Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: Revision date: : Version: 2.0
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1 Date of issue Revision date Version 2.0 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product name Carclin BL Tvätt 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Function or use category Professional use Cleaning/washing agents and additives Uses advised against 1.3. Details of the supplier of the safety data sheet K-Apex International B.V. Graafsingel RT Duiven - Nederland T +31 (0) info@k-apex.com Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Avonley Road SE14 5ER London Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 1A Serious eye damage/eye irritation, Category 1 Full text of H statements see section 16 H314 H Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Child-resistant fastening Tactile warning Danger GHS05 Natriummetasilicaat pentahydraat, C9-11 Alcoholethoxylaat H314 - Causes severe skin burns and eye damage P260 - Do not breathe vapours, gas, mist, fume, spray, dust P280 - Wear protective gloves, protective clothing, face protection, eye protection P303+P361+P353 - IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P405 - Store locked up P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation No No EN (English) 1/8
2 2.3. Other hazards Adverse physicochemical, human health and environmental effects Causes severe skin burns and eye damage. Causes serious eye damage. SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] C9-11 Alcoholethoxylaat (CAS No) Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Sodium Tripolyphosphate (CAS No) (EC no) (REACH-no) Natrium-p-cumenesulphonate (CAS No) (EC no) (REACH-no) Natriummetasilicaat pentahydraat (CAS No) (EC no) (REACH-no) Full text of H-statements see section Eye Irrit. 2, H319 STOT SE 3, H335 Aquatic Chronic 4, H413 < 5 Eye Irrit. 2, H319 < 5 Met. Corr. 1, H290 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Call a physician immediately. Remove person to fresh air and keep comfortable for breathing. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Burns. Symptoms/injuries after eye contact Serious damage to eyes. Symptoms/injuries after ingestion Burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Do not attempt to take action without suitable protective equipment. For further information refer to section 8 "Exposure controls/personal protection" EN (English) 2/8
3 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Other information 6.4. Reference to other sections For further information refer to section 13. Take up liquid spill into absorbent material. Dispose of materials or solid residues at an authorized site. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Ensure good ventilation of the work station. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Wear personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Store locked up. Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters Natriummetasilicaat pentahydraat ( ) DNEL/DMEL (Workers) Long-term - systemic effects, dermal 1,49 mg/kg bodyweight/day Long-term - systemic effects, inhalation 6,22 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 0,74 mg/kg bodyweight/day Long-term - systemic effects, dermal 0,74 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 7,5 mg/l PNEC aqua (marine water) 1 mg/l PNEC aqua (intermittent, freshwater) 7,5 mg/l PNEC (STP) PNEC sewage treatment plant 1000 mg/l Natrium-p-cumenesulphonate ( ) DNEL/DMEL (Workers) Long-term - systemic effects, dermal Long-term - systemic effects, inhalation DNEL/DMEL (General population) Long-term - systemic effects, inhalation Long-term - systemic effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (intermittent, freshwater) PNEC (STP) PNEC sewage treatment plant 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls 7,6 mg/kg bodyweight/day 53,6 mg/m³ 13,2 mg/m³ 3,8 mg/kg bodyweight/day 0,23 mg/l 2,3 mg/l 100 mg/l Ensure good ventilation of the work station. Protective gloves Safety glasses Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Avoid release to the environment EN (English) 3/8
4 SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold Liquid ph 12,8 Relative evaporation rate (butyl acetate=1) Melting point Freezing point Colourless. Not applicable Boiling point > 100 C Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Not applicable 1,06-1,07 g/cm³ The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Natriummetasilicaat pentahydraat ( ) LD50 oral rat mg/kg LD50 dermal rat > 5000 mg/kg LC50 inhalation rat (mg/l) > 2,06 mg/l/4h Natrium-p-cumenesulphonate ( ) LD50 oral rat LD50 dermal rabbit C9-11 Alcoholethoxylaat ( ) LD50 oral rat > 7000 mg/kg > 2000 mg/kg mg/kg EN (English) 4/8
5 C9-11 Alcoholethoxylaat ( ) LD50 dermal Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard mg/kg Causes severe skin burns and eye damage. ph 12,8 Causes serious eye damage. ph 12,8 SECTION 12 Ecological information Toxicity Ecology - general Before neutralisation, the product may represent a danger to aquatic organisms. Natriummetasilicaat pentahydraat ( ) LC50 fish mg/l (Brachydanio Rerio) EC50 Daphnia mg/l (Daphnia Magna) C9-11 Alcoholethoxylaat ( ) LC50 fish 1 EC50 Daphnia 1 EC50 72h algae (1) Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 3266 UN-No. (IMDG) 3266 UN-No. (IATA) 3266 UN-No. (ADN) 3266 UN-No. (RID) mg/l 1-10 mg/l (Daphnia magna) 1-10 mg/l (Skeletonema costatum) Dispose of contents/container in accordance with licensed collector s sorting instructions UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. Corrosive liquid, basic, inorganic, n.o.s. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S EN (English) 5/8
6 Transport document description (ADR) Transport document description (IMDG) UN 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (), 8, II, (E) UN 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S., 8, II Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment II II II II II No EN (English) 6/8
7 Marine pollutant Other information No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) C5 Special provisions (ADR) 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage 1l E2 P001, IBC02 MP15 T11 TP2, TP27 L4BN AT Transport category (ADR) 2 Hazard identification number (Kemler No.) 80 Orange plates Tunnel restriction code (ADR) EAC code APP code E 2X B - Transport by sea Special provisions (IMDG) 274 Limited quantities (IMDG) 1 L Excepted quantities (IMDG) E2 Packing instructions (IMDG) P001 IBC packing instructions (IMDG) IBC02 Tank instructions (IMDG) T11 Tank special provisions (IMDG) TP2, TP27 EmS-No. (Fire) F-A EmS-No. (Spillage) S-B Stowage category (IMDG) B Stowage and segregation (IMDG) Clear of living quarters. 'Separated from' acids. Properties and observations (IMDG) Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. - Air transport PCA Excepted quantities (IATA) E2 PCA Limited quantities (IATA) Y840 PCA limited quantity max net quantity (IATA) 0.5L PCA packing instructions (IATA) 851 PCA max net quantity (IATA) 1L CAO packing instructions (IATA) 855 CAO max net quantity (IATA) 30L Special provisions (IATA) A3 ERG code (IATA) 8L - Inland waterway transport Classification code (ADN) C5 Special provisions (ADN) 274 Limited quantities (ADN) 1 L Excepted quantities (ADN) E2 Carriage permitted (ADN) T Equipment required (ADN) PP, EP EN (English) 7/8
8 Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) C5 Special provisions (RID) 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) 1L E2 P001, IBC02 MP15 T11 Transport category (RID) 2 Colis express (express parcels) (RID) TP2, TP27 L4BN CE6 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Full text of H- and EUH-statements Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 4 Hazardous to the aquatic environment Chronic Hazard, Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Met. Corr. 1 Corrosive to metals, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H290 May be corrosive to metals H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H319 Causes serious eye irritation H335 May cause respiratory irritation H413 May cause long lasting harmful effects to aquatic life SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 8/8
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