan perubatan jika ejala-ejala berlaku. Curahkan pada kulit tercemar denan air yan banyak. Tanalkan pakaian dan kasut yan tercemar. Dapatkan bantuan perubatan jika ejala-ejala berlaku. Seera jirus mata denan air yan banyak, sekali-sekala kedipkan mata. Periksa jika memakai kanta mata dan keluarkan jika ada. Dapatkan bantuan perubatan jika kerensaan berlaku. Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Rawat menikut ejala. Hubuni pakar rawatan keracunan seera jika tertelan atau tersedut dalam kuantiti yan besar. Lihat Seksyen 11 untuk maklumat lebih lanjut tentan kesan-kesan dan ejala-ejala kesihatan. Date of issue /10 Tarikh keluaran

3 6. Fire-fihtin measures Flash point Extinuishin media Suitable Not suitable Special exposure hazards Hazardous combustion products Special protective equipment for fire-fihters Closed cup >101 C (>213.8 F) Use an extinuishin aent suitable for the surroundin fire. None known. In a fire or if heated, a pressure increase will occur and the container may burst. Promptly isolate the scene by removin all persons from the vicinity of the incident if there is a fire. No action shall be taken involvin any personal risk or without suitable trainin. Decomposition products may include the followin materials carbon dioxide carbon monoxide haloenated compounds metal oxide/oxides Fire-fihters should wear appropriate protective equipment and self-contained breathin apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothin for fire-fihters (includin helmets, protective boots and loves) conformin to European standard EN 469 will provide a basic level of protection for chemical incidents. 6. Lankah-lankah pemadaman kebakaran Takat kilat Media pemadam kebakaran Sesuai Tidak sesuai Bahaya pendedahan khas Produk pembakaran berbahaya Alat perlindunan khas untuk ahli bomba 7. Accidental release measures Personal precautions Environmental precautions Lare spill Small spill Cawan tertutup >101 C (>213.8 F) Guna aen pemadaman sesuai untuk linkunan api. Tiada yan diketahui. Ketika kebakaran atau jika dipanaskan, peninkatan tekanan akan berlaku dan bekas boleh pecah. Kosonkan kawasan serta-merta denan meneluarkan semua oran daripada kawasan sekelilin jika kebakaran berlaku. Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Produk penuraian munkin termasuk bahan berikut karbon dioksida karbon monoksida sebatian berhaloen oksida loam Ahli bomba perlulah memakai peralatan perlindunan bersesuaian dan peralatan pernafasan serba lenkap denan penutup muka penuh dalam operasi mod tekanan positif. Pakaian ahli bomba (termasuk topi keledar, but dan sarun tanan pelindun) yan mematuhi Piawai Eropah EN 469 akan memberikan tahap perlindunan asas bai kejadian nahas kimia. No action shall be taken involvin any personal risk or without suitable trainin. Evacuate surroundin areas. Keep unnecessary and unprotected personnel from enterin. Do not touch or walk throuh spilled material. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillaes into an effluent treatment plant or proceed as follows. Contain and collect spillae with noncombustible, absorbent material e.. sand, earth, vermiculite or diatomaceous earth and place in container for disposal accordin to local reulations. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Note see section 9 for personal protective equipment and section 13 for waste disposal. Date of issue /10 Tarikh keluaran

4 7. Accidental release measures 7. Lankah-lankah penawalan pelepasan tidak senaja Lankah berjaa-jaa diri Perinatan alam sekitar Tumpahan besar Tumpahan kecil Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Kosonkan kawasan persekitaran. Halan kakitanan tidak berkaitan dan tidak dilinduni daripada masuk. Janan sentuh atah jalan melalui bahan tertumpah. Pakai kelenkapan perlindunan peribadi bersesuaian (Lihat Seksyen 8). Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh denan tanah, jalan air, lonkan dan pembentun. Beritahu pihak berkuasa yan berkaitan jika produk menyebabkan pencemaran persekitaran (pembentun, aliran air, tanah atau udara). Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Ceah kemasukan ke dalam pembentun, aliran air, basemen atau ruan terbatas. Siram tumpahan ke dalam loji perawatan efluen atau teruskan seperti berikut. Bendun dan kumpul tumpahan denan bahan serap tidak mampu bakar seperti pasir, tanah, vermikulit dan tanah diatom, dan letakkan dalam bekas untuk pembuanan menikut peraturan tempatan. Buan melalui kontraktor pelupusan sisa yan berlesen. Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Cairkan denan air dan seka bersih jika terlarut air. Sebaai alternatif, atau jika tidak terlarut air, serap denan bahan kerin yan lenai dan isikan dalam bekas pelupusan bahan buanan yan wajar. Buan melalui kontraktor pelupusan sisa yan berlesen. Nota Lihat seksyen 9 untuk peralatan perlindunan peribadi dan seksyen 13 untuk pelupusan sisa. 8. Exposure controls/personal protection Exposure limit values Recommended monitorin procedures Exposure controls Occupational exposure controls Hyiene measures Respiratory protection Hand protection Eye protection Skin protection Environmental exposure controls Not available. If this product contains inredients with exposure limits, personal, workplace atmosphere or bioloical monitorin may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. No special ventilation requirements. Good eneral ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains inredients with exposure limits, use process enclosures, local exhaust ventilation or other enineerin controls to keep worker exposure below any recommended or statutory limits. Wash hands, forearms and face thorouhly after handlin chemical products, before eatin, smokin and usin the lavatory and at the end of the workin period. Appropriate techniques should be used to remove potentially contaminated clothin. Wash contaminated clothin before reusin. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, air-purifyin or air-fed respirator complyin with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe workin limits of the selected respirator. Chemical-resistant, impervious loves complyin with an approved standard should be worn at all times when handlin chemical products if a risk assessment indicates this is necessary. Safety eyewear complyin with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task bein performed and the risks involved and should be approved by a specialist before handlin this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection leislation. In some cases, fume scrubbers, filters or enineerin modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 8. Kawalan pendedahan dan perlindunan diri Nilai-nilai had pendedahan Tiada. Date of issue /10 Tarikh keluaran

5 8. Kawalan pendedahan dan perlindunan diri Lankah pemantauan yan disyorkan Kawalan-kawalan pendedahan Kawalan pendedahan pekerjaan Lankah-lankah kebersihan Jika produk ini menanduni ramuan denan had pendedahan, pemantauan peribadi, suasana tempat kerja atau bioloi munkin perlu untuk menentukan keberkesanan penudaraan (untuk peredaran udara) atau lain-lain lankah kawalan dan/atau keperluan menunakan peralatan perlindunan pernafasan. Tiada ventilasi khas diperlukan. Penalihudaraan am yan baik hendaklah mencukupi untuk menawal bahan cemar bawaan udara yan terdedah kepada pekerja. Jika produk ini menanduni bahan/ramuan denan had pendedahan, una proses tertutup, ventilasi ekzos setempat, atau kawalan kejuruteraan lain untuk memastikan pekerja di bawah sebaran had atau kanun yan disyorkan. Basun kedua tanan, lenan dan muka sehina bersih setelah menendali produk kimia, sebelum makan, merokok dan menunakan tandas dan pada akhir waktu kerja. Teknik yan sesuai harus diunakan apabila menanalkan pakaian yan munkin tercemar. Basuh pakaian tercemar sebelum memakai semula. Pastikan tempat mencuci mata dan pancuran air keselamatan berdekatan denan lokasi tempat kerja. Perlindunan respiratori Perlindunan tanan Guna alat penulen udara atau alat pernafasan bekal udara yan muat denan baik yan mendapat kelulusan piawai jika risiko penilaian menunjukkan ianya perlu. Pemilihan alat pernafasan mesti berdasarkan tahap pendedahan diketahui atau dijanka, bahaya produk dan had pekerjaan selamat alat pernafasan yan dipilih itu. Sarun tanan kedap penentan bahan kimia, yan mematuhi piawaian yan diluluskan hendaklah dipakai pada setiap masa apabila menendalikan produk kimia jika penilaian risiko menunjukkan ini adalah perlu. Perlindunan mata Perlindunan kulit Kawalan pendedahan alam sekitar Kacamata keselamatan yan mematuhi kelulusan piawai perlu diunakan apabila risiko penilaian menunjukkan ianya perlu untuk menelakkan pendedahan kepada percikan cecair, kabus atau debu. Peralatan perlindunan peribadi untuk badan perlu dipilih berdasarkan tuas yan dilakukan dan melibatkan risiko dan perlulah diluluskan oleh pakar sebelum menendali produk ini. Peneluaran daripada penudaraan atau peralatan proses kerja hendaklah diperiksa untuk memastikan ianya mematuhi keperluan perundanan perlindunan alam sekitar. Bai sesetenah kes, penyental wasap, penuras atau penubahsuaian kejuruteraan terhadap peralatan proses adalah perlu bai menurankan peneluaran ke tahap yan dibenarkan. 9. Handlin and storae Handlin Storae Packain materials Recommended use Put on appropriate personal protective equipment (see Section 8). Eatin, drinkin and smokin should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eatin, drinkin and smokin. Remove contaminated clothin and protective equipment before enterin eatin areas. Store in accordance with local reulations. Store in oriinal container protected from direct sunliht in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tihtly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upriht to prevent leakae. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Use oriinal container. 9. Penendalian dan penyimpanan Penendalian Pakai kelenkapan perlindunan peribadi bersesuaian (Lihat Seksyen 8). Makan, minum dan menhisap rokok harus dilaran dalam kawasan di mana bahan ini dikendalikan, disimpan dan diproses. Para pekerja harus membasuh tanan dan muka sebelum makan, minum dan menhisap rokok. Tanalkan pakaian yan tercemar dan peralatan perlindunan sebelum masuk tempat makan. Date of issue /10 Tarikh keluaran

6 9. Penendalian dan penyimpanan Penyimpanan Bahan pembunkusan Penunaan yan disyorkan Simpan menikut peraturan tempatan. Simpan di dalam bekas asal yan terlindun dari pancaran terus cahaya matahari dalam kawasan kerin, sejuk dan penudaraan yan baik, jauh daripada bahan tidak sesuai (lihat seksyen 10) dan makanan dan minuman. Simpan bekas tertutup rapat dan terkedap sehina sedia untuk diuna. Bekas yan telah dibuka mesti dikedap semula denan teliti dan disimpan meneak untuk menceah kebocoran. Janan simpan dalam bekas tidak berlabel. Gunakan kaedah penurunan yan sesuai untuk menelakkan pencemaran alam sekitar. Guna bekas asal. 10. Stability and reactivity Stability Hazardous decomposition products The product is stable. Under normal conditions of storae and use, hazardous decomposition products should not be produced. 10. Kestabilan dan kereaktifan Kestabilan Produk pereputan berbahaya 11. Taret orans Toxicoloical information Potential acute health effects Acute toxicity Produk ini stabil. Di bawah keadaan penyimpanan dan penunaan normal, produk penuraian berbahaya tidak boleh dihasilkan. Product/inredient name Result Species Dose Exposure xylene Dermal Rabbit >1700 m/k - Rat 2459 m/k - Intraperitoneal Mouse 1548 m/k - Intraperitoneal Oral Mouse 2119 m/k - Oral Rat 4300 m/k - Rat 1700 m/k - Subcutaneous LDLo Intravenous Rabbit 129 m/k - Potential chronic health effects No known sinificant effects or critical hazards. Contains material which may cause damae to the followin orans luns, upper respiratory tract, skin, eye, lens or cornea. 11. Maklumat toksikoloi Kesan Kesihatan Akut Berpotensi Ketoksikan akut Nama produk/bahan Keputusan Spesis Dos Pendedahan xylene Derma Arnab >1700 m/k - Tikus 2459 m/k - Intraperitoneum Tikus 1548 m/k - Intraperitoneum Oral Tikus 2119 m/k - Oral Tikus 4300 m/k - Tikus 1700 m/k - Subkutaneus LDLo Intravena Arnab 129 m/k - Kesan Kesihatan Kronik Berpotensi Tiada kesan yan pentin atau bahaya kritikal yan diketahui. Oran Sasaran Menanduni bahan yan boleh menyebabkan kerosakan kepada oran-oran berikut paru-paru, saluran atas pernafasan, kulit, mata, kanta atau kornea. Date of issue /10 Tarikh keluaran

7 12. Ecoloical information Environmental effects Aquatic ecotoxicity No known sinificant effects or critical hazards. Product/inredient name Test Result Species xylene 8.5 ppm Marine water Crustaceans - Daerblade rass shrimp - Palaemonetes puio - Adult to u/l Fresh water to u/l Fresh water u/l Fresh water to u/l Fresh water to u/l Fresh water to u/l Fresh water 8600 to 9591 u/l Fresh water 8500 u/l Marine water 8200 to u/l Fresh water 3300 to 4093 u/l Fresh water to u/l Fresh water Fish - Blueill - macrochirus Fish - Rainbow mykiss Fish - Fathead minnow - Pimephales promelas - 31 days mm Fish - Blueill - Fish - Blueill - Fish - Blueill - Fish - Blueill - macrochirus Crustaceans - Daerblade rass shrimp - Palaemonetes puio Fish - Rainbow mykiss Fish - Rainbow mykiss Fish - Blueill - Exposure 48 hours 48 hours 12. Maklumat ekoloi Kesan-Kesan Alam Sekitar Keekotoksikan akuatik Tiada kesan yan pentin atau bahaya kritikal yan diketahui. Nama produk/bahan Ujian Keputusan Spesis Pendedahan Date of issue /10 Tarikh keluaran

8 12. Maklumat ekoloi xylene - Akut LC ppm Air laut - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada 9591 u/l Air tawar - Akut LC u/l Air laut - Akut LC kepada u/l Air tawar - Akut LC kepada 4093 u/l Air tawar - Akut LC kepada u/l Air tawar Crustacea - Daerblade rass shrimp - Palaemonetes puio - Adult Ikan - Blueill - macrochirus Ikan - Rainbow mykiss Ikan - Fathead minnow - Pimephales promelas - 31 hari mm Ikan - Blueill - Ikan - Blueill - Ikan - Blueill - Ikan - Blueill - macrochirus Crustacea - Daerblade rass shrimp - Palaemonetes puio Ikan - Rainbow mykiss Ikan - Rainbow mykiss Ikan - Blueill - 48 jam 48 jam 13. Disposal considerations Waste must be disposed of in accordance with federal, state and local environmental control reulations. Methods of disposal The eneration of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal leislation and any reional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Date of issue /10 Tarikh keluaran

9 13. Disposal considerations 13. Maklumat pembuanan Sisa harus dibuankan menikut peraturan persekutuan, neeri dan kawalan alam sekitar tempatan. Kaedah pembuanan Penhasilan sisa perlulah dielakkan atau diminimumkan sekiranya boleh. Bekas atau pelapik koson munkin menanduni sisa-sisa produk. Bahan ini dan bekasnya hendaklah dilupuskan denan cara yan selamat. Pembuanan lebihan dan hasilan yan tidak boleh dikitar semula melalui kontraktor pelupusan sisa yan berlesen. Pelupusan produk ini, larutan dan sebaran produk sampinan perlulah pada setiap masa mematuhi keperluan perlindunan alam sekitar dan perundanan pelupusan sisa dan sebaran keperluan pihak berkuasa serantau tempatan. Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh denan tanah, jalan air, lonkan dan pembentun. 14. Transport information International transport reulations ADR Not reulated. IMDG Not reulated. Marine pollutant IATA Not reulated. No. 14. Maklumat penankutan Peraturan penankutan antarabansa ADR No danerous oods. IMDG Not reulated. Marine pollutant IATA Not reulated. No. 15. Reulatory information EU reulations Risk phrases Product use Other EU reulations Additional warnin phrases This product is not classified accordin to EU leislation. Professional applications. Contains isocyanates. See information supplied by the manufacturer. Safety Data Sheet available for professional user on request. 15. Maklumat penawalan Peraturan-Peraturan EU Unkapan risiko Keunaan Produk Produk ini tidak diklasifikasi menurut perundanan EU. Aplikasi profesional. Peraturan EU Lain Unkapan Amaran Tambahan Menanduni isosianat. Lihat maklumat diberikan oleh penilan. Risalah Data Keselamatan tersedia untuk penuna profesional apabila diminta. Date of issue /10 Tarikh keluaran

10 16. Other information History Date of printin Date of issue Date of previous issue Version Notice to reader No previous validation. 1 Indicates information that has chaned from previously issued version. The information contained in this Safety Data Sheet corresponds to our level of knowlede at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processin. 16. Maklumat lain Sejarah Tarikh cetakan Tarikh keluaran Tarikh Keluaran Terdahulu Versi Notis kepada pembaca Tiada Penesahan Terdahulu. 1 Menunjukkan maklumat yan telah berubah daripada versi isu terdahulu. Informasi yan terkandun di dalam Risalah Data Keselamatan Kimia ini adalah sejajar denan tahap penetahuan kami pada masa ianya diterbitkan. Sebaran jaminan adalah dikecualikan. Syarat - syarat Penjualan Am kami yan terkini tertakluk. Sila rujuk Risalah Data Teknikal kami sebelum sebaran penunaan dan pemprosesan. Date of issue /10 Tarikh keluaran