SAFETY DATA SHEET EPOXY TOOLING GEL COAT

Transcription

1 Easy Composites Ltd MSDS EPOXY TOOLING GEL COAT Revision 1 Page 1 of 7 SAFETY DATA SHEET EPOXY TOOLING GEL COAT 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company Epoxy Tooling Gel Coat Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke on Trent ST3 5XA United Kingdom sales@easycomposites.co.uk Telephone +44 (0) HAZARDS IDENTIFICATION Main hazards Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients Conc. CAS EINECS CAS Symbols/Risk phrases Glycidyl ether 1 30% Xi; R36/38-43 N; R51/53 Bisphenol A-(epichlorhydrin) (reaction product) 20-60% Xi; R36/37/38 R43 N; R51/53 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion 5. FIRE FIGHTING MEASURES Extinguishing media Fire hazards Protective equipment 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Irritating to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. Carbon oxides. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. Ensure adequate ventilation of the working area. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe.

2 Easy Composites Ltd MSDS EPOXY TOOLING GEL COAT Revision 1 Page 2 of 7 Clean up methods Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. 7. HANDLING AND STORAGE Handling Storage Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Respiratory protection Hand protection Eye protection Protective equipment Ensure adequate ventilation of the working area. Wear: Suitable respiratory equipment. Chemical resistant gloves (PVC) Approved safety goggles. Wear chemical protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Description Paste. Colour Bright Green. Odour Odourless. Relative density 1.45 Viscosity mpa.s (25 C) 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION Toxicological information Bisphenol A-(epichlorhydrin) (reaction product) Oral Rat LD50 = mg/kg Dermal Rabbit LD50 = > 2000 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Bisphenol A (epichlorhydrin) (reaction product) Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. Green algae EC50/96h = 220 mg/l Rainbow trout LC50/96h = mg/l 13. DISPOSAL CONSIDERATIONS General information Dispose of in compliance with all local and national regulations. 14. TRANSPORT INFORMATION ADR/RID UN 3082 Packing group III Class 9 Hazard ID 90 Proper Shipping Name ENVIRONMENTALLY

3 Easy Composites Ltd MSDS EPOXY TOOLING GEL COAT Revision 1 Page 3 of 7 IMDG HAZARDOUS SUBSTANCE, LIQUID, N.O.S. UN 3082 Packing group III Class 9 Marine pollutant EmS Code F A S B IATA UN 3082 Packing group III Class 9 Subsidiary risk Packing Instruction (Cargo) 914 Maximum quantity 450L Packing Instruction (Passenger) 914 Maximum quantity 450L 15. REGULATORY INFORMATION Labelling Symbols The product is classified in accordance with 67/548/EEC. Xi Irritant; N - Dangerous for the environment Risk phrases Safety phrases R36/38 Irritating to eyes and skin. R52/53 Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment. S24 Avoid contact with skin. S29 Do not empty into drains. S37 Wear suitable gloves. 16. OTHER INFORMATION Text of risk phrases in Section 3. Further information R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.

4 Page 4 of 7 SAFETY DATA SHEET EPOXY TOOLING GEL COAT 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company Epoxy Tooling Gel Coat Hardener Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke on Trent ST3 5XA United Kingdom sales@easycomposites.co.uk Telephone +44 (0) HAZARDS IDENTIFICATION Classification 1999/45/ЕC Main hazards Symbols T+; R26 C; R34 Xn; R62 Xi; R43 N; R50/53 Symbols: T+: Very toxic. N: Dangerous for the environment. Very toxic by inhalation. Causes burns. May cause sensitisation by skin contact. Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. Possible risk of impaired fertility. Risk phrases Safety phrases R26 Very toxic by inhalation. R34 Causes burns. R50/53 Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. S29 Do not empty into drains. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S63 In case of accident by inhalation: remove casualty to fresh air and keep at rest. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients Conc. CAS EINECS CAS Symbols/Risk phrases 3,6,9,12 Tetra azatetradecamethylenediamine % C; R34 R43 N; R50/53 2,2' Iminodiethylamine (2,2' Iminodi(ethylamine)) 1 25% T+; R26 C; R34 Xn; R21/22 Xi;R43 4,4' Isopropylidenediphenol 1 25% Re. C. 3; R62 Xi; R37 41 R43 R52

5 Page 5 of 7 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion 5. FIRE FIGHTING MEASURES Extinguishing media Special hazards Advice for firefighters 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean up methods 7. HANDLING AND STORAGE Handling Storage Specific End Uses Causes burns. Remove contaminated clothing. Wash off immediately with plenty of soap and water. Seek medical attention. Causes burns. Causes severe inflammation and may damage the cornea. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention. Very toxic by inhalation. Seek medical attention. Immediate medical attention is required. Remove casualty from exposure ensuring one's own safety whilst doing so. Remove the affected person from the source of contamination immediately. Ingestion causes burns to the respiratory tract. DO NOT INDUCE VOMITING. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Drink 1 to 2 glasses of water. Carbon dioxide (CO2). Dry chemical. For large fires:. Water spray. Alcohol resistant foam. Corrosive. Burning produces irritating, toxic and obnoxious fumes. Wear self contained breathing apparatus and protective clothing. Do not allow runoff water to enter sewers or drains. Ensure adequate ventilation of the working area. Wear suitable protective clothing. Wear suitable protective equipment. Wear suitable respiratory equipment when necessary. Do not allow runoff water to enter sewers or drains. Do not flush into surface water. Do not let product contaminate subsoil. Prevent further spillage if safe. Absorb with inert, absorbent material. Clean area thoroughly with detergent. Transfer to suitable, labelled containers for disposal. Ensure adequate ventilation of the working area. Wear suitable respiratory equipment when necessary. Avoid contact with eyes and skin. Adopt best Manual Handling considerations when handling, carrying and dispensing. Do not eat, drink or smoke in areas where this product is used or stored. Wash hands after handling the product. Keep container tightly closed and dry. Keep in a cool, dry, well ventilated area. Wear suitable protective clothing. Wear suitable protective equipment. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits 2,2'-Iminodiethylamine WEL 8 hr limit ppm: 1 WEL 8 hr limit mg/m3: 4.3 (2,2'-Iminodi(ethylamine)) WEL 15 min limit ppm: WEL 15 min limit mg/m3: 3,6,9,12 Tetraazatetradecameth ylenediamine WEL 8 hr limit ppm: WEL 8 hr limit mg/m3: 1.59 WEL 15 min limit ppm: WEL 15 min limit mg/m3: 8550 Engineering measures Respiratory protection Hand protection Eye protection Protective equipment Ensure adequate ventilation of the working area. Do not breathe gas/fumes/vapour/spray. Wear suitable respiratory equipment when necessary. Wear:. Butyl rubber gloves. Nitrile rubber gloves. Wash hands after handling the product. Approved safety goggles. Avoid contact with eyes Wear suitable gloves and eye/face protection. Wear suitable protective clothing. Wear suitable protective equipment.

6 Page 6 of 7 9. PHYSICAL AND CHEMICAL PROPERTIES Description Liquid. Colour Amber. Odour Ammoniacal. Relative density Viscosity 350 mpa.s (25 C) 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Incompatible materials Hazardous decomp. products 11. TOXICOLOGICAL INFORMATION Avoid contact with: Acids, Alkalis, Oxidising agents. Will not decompose if stored and used as recommended. Avoid contact with: Acids, Alkalis, Oxidising agents. Contact with strong acids will produce an exothermic reaction. Strong acids. Strong bases. Strong oxidising agents. Will not decompose if stored and used as recommended. Burning produces irritating, toxic and obnoxious fumes. Carbon oxides. Nitrogen oxides. Ammonia. Acute toxicity Skin corrosion/irritation Serious eye damage Respiratory or skin sensitisation Reproductive toxicity Causes severe burns. Very toxic by inhalation. CAUSES SKIN BURNS. May cause allergic reactions in susceptible people. CAUSES EYE BURNS. May cause sensitisation by inhalation and skin contact. Possible risk of impaired fertility. 2,2' iminodiethylamine Oral Rat LD50: 1620 mg/kg Dermal Rabbit LD50: 1045 mg/kg 3,6,9,12 Tetraazatetradecameth Oral Rat LD50: 1600 mg/kg Dermal Guinea Pig LD50: Sensitising ylenediamine 4,4' Inhalation Rat LC50/4 h: > 5 mg/l Oral Rat LD50: 3250 mg/kg Isopropylidenediphenol Dermal Rabbit LD50: 3000 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 2,2' iminodiethylamine Daphnia EC50/48h: mg/l Fish LC50/96h: mg/l Algae EC50/72h: 1164 mg/l 3,6,9,12 Tetra azatetradecameth Daphnia EC50/48h: 17.5 mg/l Algae IC50/72h: mg/l ylenediamine Fish LC50/96h: 180 mg/l Algae EC50/72h: 0.7 mg/l 13. DISPOSAL CONSIDERATIONS General information Disposal methods Disposal of packaging Dispose of in compliance with all local and national regulations. Incinerate in suitable incineration plant, observing local authority regulations. Containers must be recycled in compliance with national legislation and environmental regulations. Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.

7 Page 7 of TRANSPORT INFORMATION Hazard pictograms ADR/RID UN 2079 Packing group II Class 8 Hazard ID 80 Proper Shipping Name DIETHYLENETRIAMINE (Contains: 3,6,9,12 Tetra azatetradecamethylenediamine; Diethylenetriamine) IMDG UN 2079 Packing group II Class 8 Marine pollutant EmS Code F A S B IATA UN 2079 Packing group II Maximum quantity 1L Packing Instruction 851 (Passenger) (Passenger) Maximum quantity 30L Class 8 (Cargo) Subsidiary Risk Packing Instruction (Cargo) REGULATORY INFORMATION Regulations WGK 3. Chemical safety A Chemical Safety Assessment has not been carried out for this product. assessment 16. OTHER INFORMATION Text of risk phrases in Section 3. Further information R21/22 Harmful in contact with skin and if swallowed. R26 Very toxic by inhalation. R34 Causes burns. R37 Irritating to respiratory system. R41 Risk of serious damage to eyes. R50/53 Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. R52 Harmful to aquatic organisms. R62 Possible risk of impaired fertility. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.