MATERIAL SAFETY DATA SHEET

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY Product rbs Epoxy Pourable Grout Base Component Company Name Resapol Ltd Unit E Aspul Court Moss Industrial Estate Leigh. Lancashire WN7 3PT Tel: +44 (0) Fax: +44 (0) COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients Mixture of Epoxy Resin and reactive diluent Name EC No CAS No Content Symbol R Phrase Bisphenol A=Epichlorhydrin Resin with no. average M.W.= % Xi,N R36/3 R43 R51 R53 Bisphenol F = Epoxy Resin % Xi N R36/3 R43 R51 R53 C 12-C 14 aliphatic Glycidyl Ether % Xi,N R36/3 R43 R51 R53 3. HAZARDS INDENTIFICATION Main Hazards Irritating to eyes and skin. May cause sensitisation by skin contact. Not classified as flammable but will burn. 4. FIRST AID MEASURES Skin contact Eye contact Ingestion Inhalation Remove contaminated clothing immediately. Rinse affected skin with copious amounts of soap and water. If persistent irritation occurs obtain medical attention. Immediately flush eyes with running water for at least 15 minutes without interruption. Seek medical advice. DO NOT induce vomiting. If rapid recovery does not occur obtain medical attention. No specific measures. Remove to fresh air in case of indisposition. rbs Epoxy Pourable Grout Page 1 of

2 5. FIRE-FIGHTING MEASURES Extinguishing media Exposure hazards Protection of fire fighters Dry powder, Carbon Dioxide, Water spray. Carbon Monoxide may be evolved if incomplete combustion occurs. Wear full protective clothing and self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean-up procedures Avoid skin, eye and clothing contact. Provide sufficient ventilation during use. Prevent from entering sewer system, surface water or soil. Prevent from spreading into drains, ditches or rivers by using sand, earth or other appropriate barriers Soak up with absorbent material e.g. dry sand, vermiculite, and dispose of as instructed Shovel up and place in a labeled, sealable container for subsequent disposal. 7. HANDLING AND STORAGE Handling requirements Storage conditions Suitable packaging Use in well ventilated areas. Keep containers tightly closed when not in use. Avoid contact with skin, eyes and clothing. Avoid temperatures below 5 C. Store at ambient temperatures. Must only be kept in original packaging.. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures Hand protection Eye protection Skin protection Ensure there is sufficient ventilation of the work area. PVC or Rubber Protective Gloves. Mono-goggles. Standard issue work clothes. Chemical Resistant Safety Boots/Shoes.. PHYSICAL AND CHEMICAL PROPERTIES State Colour Odour Solubility in water Density Flash point C Liquid Clear. Slight Negligible /cm³@20 C. >200 C 10. STABILITY AND REACTIVITY rbs Epoxy Pourable Grout Page 2 of

3 Stability Conditions to avoid Materials to avoid Haz. Decompositon Products Stable under normal conditions. Thermal decomposition not applicable under normal conditions. Temperatures above 5 C. Acids, Strong Oxidising Agents, and Caustic Soda. Carbon Dioxide, Carbon Monoxide. 11. TOXICOLOGICAL INFORMATION Ingestion Eye Contact Skin Contact Mutagenicity LD50 Acute oral toxicity in rats : >2000mg/kg. Eye irritation tested in rabbits : Irritant Skin irritation tested in rabbits : Irritant Negative Ames test. 12. ECOLOGICAL INFORMATION Mobility Readily absorbed into soil. Prevent contamination of soil, drains or surface water Bioaccumulative potential Other adverse effects Material sinks in water and has the potential to Bio-accumulate. Not readily Bio-degradable (Sturm Test), Toxic to aquatic organisms 13. DISPOSABLE CONSIDERATIONS 14. TRANSPORT INFORMATION ADR/RID Recover or recycle if possible. Otherwise dispose to licensed disposal contractor. 302 ADR Class Classification code C11 Proper Shipping Name Environmentally Hazardous Substance, Liquid n.o.s (Bisphenol A Epoxy Resins) Risk no 0 IMDG/IMO 302 Class EmS F-A S-F Marine Pollutant Y Labelling IATA/ICAO rbs Epoxy Pourable Grout Page 3 of

4 302 Class Packing Instruction 14 (cargo/passenger aircraft) Labelling 15. REGULATORY INFORMATION Hazard Symbol Risk Phrases Safety Phrases Xi, Irritant. N, Dangerous to the environment. R36/3, Irritating to eyes and skin. R43, May cause sensitization by skin contact. R51, Toxic to aquatic organisms R53, May cause long-term adverse effects in the aquatic environment. S24, Avoid contact with skin. S26, In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S2, After contact with skin, wash immediately with soap and water. S37/3, Wear suitable protective clothing, gloves, and eye/face protection. S61, Avoid release to the environment. 16. OTHER INFORMATION Other information rbs Epoxy Pourable Grout Page 4 of

5 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY Product rbs Epoxy Pourable Grout Hardener Component Company Name Resapol Ltd Unit E Aspul Court Moss Industrial Estate Leigh. Lancashire WN7 3PT Tel: +44 (0) Fax: +44 (0) COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients Modified cycloaliphatic polyamine Name EC No CAS No Content Classification Trimethylhexamethylene diamine % R22 R34 R43. R52/53 3. HAZARDS INDENTIFICATION Main Hazards Harmful by inhalation and if swallowed. Causes burns. May cause sensitization by skin contact. Harful to aquatic organisms, may cause long term adverse effects in the aquatic environment C; R22, R34. R43, R52/53 4. FIRST AID MEASURES Note: Skin contact Eye contact Ingestion Inhalation Treat like chemical burns Remove contaminated clothing immediately. Rinse affected skin with copious amounts of water. Immediately flush eyes with running water for a least 15 minutes without interruption. Seek medical advice. DO NOT induce vomiting. Drink water to dilute. Drink citrus fruit juice for neutralisation. Remove to fresh air in case of indisposition. 5. FIRE-FIGHTING MEASURES Extinguishing media Exposure hazards Protection of fire-fighters Dry powder, Carbon dioxide, Water spray. Foam. Carbon Dioxide, Carbon Monoxide, and Nitrogen Oxides may be formed. Wear self contained breathing apparatus. rbs Epoxy Pourable Grout Page 5 of

6 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean-up procedures Avoid skin and eye contact, Provide sufficient ventilation during use. Prevent from entering sewer system, surface water or soil. Soak up with absorbent material e.g. dry sand, vermiculite, and dispose of as instructed (see section 13). 7. HANDLING AND STORAGE Handling requirements Storage conditions Use in well ventilated areas. Keep containers tightly closed when not in use. Avoid temperatures below 5 C. Must only be kept in original packaging.. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures Hand protection Eye protection Skin protection Ensure there is sufficient ventilation of the area. Protective gloves of PVC or rubber. Full face safety goggles. Rubber or plastic apron, Suitable arm protection if body contact is possible.. PHYSICAL AND CHEMICAL PROPERTIES State Colour Odour Specific Gravity Solubility in water Viscosity Flash point C Liquid. Pale Yellow. Characteristic Amine gcm-³ Partly soluble. C. 114 C. 10. STABILITY AND REACTIVITY Stability Conditions to avoid Materials to avoid Haz. Decomp. Products Stable under normal conditions. Thermal decomposition occurs at temperatures above 250 C with liberation of harmful gases. Frost, contact with reactive materials. Strong acids and strong bases. Strong oxidizing agents. Carbon Dioxide, Carbon Monoxide, Nitrogen Oxides, Ammonia 11. TOXICOLOGICAL INFORMATION rbs Epoxy Pourable Grout Page 6 of

7 Ingestion Eye Contact Skin Contact Sensitization LD50 Acute oral toxicity in rats : 50 mg/kg. Eye irritation tested in rabbits : Corrosive. Skin irritation tested in rabbits : Corrosive. Causes sensitization (guinea pig) 12. ECOLOGICAL INFORMATION Mobility Bioaccumulative potential Other adverse effects Readily absorbed into soil. Prevent contamination of soil, drains or surface water. No data available. Not regarded as dangerous for the environment 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION ADR/RID Burn in compliance with local and national regulations in a hazardous incinerator ADR Class Classification code C7 Proper Shipping Name Trimethyl Hexamethylenediamine Hazard ID no 0 Labelling IMDG/IMO 2327 Class EmS F-A,S-B Marine Pollutant No Proper Shipping Name Trimethyl Hexamethylenediamine IATA/ICAO 2327 Class Packing Instruction 1(P & CA); 20(CAO) Labelling Proper Shipping Name Trimethyl Hexamethylenediamine 15. REGULATORY INFORMATION rbs Epoxy Pourable Grout Page 7 of

8 Hazard Symbol Risk Phrases Corrosive R22, Harmful if swallowed, R34, Causes burns, R43, May cause sensitization by skin contact R52/53, Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment. Safety Phrases S26, In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; S36/37/3, Wear suitable protective clothing, gloves and eye/face protection; S45, In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 16. OTHER INFORMATION Other information Legal disclaimer. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Resapol Ltd shall not be held liable for any damage resulting from handling or from contact with the above product. rbs Epoxy Pourable Grout Page of