Triton Systems Flooring Systems MSDS Data Pack

Transcription

1 Triton Systems Flooring Systems MSDS Data Pack Triton Contact Details: Triton Systems Ltd. Units 3 5 Crayford Commercial Centre, Greyhound Way, Crayford, Kent DA1 4HF Tel: Fax: info@tritonsystems.co.uk /16

2 CONTENTS: 1. Triseal 2. TT Vapour Membrane 3. Triton LPA Primer 4. Triton Floor Levelling Compound 5. Trifix 6. Triton Fillet Seal /16

3 IRRITANT Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication date Revision date 26/02/ /06/ PRODUCT NAME: TRISEAL - RESIN (Part 1) 2. HAZARD IDENTIFICATION IRRITANT Irritant Irritating to skin and eyes. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. 3. COMPOSITION Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases Bisphenol A and F epoxy <60% Xi (Irritant) R36/38,43 Resins Alkylglycidylether <15% Xi (Irritant) R36/38,R43,R51/53 4. FIRST AID { CONTACT WITH SKIN: CONTACT WITH EYES: INGESTION: INHALATION: OTHER INFORMATION: Wash with plenty of soap and water. Wash out with water for several minutes and seek medical advice. Seek medical advice in the event of discomfort. Remove to fresh air if fumes cause irritation of nose or throat. May aggravate existing respiratory problems. 5.FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: Dry powder or foam. For small fires use CO Never use water jet. SPECIAL PROTECTIVE EQUIPMENT: For fires in confined spaces, use breathing apparatus. 6.ACCIDENTAL RELEASE MEASURES ² PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: CLEAN-UP PROCEDURES Wear suitable protective clothing appropriate to the amount involved, which may include eye/face protection, PVC or synthetic rubber gloves, protective footwear, overalls. Do not allow to enter public sewers and watercourses. If this cannot be avoided, inform the appropriate authority. Absorb in dry sand or earth or similar absorbent and shovel into a suitable closed container for disposal according to item 13.

4 7.HANDLING AND STORAGE HANDLING PRECAUTIONS STORAGE INFORMATION Observe good hygiene standards and minimise skin contact. Wear suitable protective clothing according to item 8. Avoid open flames and sources of ignition. Keep containers tightly closed in a cool place, out of direct sunlight. Keep stored well ventilated. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Where prolonged or repeated exposure is likely, protective clothing should be worn, including eye protection and PVC or synthetic rubber gloves. Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke whilst handling the product. Do not wear contaminated clothing. Ventilate confined spaces thoroughly. EXPOSURE LIMITS None prescribed in EH40 Slight irritant, not considered hazardous. 9.PHYSICAL AND CHEMICAL PROPERTIES Appearance Red Liquid Oxidising Properties None Odour Faint Vapour Pressure No Data ph N/A Relative density 1.13 (25 C) Boiling Point 200 C Bulk density Not Relevant Melting Point Not Relevant Viscosity No data Flash Point >150C Solubility Insoluble in water Autoignition temperature No data Partition Coefficient No data Explosive properties No data Other data 10.STABILITY/REACTIVITY STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: Stable under normal conditions of use. High temperatures (degrades resin). Strong oxidising agents, strong acids and bases. 11.TOXICOLOGICAL INFORMATION No available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent. 12.ECOLOGICAL INFORMATION MOBILITY: DEGRADABILITY: ACCUMULATION: ECOTOXICITY: Low soil absorption Not easily biodegradable. There is potential for bioaccumlation. Biomagnification is unlikely. Toxic to aquatic organisms.

5 13.DISPOSAL CONSIDERATIONS DISPOSAL OF PRODUCT: DISPOSAL OF PACKAGING: Chemical residues are normally regarded as Special Waste. Dispose of in accordance with local and national regulations (incinerate or landfill). Uncleaned packaging should be treated as for the product. 14. TRANSPORT INFORMATION UN NO PROPER SHIPPING NAME Liquid epoxy resin ADR/RID Class 9 No/letter:11-C IMCO MFAG Table No. EmS No. IATA/IACO Class 9 Environmentally hazardous substance, liquid, n.o.s. PACKING GROUP III LABEL No hazard label 15. REGULATORY INFORMATION CLASSIFICATION Irritant LABEL INFORMATION R36/38: Irritating to eyes and skin. R43: May cause sensitisation by skin contact. S28: After contact with skin, wash immediately with plenty of water. S37/39: Wear suitable gloves and eye/face protection. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S61: Avoid release to the environment. Refer to special instructions/safety data sheets. Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act. The information contained in this safety data sheet does not constitute the user s own assessment of workplace risk as Required by health and safety legislation. 16.OTHER INFORMATION The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

6 CORROSIVE Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication date Revision date 26/02/ /05/ PRODUCT NAME: TRISEAL - HARDENER (Part 2) 2. HAZARD IDENTIFICATION Corrosive Corrosive Causes Burns. Harmful if swallowed. May cause sensitisation by skin contact. 3. COMPOSITION Hazardous ingredient CAS No. Weight % Symbols Risk Phrases Tris-2,4,6(Dimethyl amino methyl) phenol <5.0% Xn R22-36/38 Bis(Dimethyl amino methyl) phenol <1.0% Xn R22-36/38 Alkylated polyamine adduct <90% C (Corrosive) R21/22,34, 42/43 4. FIRST AID CONTACT WITH SKIN: CONTACT WITH EYES: INGESTION: INHALATION: OTHER INFORMATION: Wash with plenty of soap and water. If irritation persists, obtain medical advice. Wash out with water for several minutes and seek medical advice. Give plenty of water if possible, charcoal slurry. Do not induce vomiting. Remove to fresh air. If symptoms persist, seek medical advice. Treat symptomatically. 5.FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: Dry powder, fog or foam. For small fires use CO Do not use high ² pressure water jet. SPECIAL PROTECTIVE EQUIPMENT: Full protective equipment. Toxic and irritant fumes may be produced. 6.ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: CLEAN-UP PROCEDURES: Wear suitable protective clothing appropriate to the amount involved, which may include eye/face protection, PVC or synthetic rubber gloves, protective footwear, overalls. Avoid contact with eyes and skin. Do not allow to enter public sewers and watercourses. If this cannot be avoided, inform the appropriate authority. Absorb in dry sand or earth or similar absorbent and shovel into a suitable closed container for disposal according to item 13.

7 7.HANDLING AND STORAGE HANDLING PRECAUTIONS: STORAGE INFORMATION: Ensure adequate ventilation in work areas. Keep away from sources of ignition no smoking. Avoid contact with eyes and skin. Avoid inhaling vapour, ensure good ventilation. Keep containers tightly closed in a cool place, out of direct sunlight. Keep stored well ventilated. Keep away from food and feeding stuffs. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS 9.PHYSICAL AND CHEMICAL PROPERTIES Wear protective clothing, including eye protection and PVC or synthetic/rubber gloves. Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke whilst handling the product. None prescribed in EH40 Appearance Brown Liquid Oxidising Properties None Odour Amine-Like Vapour Pressure <8 25 C ph >7 (in water) Relative density 1.01 (25 C) Boiling Point Decomposes Bulk density Not Relevant Melting Point Not Relevant Viscosity No data Flash Point >100 C (CC) Solubility Autoignition temperature No data Partition Coefficient No data Explosive properties No data Other data 10.STABILITY/REACTIVITY Partially miscible with water Avoid contact with strong acids and oxidizers. STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: Stable under normal conditions of use. High temperatures, formation of aerosols, static discharges. Strong oxidising agents, acids and bases. 11.TOXICOLOGICAL INFORMATION LD (rat, oral): > 5000mg/kg (by calculation). Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive. 50 Dermal sensitisation (guinea pig): sensitiser 12.ECOLOGICAL INFORMATION MOBILITY: DEGRADABILITY: ACCUMULATION: ECOTOXICITY: Likely to be mobile in soil. Readily biodegradable. There is little potential for bioaccumlation. Biomagnification is unlikely. Harmful to aquatic organisms:

8 13.DISPOSAL CONSIDERATIONS DISPOSAL OF PRODUCT: DISPOSAL OF PACKAGING: Chemical residues are normally regarded as Special Waste. Incinerate in compliance with the Environmental Protection Act 1990 (Process Guidance Note IPR5/1) As for the product. 14. TRANSPORT INFORMATION UN NO PROPER SHIPPING NAME ADR/RID Class 8. Item 53(b) IMCO Class 8. IMDG Code page MFAG Table No. 320 EmS No IATA/IACO Class 8 PACKING GROUP 3 LABEL Corrosive 15. REGULATORY INFORMATION CLASSIFICATION Corrosive LABEL INFORMATION R34: Causes burns. R21/22: Harmful in contact with skin and if swallowed. R42/43: May cause sensitisation by inhalation and skin contact. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S28: After contact with skin, wash immediately with plenty of water and mild soap. Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act. The information contained in this safety data sheet does not constitute the user s own assessment of workplace risk as required by health and safety legislation. 16.OTHER INFORMATION The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

9 Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication Date Revision Date TR 22/06/ /09/ PRODUCT NAME TRITON TT VAPOUR MEMBRANE 2. HAZARD IDENTIFICATION Not regarded as a health or environmental hazard under current legislation. 3. COMPOSITION/INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES GENERAL INFORMATION: INHALATION: INGESTION: SKIN CONTACT: EYE CONTACT: General first aid, rest, warmth and fresh air. Not relevant. Immediately rinse mouth and provide fresh air. DO NOT INDUCE VOMITING! Wash the skin immediately with soap and water. Immediately flush with plenty of water or eyewash solution for up to 10 minutes. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE & EXPLOSION HAZARDS: PROTECTIVE MEASURES IN FIRE: Water spray, dry powder or carbon dioxide. Extinguish with dry sand. No specific fire fighting procedure given. No unusual fire or explosion hazards noted. Wear full protective clothing. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: SPILL CLEAN UP METHODS: Wear protective clothing as described in Section 8 of this safety data sheet. Eliminate all ignition sources. Keep people and animals away. Prevent entry into drains, sewers and watercourses. If spillage enters drains leading to sewerage works inform the local water company. If spillage enters rivers or watercourses inform the Environment Agency. Absorb spillage with non-combustible, absorbent material. Collect in containers and seal securely. Remove containers and flush area with water.

10 7. HANDLING AND STORAGE USAGE PRECAUTIONS: STORAGE PRECAUTIONS: Read and follow manufacturer s recommendations. Keep in original container. Store in closed original container at temperatures between 5 C and 30 C. Protect from freezing and direct sunlight. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION PROTECTIVE EQUIPMENT: RESPIRATORY EQUIPMENT: HAND PROTECTION: EYE PROTECTION: HYGIENE MEASURES: If ventilation is insufficient, suitable respiratory protection must be provided. PVC gloves are recommended. Wear approved safety goggles. Wash hands after contact. 9.PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: COLOUR: ODOUR: SOLUBILITY: Viscous liquid Blue Mild Miscible with water RELATIVE DENSITY: ph-value, CONC. SOLUTION 6-8 VISCOSITY: mpas STABILITY AND REACTIVITY STABILITY: MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: Stable under normal temperature conditions and recommended use. Strong acids. In case of fire, toxic gases (CO, CO2, NOX) may be formed. 11.TOXICOLOGICAL INFORMATION GENERAL INFORMATION: INHALATION: INGESTION: SKIN CONTACT: EYE CONTACT: No specific health warnings noted. Not relevant at normal room temperatures. When heated, irritating vapours may be formed. May cause discomfort if swallowed. Skin irritation is not anticipated when used normally. May cause temporary eye irritation.

11 12.ECOLOGICAL INFORMATION ECOTOXICITY: DEGRADABILITY: No data on possible environmental effects have been found. No data available. 13.DISPOSAL CONSIDERATIONS GENERAL INFORMATION: DISPOSAL METHODS: Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. Dispose of waste and residues in accordance with local authority requirements. 14. TRANSPORT INFORMATION GENERAL: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). 15. REGULATION INFORMATION RISK PHRASES: NC Not Classified APPROVED CODE OF PRACTICE: Classification and Labelling of Substances and Preparations Dangerous for Supply 16.OTHER INFORMATION REVISION DATE 20/04/2010 REV.NO./REPL. SDS GENERATED 1 DATE 20/04/2010 The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

12 Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication date Revision date Not classified TR 09/01/2012 as Hazardous 1. PRODUCT NAME: TRITON LPA / PRIMER 2. HAZARD IDENTIFICATION This product is not hazardous according to EEC criteria. 3. COMPOSITION Styrene/butadiene polymer dispersion in water 4. FIRST AID Never give fluids or induce vomiting if patient is unconscious or is having convulsions. SWALLOWING: CONTACT WITH EYES. INHALATION: SKIN: No adverse effects anticipated by this route of exposure incidental to proper industrial handling. Irrigate immediately with water for at least 5 minutes. No adverse effects anticipated by this route of exposure. Wash off in flowing water or shower. 5. FIRE-FIGHTING MEASURES This product is an aqueous dispersion, unless dried it will not burn. EXTINGUISHING MEDIA: HAZARDOUS COMBUSTION PRODUCTS: PROTECTION OF FIREFIGHTERS: Water fog, Carbon Dioxide, Foam, Dry Chemicals. Upon burning, the dry product generates dense black smoke. Wear positive-pressure self-contained breathing apparatus and protective fire-fighting clothing, (includes fire-fighting helmet, coat, pants, boots and gloves). 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear adequate personal protective equipment. See Section 8, Exposure Controls/Personal Protection. ENVIRONMENTAL PRECAUTIONS: METHODS OF CLEANING UP: Prevent contamination of surface and groundwater. Small spills may be flushed away with large quantities of water. Large spills should be contained and recovered if possible; if not possible divert spill to pond and allow to dry.

13 7. HANDLING AND STORAGE HANDLING PRECAUTIONS: STORAGE INFORMATION: Good general ventilation should be sufficient for most conditions. This product must be protected from freezing and exposure to temperatures exceeding 40 deg C. Store at room temperature. Product may develop bacterial odours upon long-term storage. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: None established. ENGINEERING CONTROL: Good general ventilation should be sufficient for most conditions. PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: SKIN PROTECTION: EYE/FACE PROTECTION: For most conditions, no respiratory protection should be needed however, in misty atmospheres, use an approved mist respirator. No precautions other than clean body-covering clothing should be needed. Use impervious gloves when prolonged or frequently repeated contact could occur. Use safety glasses. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Emulsion Freezing point/range 0 deg. C (water) Colour Milky White Boiling point/range 100 deg C (water) Odour Practically Odourless Water Solubility Miscible in all proportions Solid Content 45% (approx) Flash point Not applicable ph 10.5 Flammability Not applicable Rel. density (water=1) Auto-ignition temp Not applicable 10. STABILITY / REACTIVITY CHEMICAL STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: Stable under normal handling and storage conditions. May coagulate if frozen (0.deg.C) The dry resin is combustible. Addition of chemicals, such as acids or multivalent metal salts, may cause coagulation. 11. TOXICOLOGICAL INFORMATION INGESTION: SKIN CONTACT: Single dose oral toxicity is low. The oral LD50 for rats is >2000 mg/kg. No hazards anticipated from swallowing small amounts incidental to normal industrial handling. The LD50 for skin absorption in rats is >2000 mg/kg. Short single exposure is not likely to cause significant skin irritation. Prolonged or repeated exposure may cause skin irritation. Skin absorption is unlikely due to physical properties. INHALATION: No adverse effects are anticipated from inhalation. EYE CONTACT: May cause slight transient (temporary) eye irritation. Corneal injury is unlikely.

14 12. ECOLOGICAL INFORMATION DEGRADATION: Biodegradation reached in the Closed Bottle Test (OECD Test No. 301 D) after 28 days: <10 % Latex dispersions will colour waters to a milky white. AQUATIC TOXICITY: Acute LC50 for rainbow trout (Onchorynchus mykiss) is >100 mg/l. Acute EC50 for water flea (Daphnia magna) is mg/l. 13. DISPOSAL CONSIDERATIONS Dispose of according to local and national regulations. 14. TRANSPORT INFORMATION Product is not classified for any mode of transportation. 15. REGULATORY INFORMATION EEC Classification and User Label Information This product does not require classification according to the criteria of the Commission of the European Communities. 16. OTHER INFORMATION No other information NOTICE TO CUSTOMER:- ENSURE ALL POTENTIAL USERS OF THIS PRODUCT ARE AWARE OF THIS SDS PRIOR TO USING THE PRODUCT. KEEP SDS IN A SAFE PLACE READILY LOCATABLE IN CASE OF FUTURE REQUIREMENT. READ THIS SDS IN CONJUNCTION WITH THE LABEL AND DIRECTIONS FOR USE ON THE PRODUCT CONTAINER. DESTROY ALL OBSOLETE COPIES RELATING TO THIS PRODUCT THIS SDS RELATES ONLY TO THE PRODUCT SPECIFIED. COPIES OF THIS DOCUMENT ARE AVAILABLE ON REQUEST. THIS SAFETY DATA SHEET IS BASED ON THE BEST OF CURRENT INFORMATION AND ADVICE AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE. NO LIABILITY CAN BE ACCEPTED FOR LOSS, DAMAGE OR INJURY AS CONDITIONS OF USE ARE OUTSIDE OUR CONTROL. THIS IS NOT A TECHNICAL SPECIFICATION. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

15 MSDS Ref: Publication date Revision date IRRITANT 07/12/ /05/ PRODUCT NAME: FLOOR LEVELLING COMPOUND 2. HAZARD IDENTIFICATION Risk of serious damage to eyes Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: CLASSIFICATION ENVIRONMENT HUMAN HEALTH Xi: R41 The product may affect the acidity (ph-factor) in water with risk of harmful effects to aquatic organisms. Prolonged contact with wet cement/mixture may cause burns. When mixes with water or gauging liquid splashes may cause serious eye damage. This material contains a low level of soluble Chromium VI. A reducing agent has been added which will, when mixed, reduce the level the of soluble Chromium (VI) to no more than % (2ppm) of the total dry weight of cement providing the product is stored correctly as indicated in Section 7, and used within six months. Persons with a known sensitivity to Chromium VI would be advised not to use this product. 3. COMPOSITION Key to proportions High %, Med 11-60%, Low 1-10%, Very Low<1% Key to identification: A = Chip Index No. B = EC No. C = Case No. COMPONENT Classification Proportions Exposure Levels Identification R-Phrases (8hr TWA) PORTLAND CEMENT X, R41 MED 10 mg/m² (C) 4 mg/m³ respirable dust CALCIUM ALUMINATES X, R41 MED 10 mg/m² (C) 4 mg/m³ respirable dust A cement / silica sand mixture with extenders and small percentages of additives. The product may contain a low level of respirable crystalline silica. The product contains calcium carbonate. 4. FIRST AID CONTACT WITH EYES: Immediately rinse with water. Continue to rinse for at least 15 minutes and get medical attention. CONTACT WITH SKIN: INGESTION: INHALATION: Remove contaminated clothing. Rinse the skin immediately with lots of water. Get medical attention if any discomfort continues. Rinse mouth thoroughly. Drink plenty of water. Do not induce vomiting. Get medical attention if any discomfort continues. Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Medical practitioners may obtain further information from the National Poisons Information Centre.

16 5.FIRE-FIGHTING MEASURES Product does not represent a fire hazard. All types of extinguisher applicable. Use extinguisher appropriate to the surrounding conditions. 6.ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Avoid inhalation of dust. Avoid contact with skin and eyes. SPILL CLEAN UP METHODS: Avoid dust formation. Preferably remove spillage with a vacuum cleaner. Collect spillage in containers, seal securely and deliver for disposal as hazardous waste. 7.HANDLING AND STORAGE HANDLING PRECAUTIONS Avoid handling which leads to dust formation. Observe good industrial hygiene practices. Do not eat, drink or smoke when using the product. STORAGE INFORMATION Keep separate from food, feedstuffs, fertilisers and other sensitive material. The product must be stored under cover, in unopened bags clear of the ground in cool dry conditions, protected from frost and excessive draught 8.EXPOSURE CONTROLS/PERSONAL PROTECTION EYES: Where risk of splashing occurs, particularly from wet product, wear goggles conforming to BSEN 166 to avoid any possibility of eye contact. HANDS, FACE, BODY: Wear CE approved nitrile gloves and overalls when handling to avoid skin contact. When grouting do not use fingers as grouting tool. RESPIRATORY: Provide adequate ventilation, especially when mixing and wear dust mask. Following the guidelines of EH40 exposure to dust should be adequately controlled and kept below 10 mg/m³ 8 hour TWA total inhalable dust and 4 mg/m³ 8 hour TWA total respirable dust. Such (or greater) dust concentrations should be taken as the substantial concentrations to which Regulation 2 of the C.O.S.H.H Regulation refers. Total inhalable dust the fraction of airborne material which enters the nose and throat. Respirable dust the fraction of airborne material which enters the gas exchange region of the lung. If ventilation is not adequate, wear respiratory protection, conforming to EN 140 with A1 filters. Engineering Controls of operator exposure may replace personal protective equipment if a C.O.S.H.H. Assessment shows a higher standard of protection. Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes wet.

17 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Powder Colour Grey Odour ph-value Conc. Solution: Melting Point 10. STABILITY / REACTIVITY Slight Odour High Alkaline ph Variable, depends Relative density When mixed with on packing effects water Flash Point (ºC) Not relevant >1500 C STABILITY: CONDITIONS TO AVOID: Stable under normal temperature conditions and recommended use. Avoid wet and damp conditions. Avoid strong acids and alkalis. 11.TOXICOLOGICAL INFORMATION SKIN: EYES: INGESTION: INHALATION: Prolonged or repeated contact with the powder or mixtures with water may cause irritation or burns with the possibility of irritant or allergic dermatitis in some individuals. Risk of serious damage to eyes. Wet product is alkaline. Dry product is abrasive. Small quantities ingested unlikely to cause more than temporary discomfort. Dust in high concentrations may irritate the respiratory system. The product may contain a small percentage of respirable crystalline silica. Prolonged exposure to dust may result in long-term irreversible effects. 12.ECOLOGICAL INFORMATION Do not contaminate drains, sewers or waterways with this product. The product may affect the acidity (ph-factor) in water with risk of harmful effects to aquatic organisms. 13.DISPOSAL CONSIDERATIONS Small quantities may be mixed with water, allowed to cure fully and disposed of as low hazard waste. Larger quantities should be disposed of as hazardous waste via a licensed waste operator. 14. TRANSPORT INFORMATION Not regulated.

18 15. REGULATORY INFORMATION IRRITANT RISK PHRASES: R41 Risk of serious damage to eyes. SAFETY PHRASES: S2 Keep out of reach of children S24/25 Avoid contact with eyes/skin S26 After contact with skin, wash with soap and water. S28 In case of contact with eyes rinse immediately with copious amounts of water and seek medical attention. S36/37/38 Wear suitable protective clothing, gloves and eye/face protection. S60 This material and/or its container must be disposed of as hazardous waste. 16. OTHER INFORMATION EH40 Occupational Exposure Limits. Control of Substances Hazardous to Health Regulations. HS(G)97 A Step by Step Guide to C.O.S.H.H. Assessment. Approved Carriage and Supply Lists. The Chemicals (Hazards, Identification, Packaging) Regulations This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not be construed therefore as guaranteeing specific properties. The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long-term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

19 Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication date Revision date TR /04/ /05/2015 IRRITANT 1.PRODUCT NAME: TRIFIX ADHESIVE - RESIN 2. HAZARD IDENTIFICATION Irritant Irritating to skin and eyes. IRRITANT Dangerous to the Environment 3. COMPOSITION Hazardous ingredient CAS No. Weight % Symbols Risk Phrases Bisphenol A and F epoxy , Xi (Irritant) S24,S26,S28,S37/39 Resins, diglycidyl R51/53 4. FIRST AID CONTACT WITH SKIN: CONTACT WITH EYES: INGESTION: INHALATION: OTHER INFORMATION: Wash with plenty of soap and water. Wash out with water for several minutes and seek medical advice. Seek medical advice in the event of discomfort. Remove to fresh air if fumes cause irritation of nose or throat. May aggravate existing respiratory problems. 5.FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL PROTECTIVE EQUIPMENT: Dry powder or foam. For small fires use CO2. Never use water jet. For fires in confined spaces, use breathing apparatus. 6.ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: CLEAN-UP PROCEDURES Wear suitable protective clothing appropriate to the amount involved, which may include eye/face protection, PVC or synthetic rubber gloves, protective footwear, overalls. Do not allow to enter public sewers and watercourses. If this cannot be avoided, inform the appropriate authority. Absorb in dry sand or earth or similar absorbent and shovel into a suitable closed container for disposal according to item 13.

20 7.HANDLING AND STORAGE HANDLING PRECAUTIONS STORAGE INFORMATION Observe good hygiene standards and minimise skin contact. Wear suitable protective clothing according to item 8. Avoid open flames and sources of ignition. Keep containers tightly closed in a cool place, out of direct sunlight. Keep stored well ventilated. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Where prolonged or repeated exposure is likely, protective clothing should be worn, including eye protection and PVC or synthetic rubber gloves. Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke whilst handling the product. Do not wear contaminated clothing. Ventilate confined spaces thoroughly. EXPOSURE LIMITS None prescribed in EH40 Slight irritant, not considered hazardous. 9.PHYSICAL AND CHEMICAL PROPERTIES Appearance Beige, thixotropic Oxidising liquid. Properties None Odour Faint Vapour Pressure 1Pa (20 C) ph 7 (50% suspension in water Relative density 1.7 (25 C) Boiling Point Decomposes Bulk density Not Relevant Melting Point Not Relevant Viscosity No Data Flash Point > 150 C Solubility Insoluble in water Autoignition temperature No data Partition Coefficient No data Explosive properties No data Other data 10.STABILITY/REACTIVITY STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: Stable under normal conditions of use. High temperatures (degrades resin). Strong oxidising agents, strong acids and bases. Excess of hardener (uncontrolled polymerisation reaction). 11.TOXICOLOGICAL INFORMATION No available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent. 12.ECOLOGICAL INFORMATION MOBILITY: DEGRADABILITY: ACCUMULATION: ECOTOXICITY: Low soil absorption. Not easily biodegradable. There is potential for bioaccumulation. Biomagnification is unlikely. Toxic to aquatic organisms.

21 13.DISPOSAL CONSIDERATIONS DISPOSAL OF PRODUCT: DISPOSAL OF PACKAGING: Chemical residues are normally regarded as Special Waste. Dispose of in accordance with local and national regulations (incinerate or landfill). Uncleaned packaging should be treated as for the product. 14. TRANSPORT INFORMATION UN NO. PROPER SHIPPING NAME ADR/RID IMCO IATA/IACO PACKING GROUP LABEL None assigned Liquid Epoxy Resin Not classified as hazardous Not classified as hazardous MFAG Table No. EmS No. Not classified as hazardous None assigned Marine pollutant 15. REGULATORY INFORMATION CLASSIFICATION SAFETY PHRASES Irritant S24: Irritating to eyes and skin. S26: May cause sensitisation by skin contact. S28: After contact with skin, wash immediately with plenty of water. S37/39: Wear suitable gloves and eye/face protection. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act. The information contained in this safety data sheet does not constitute the user s own assessment of workplace risk as required by health and safety legislation. 16.OTHER INFORMATION The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

22 CORROSIVE Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication date Revision date TR /04/ /05/ PRODUCT NAME: TRIFIX ADHESIVE - HARDENER 2. HAZARD IDENTIFICATION Corrosive Causes burns. Harmful if swallowed. May cause sensitisation by skin contact. CORROSIVE 3. COMPOSITION HAZARDOUS INGREDIENT CAS No. EC No. Weight % Symbols Risk Phrases Bisphenol A and F epoxy C (Corrosive) R21/22,34,43 Triphenol phosphate Xi (Irritant) R36/38 Alkylated polyamine adduct 30.6 C (Corrosive) R21/22,34,43 4. FIRST AID CONTACT WITH SKIN: CONTACT WITH EYES: INGESTION: INHALATION: OTHER INFORMATION: Wash with plenty of soap and water. If irritation persists, obtain medical advice. Wash out with water for several minutes and seek medical advice. Give plenty of water if possible, charcoal slurry. Do not induce vomiting. Remove to fresh air. If symptoms persist, seek medical advice. Treat symptomatically. 5.FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL PROTECTIVE EQUIPMENT: Dry powder, fog or foam. For small fires use CO2.. DO NOT use halones. Full protective equipment. Toxic and irritant fumes may be produced. 6.ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: CLEAN-UP PROCEDURES Wear suitable protective clothing appropriate to the amount involved, which may include eye/face protection, PVC or synthetic rubber gloves, protective footwear, overalls. Do not allow to enter public sewers and watercourses. If this cannot be avoided, inform the appropriate authority. Absorb in dry sand or earth or similar absorbent and shovel into a suitable closed container for disposal according to item 13.

23 7.HANDLING AND STORAGE HANDLING PRECAUTIONS STORAGE INFORMATION Ensure adequate ventilation in work areas. Keep away from sources of ignition No smoking. Do not break open the dispenser cartridge. Keep containers tightly closed in a cool place, out of direct sunlight. Keep stored well ventilated. Keep away from food and feeding stuffs. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Wear protective clothing, including eye protection and PVC or synthetic / rubber gloves. Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke whilst handling the product. EXPOSURE LIMITS None prescribed in EH40 9.PHYSICAL AND CHEMICAL PROPERTIES Appearance Red Paste Oxidising Properties None Odour Amine Like Vapour Pressure No data ph > 7 (in water) Relative density 1.2 (25 C) Boiling Point Decomposes Bulk density Not Relevant Melting Point Not Relevant Viscosity No Data Flash Point > 100 C (CC) Solubility Partially miscible with water Autoignition temperature No data Partition Coefficient No data Explosive properties No data Other data 10.STABILITY/REACTIVITY STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: Stable under normal conditions of use. High temperatures, formation of aerosols, static discharges. Strong oxidising agents, strong acids and bases. 11.TOXICOLOGICAL INFORMATION LD50 (rat, oral): > 5000mg/kg (by calculation). Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive Dermal sensitisation (guinea-pig): sensitiser 12.ECOLOGICAL INFORMATION MOBILITY: DEGRADABILITY: ACCUMULATION: ECOTOXICITY: Likely to be mobile in soil. Readily biodegradable. There is little potential for bioaccumulation. Biomagnification is unlikely. Toxic to aquatic organisms.

24 13.DISPOSAL CONSIDERATIONS DISPOSAL OF PRODUCT: DISPOSAL OF PACKAGING: Chemical residues are normally regarded as Special Waste. Incinerate in compliance with the Environmental Protection Act 1990 (Process Guidance Note IPR5/1) As for the product. 14. TRANSPORT INFORMATION UN NO PROPER SHIPPING NAME ADR/RID Class 8. Item 53(b) IMCO Class 8. IMDG Code page MFAG Table No. 320 EmS No IATA/IACO Class 8 PACKING GROUP 3 LABEL Corrosive 15. REGULATORY INFORMATION CLASSIFICATION SAFETY PHRASES Corrosive R34: Causes burns R22: Harmful if swallowed. R43: May cause sensitisation by skin contact. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act. The information contained in this safety data sheet does not constitute the user s own assessment of workplace risk as required by health and safety legislation. 16.OTHER INFORMATION The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.

25 Triton Systems Units 3-5 Crayford Commercial Centre, Greyhound Way Crayford, Kent DA1 4HF Tel: Fax: MSDS Ref: Publication date Revision date IRRITANT TR /09/ /05/ PRODUCT NAME: TRITON FILLET SEAL 2. HAZARD IDENTIFICATION IRRITANT Irritating to the skin. Risk of serious damage to eyes. May cause sensitisation by skin contact. 3. COMPOSITION HAZARDOUS INGREDIENT CAS No. EC No. Weight % Symbols Risk Phrases Ordinary Portland Cement Xi (Irritant) See section FIRST AID Also contains silica flour, silica sand and other additives. CONTACT WITH SKIN: CONTACT WITH EYES: INGESTION: INHALATION: OTHER INFORMATION: Wash off with plenty of soap and water. Remove contaminated clothing. Wash out with water for at least 15 minutes and seek medical advice without delay. Wash out mouth with water and give plenty of water to drink. DO NOT INDUCE VOMITING. Remove to fresh air. If nose or airways become inflamed, seek medical advice. Until the mixture has set, may cause both irritant and allergic contact dermatitis. 5. FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL PROTECTIVE EQUIPMENT: As appropriate to surrounding fire. No particular requirements. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: CLEAN-UP PROCEDURES: Wear suitable protective clothing appropriate to the amount involved which may include eye/face protection, PVC or synthetic rubber gloves, protective footwear and overalls, particularly during mixing operations. Contain the spillage and keep children away from the area. Recover the spilt material in a dry state if possible.

26 Minimise generation of airborne dust. 7. HANDLING AND STORAGE HANDLING PRECAUTIONS: STORAGE INFORMATION: Observe good hygiene standards and minimise skin contact. Wear suitable protective clothing according to item 8. Keep containers tightly closed in a cool place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION When handling or mixing the product, protective clothing should be worn, including eye protection and PVC or synthetic rubber gloves. Wash hands and exposed skin before meals and after work. Do not wear contaminated clothing. EXPOSURE LIMITS Occupational exposure standard (8h TWA): 10mg/m³ total inhalable dust, 5mg/m³ respirable dust 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Grey Powder Oxidising Properties None Odour None Vapour Pressure Not relevant ph 11, when wet Relative density Not relevant Boiling Point Not Relevant Bulk density 1300 kg/m³ Melting Point Not Relevant Viscosity Not relevant Flash Point None Solubility Very slightly soluble in water Autoignition temperature Not Combustible Partition Coefficient Not relevant Explosive Properties: None Other data 10. STABILITY / REACTIVITY STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID: Stable under normal conditions of use. Damp (degrades product). No particular requirements. 11. TOXICOLOGICAL INFORMATION Severe eye irritant. Irritating to skin the powder or its mixture with water may cause irritant dermatitis or burns, and traces of hexavalent chromium in the product may cause allergic dermatitis. Ingestion of small amounts is unlikely to cause any significant reaction, but large doses may result in irritation to the gastro intestinal tract. 12. ECOLOGICAL INFORMATION MOBILITY: DEGRADABILITY: ACCUMULATION: Not mobile in soil. Relatively inert. No potential for bioaccumlation or biomagnification.

27 ECOTOXICITY: Addition of cement-based products to water may cause the ph to rise, and they may therefore be toxic to aquatic life in some circumstances. 13. DISPOSAL CONSIDERATIONS DISPOSAL OF PRODUCT: DISPOSAL OF PACKAGING: Dispose of in accordance with local and national regulations (normally landfill), or to any place authorised to accept builders waste. Packaging should be treated as for the product, or may be incinerated. 14. TRANSPORT INFORMATION UN NO. PROPER SHIPPING NAME ADR/RID IMCO ICAO/IATA PACKING GROUP LABEL None assigned Portland cement mixture Not classified as hazardous Not classified as hazardous Not classified as hazardous No hazard label 15. REGULATORY INFORMATION CLASSIFICATION LABEL INFORMATION: Irritant IRRITATING TO THE SKIN RISK OF SERIOUS DAMAGE TO THE EYES MAY CAUSE SENSITISATION BY SKIN CONTACT DO NOT BREATHE DUST AVOID CONTACT WITH THE SKIN READ ALL PRECAUTIONS BEFORE USE The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the following items of personal protective equipment. WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection. IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice. AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water. KEEP OUT OF REACH OF CHILDREN. Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act. The information contained in this safety data sheet does not constitute the user s own assessment of workplace risk as required by health and safety legislation. 16. OTHER INFORMATION The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES occupational exposure standard. STEL short-term exposure limit. LTEL long term exposure limit. TWA time weighted (8 hour) average. LEL lower explosive limit. UEL upper explosive limit.