1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Avonley Road

Transcription

1 Date of issue Revision datesupersedes Version 3.0 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product name Carclin Pro Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Function or use category Professional use Cleaning/washing agents and additives Uses advised against 1.3. Details of the supplier of the safety data sheet K-Apex International B.V. Graafsingel RT Duiven - Nederland T +31 (0) info@k-apex.com Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Avonley Road SE14 5ER London Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Corrosive to metals, Category 1 Skin corrosion/irritation, Category 1A Serious eye damage/eye irritation, Category 1 Full text of H statements see section 16 H290 H314 H Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) Child-resistant fastening Tactile warning Danger GHS05 H290 - May be corrosive to metals H314 - Causes severe skin burns and eye damage P260 - Do not breathe dust, fume, gas, mist, vapours, spray P303+P361+P353 - IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P405 - Store locked up P501 - Dispose of contents/container to a hazardous or special waste collection point No No EN (English) 1/7

2 2.3. Other hazards Adverse physicochemical, human health and environmental effects May be corrosive to metals. Causes severe skin burns and eye damage. Causes serious eye damage. SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Call a physician immediately. Remove person to fresh air and keep comfortable for breathing. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Burns. Symptoms/injuries after eye contact Serious damage to eyes. Symptoms/injuries after ingestion Burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Do not attempt to take action without suitable protective equipment. For further information refer to section 8 "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Take up liquid spill into absorbent material. Other information Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Ensure good ventilation of the work station. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Wear personal protective equipment EN (English) 2/7

3 Hygiene measures Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials 7.3. Specific end use(s) Store in corrosive resistant container with a resistant inner liner. Keep only in original container. Store locked up. Store in a well-ventilated place. Keep cool. Metals. SECTION 8 Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Ensure good ventilation of the work station. protective gloves Type Material Permeation Thickness (mm) Penetration Standard Disposable gloves Neoprene rubber (HNBR) 6 (> 480 minutes) 0,25 mm EN 374 Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) > 0,31 mm EN 374 Disposable gloves Eye protection Polyvinylchloride (PVC) 6 (> 480 minutes) 0,2 mm EN 374 Safety glasses Skin and body protection Respiratory protection Environmental exposure controls Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Avoid release to the environment. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour dark brown. Odour Sweet. Odour threshold ph 12-13,5 Relative evaporation rate (butyl acetate=1) Melting point Not applicable Freezing point Boiling point 100 C Flash point > 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Not applicable Vapour pressure 23 hpa Relative vapour density at 20 C 1,06-1,08 Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information EN (English) 3/7

4 SECTION 10 Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials metals Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Causes severe skin burns and eye damage. ph 12-13,5 Causes serious eye damage. ph 12-13,5 SECTION 12 Ecological information Toxicity Ecology - general Before neutralisation, the product may represent a danger to aquatic organisms Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Waste treatment methods Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1760 UN-No. (IMDG) EN (English) 4/7

5 UN-No. (IATA) 1760 UN-No. (ADN) 1760 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. Corrosive liquid, n.o.s. CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. UN 1760 CORROSIVE LIQUID, N.O.S. (), 8, III, (E) UN 1760 CORROSIVE LIQUID, N.O.S., 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) EN (English) 5/7

6 Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) C9 Special provisions (ADR) 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage 5l E1 P001, IBC03, LP01, R001 MP19 T7 TP1, TP28 L4BN AT Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) V12 Hazard identification number (Kemler No.) 80 Orange plates Tunnel restriction code (ADR) EAC code APP code E 2X B - Transport by sea Special provisions (IMDG) 223, 274 Limited quantities (IMDG) 5 L Excepted quantities (IMDG) E1 Packing instructions (IMDG) P001, LP01 IBC packing instructions (IMDG) IBC03 Tank instructions (IMDG) T7 Tank special provisions (IMDG) TP1, TP28 EmS-No. (Fire) F-A EmS-No. (Spillage) S-B Stowage category (IMDG) A Stowage and segregation (IMDG) Clear of living quarters. Properties and observations (IMDG) Causes burns to skin, eyes and mucous membranes. - Air transport PCA Excepted quantities (IATA) E1 PCA Limited quantities (IATA) Y841 PCA limited quantity max net quantity (IATA) 1L PCA packing instructions (IATA) 852 PCA max net quantity (IATA) 5L CAO packing instructions (IATA) 856 CAO max net quantity (IATA) 60L Special provisions (IATA) A3 ERG code (IATA) 8L EN (English) 6/7

7 - Inland waterway transport Classification code (ADN) C9 Special provisions (ADN) 274 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 5 L E1 T Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) PP, EP C9 Special provisions (RID) 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) 5L E1 P001, IBC03, LP01, R001 MP19 T7 Transport category (RID) 3 Special provisions for carriage Packages (RID) Colis express (express parcels) (RID) TP1, TP28 L4BN W12 CE8 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Full text of H- and EUH-statements H290 H314 H318 May be corrosive to metals Causes severe skin burns and eye damage Causes serious eye damage SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 7/7