: Rhino Non-Acid Drain Unblocker

Transcription

1 Date of issue: 9/7/2017 Revision date: 9/7/2017 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Type of product : Mixture : Rhino Non-Acid Drain Unblocker : Detergent 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Main use category Use of the substance/mixture : Professional use,consumer use : Cleaning agent Uses advised against 1.3. Details of the supplier of the safety data sheet Kilrock Products Ltd Units 1b/2b Alma Road ind Est HP5 3HB Chesham - United Kingdom T +44 (0) velda@kilrock.co.uk 1.4. Emergency telephone number Emergency number : +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 1A H314 Full text of hazard classes and H-statements : see section 16 Adverse physicochemical, human health and environmental effects Causes severe skin burns and eye damage Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Security closing plug for children Tactile warning : Danger GHS05 : Sodium Hydroxide : H314 - Causes severe skin burns and eye damage. : P102 - Keep out of reach of children. P260 - Do not breathe fume, mist, spray, vapours. P280 - Wear eye protection, protective clothing, protective gloves. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER or doctor/physician. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : Applicable : Applicable 9/7/2017 EN (English) 1/7

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Sodium Hydroxide (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium hydroxide Skin Corr. 1A, H314 (EC-No.) Skin Irrit. 2, H315 Eye Dam. 1, H318 Specific concentration limits: Name Product identifier Specific concentration limits Sodium Hydroxide (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Full text of H-statements: see section 16 ( 0.5 =<C < 2) Eye Irrit. 2, H319 ( 0.5 =<C < 2) Skin Irrit. 2, H315 ( 2 =<C < 5) Skin Corr. 1B, H314 (C >= 5) Skin Corr. 1A, H314 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a physician immediately. : Remove person to fresh air and keep comfortable for breathing. : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. : Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion : Burns. : Serious damage to eyes. : Burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Use extinguishing media appropriate for surrounding fire. : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe fume, mist, spray, vapours. 9/7/2017 EN (English) 2/7

3 For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Do not breathe fume, mist, spray, vapours. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Sodium Hydroxide ( ) : Store locked up. Store in a well-ventilated place. Keep cool. United Kingdom Local name Sodium hydroxide United Kingdom WEL STEL (mg/m³) 2 mg/m³ 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Personal protective equipment: Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing. Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear respiratory protection Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour 9/7/2017 EN (English) 3/7

4 Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Not applicable : Not applicable 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : Causes severe skin burns and eye damage. : Serious eye damage, category 1, implicit SECTION 12: Ecological information Toxicity Ecology - general : Before neutralisation, the product may represent a danger to aquatic organisms. 9/7/2017 EN (English) 4/7

5 Sodium Hydroxide ( ) LC50 fish 1 EC50 other aquatic organisms 1 > 35 mg/l > 33 mg/l waterflea Persistence and degradability Bioaccumulative potential Sodium Hydroxide ( ) Log Pow Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Avoid release to the environment. ADR IMDG IATA ADN RID UN number UN proper shipping name Transport document description HYDROXIDE, HYDROXIDE, 8, II, (E) 8, II Sodium hydroxide solution UN 1824 Sodium hydroxide solution, 8, II HYDROXIDE, 8, II HYDROXIDE, 8, II Transport hazard class(es) Packing group II II II II II Environmental hazards Marine pollutant : No Special precautions for user No supplementary information available - Overland transport Classification code (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) : C5 : 1l : P001, IBC02 : MP15 : T7 : TP2 9/7/2017 EN (English) 5/7

6 Tank code (ADR) Vehicle for tank carriage : L4BN : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) EAC code - Transport by sea Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Segregation (IMDG) Properties and observations (IMDG) : E : 2R : 1 L : P001 : IBC02 : T7 : TP2 : F-A : S-B : A : SG35 : Colourless liquid. Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) : 30L : A3 : 8L : C5 : 1 L : T Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : PP, EP : C5 : 1L : P001, IBC02 : MP15 : T7 : TP2 Transport category (RID) : 2 Colis express (express parcels) (RID) : L4BN : CE6 Hazard identification number (RID) : Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable 9/7/2017 EN (English) 6/7

7 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Rhino Non-Acid Drain Unblocker - Reaction products of C12-18-(even numbered)- alkylamines and acrylic acid and sodium hydroxide Detergent Regulation : Ingredient data sheet: Component CAS-No. % AQUA >=10% Sodium hydroxide >=10% Reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium hydroxide Detergent Regulation : Labelling of contents: Component % amphoteric surfactants <5% 1-10% National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 H314 H315 H318 Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage SDS EU (REACH Annex II) - Llewellyn This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 9/7/2017 EN (English) 7/7