1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Avonley Road

Transcription

1 Date of issue Revision datesupersedes Version 3.0 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Function or use category Professional use Cleaning/washing agents and additives Uses advised against 1.3. Details of the supplier of the safety data sheet K-Apex International B.V. Graafsingel RT Duiven - Nederland T +31 (0) info@k-apex.com Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Avonley Road SE14 5ER London Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Corrosive to metals, Category 1 Skin corrosion/irritation, Category 1A Serious eye damage/eye irritation, Category 1 Full text of H statements see section 16 H290 H314 H Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Child-resistant fastening Tactile warning Danger GHS05 Tetrasodium ethylene diamine tetraacetate, sodium hydroxide, caustic soda H290 - May be corrosive to metals H314 - Causes severe skin burns and eye damage P260 - Do not breathe vapours, gas, mist, fume, spray, dust P303+P361+P353 - IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P405 - Store locked up P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation No No EN (English) 1/9

2 2.3. Other hazards Adverse physicochemical, human health and environmental effects May be corrosive to metals. Causes severe skin burns and eye damage. Causes serious eye damage. SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] sodium hydroxide, caustic soda (CAS No) (EC no) (EC index no) Tetrasodium ethylene diamine tetraacetate (CAS No) (EC no) (EC index no) (REACH-no) Natrium-p-cumenesulphonate (CAS No) (EC no) (REACH-no) propan-2-ol, isopropyl alcohol, isopropanol (CAS No) (EC no) (EC index no) Natriummetasilicaat pentahydraat (CAS No) (EC no) (REACH-no) Skin Corr. 1A, H314 < 5 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Eye Dam. 1, H318 STOT RE 2, H373 (CAS No) < 5 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 < 5 Eye Irrit. 2, H319 < 5 Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 < 5 Met. Corr. 1, H290 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 Specific concentration limits Name Product identifier Specific concentration limits sodium hydroxide, caustic soda (CAS No) (EC no) (EC index no) Full text of H-statements see section 16 (0,5 =< C < 2) Skin Irrit. 2, H315 (0,5 =< C < 2) Eye Irrit. 2, H319 (2 =< C < 5) Skin Corr. 1B, H314 (C >= 5) Skin Corr. 1A, H314 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Call a physician immediately. Remove person to fresh air and keep comfortable for breathing. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Burns. Symptoms/injuries after eye contact Serious damage to eyes. Symptoms/injuries after ingestion Burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released EN (English) 2/9

3 5.3. Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Do not attempt to take action without suitable protective equipment. For further information refer to section 8 "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Take up liquid spill into absorbent material. Other information Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Ensure good ventilation of the work station. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Wear personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials 7.3. Specific end use(s) Store in corrosive resistant container with a resistant inner liner. Keep only in original container. Store locked up. Store in a well-ventilated place. Keep cool. Metals. SECTION 8 Exposure controls/personal protection 8.1. Control parameters Tetrasodium ethylene diamine tetraacetate ( ) DNEL/DMEL (Workers) Acute - local effects, inhalation 2,8 mg/m³ DNEL/DMEL (General population) Acute - systemic effects, inhalation 1,7 Long-term - systemic effects,oral 28 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 2,8 mg/l PNEC aqua (marine water) 0,28 mg/l PNEC (Sediment) PNEC sediment (freshwater) 0,95 mg/kg dwt PNEC (STP) PNEC sewage treatment plant 57 mg/l sodium hydroxide, caustic soda ( ) DNEL/DMEL (Workers) Long-term - local effects, inhalation DNEL/DMEL (General population) Long-term - local effects, inhalation Natrium-p-cumenesulphonate ( ) DNEL/DMEL (Workers) Long-term - systemic effects, dermal Long-term - systemic effects, inhalation 1 mg/m³ 1 mg/m³ 7,6 mg/kg bodyweight/day 53,6 mg/m³ EN (English) 3/9

4 Natrium-p-cumenesulphonate ( ) DNEL/DMEL (General population) Long-term - systemic effects, inhalation Long-term - systemic effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (intermittent, freshwater) PNEC (STP) PNEC sewage treatment plant 13,2 mg/m³ 3,8 mg/kg bodyweight/day 0,23 mg/l 2,3 mg/l 100 mg/l propan-2-ol, isopropyl alcohol, isopropanol ( ) DNEL/DMEL (Workers) Acute - local effects, inhalation 500 mg/m³ Long-term - systemic effects, dermal 888 mg/kg bodyweight/day DNEL/DMEL (General population) Long-term - systemic effects,oral 26 mg/kg bodyweight/day Long-term - systemic effects, inhalation 89 mg/m³ Long-term - systemic effects, dermal 319 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 140,9 mg/l PNEC aqua (marine water) 140,9 mg/l PNEC aqua (intermittent, freshwater) 140,9 mg/l PNEC (Sediment) PNEC sediment (freshwater) 552 mg/kg dwt PNEC sediment (marine water) 552 mg/kg dwt PNEC (Soil) PNEC soil 28 mg/kg dwt PNEC (STP) PNEC sewage treatment plant 2251 mg/l 8.2. Exposure controls Appropriate engineering controls Hand protection Ensure good ventilation of the work station. protective gloves Type Material Permeation Thickness (mm) Penetration Standard Disposable gloves Neoprene rubber (HNBR) 6 (> 480 minutes) 0,25 mm EN 374 Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) > 0,31 mm EN 374 Eye protection Skin and body protection Respiratory protection Environmental exposure controls Safety glasses Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Avoid release to the environment. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour light yellow. Odour characteristic. Odour threshold ph 12,2 Relative evaporation rate (butyl acetate=1) Melting point Not applicable Freezing point Boiling point 100 C Flash point > 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Not applicable Vapour pressure 23 hpa EN (English) 4/9

5 Relative vapour density at 20 C Relative density 1,095 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity completely miscible. The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials metals Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Tetrasodium ethylene diamine tetraacetate ( ) LD50 oral 1780 mg/kg bodyweight Natrium-p-cumenesulphonate ( ) LD50 oral rat LD50 dermal rabbit > 7000 mg/kg > 2000 mg/kg propan-2-ol, isopropyl alcohol, isopropanol ( ) LD50 oral rat 5840 mg/kg LD50 dermal rabbit > mg/kg LC50 inhalation rat (mg/l) 72,6 mg/l/4h Natriummetasilicaat pentahydraat ( ) LD50 oral rat mg/kg LD50 dermal rat > 5000 mg/kg LC50 inhalation rat (mg/l) > 2,06 mg/l/4h Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Causes severe skin burns and eye damage. ph 12,2 Causes serious eye damage. ph 12,2 Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard EN (English) 5/9

6 SECTION 12 Ecological information Toxicity Ecology - general Before neutralisation, the product may represent a danger to aquatic organisms. Tetrasodium ethylene diamine tetraacetate ( ) LC50 fish 1 > 121 mg/l EC50 other aquatic organisms mg/l EC50 waterflea (48 h) EC50 other aquatic organisms 2 2,77 mg/l IC50 algea (72 h) mg/l sodium hydroxide, caustic soda ( ) EC50 Daphnia 1 40,4 mg/l propan-2-ol, isopropyl alcohol, isopropanol ( ) LC50 fish mg/kg (Lepomis Macrochirus) EC50 Daphnia mg/l Natriummetasilicaat pentahydraat ( ) LC50 fish mg/l (Brachydanio Rerio) EC50 Daphnia mg/l (Daphnia Magna) Persistence and degradability Bioaccumulative potential Tetrasodium ethylene diamine tetraacetate ( ) Log Pow -13, Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1760 UN-No. (IMDG) 1760 UN-No. (IATA) 1760 UN-No. (ADN) 1760 UN-No. (RID) 1760 Dispose of contents/container in accordance with licensed collector s sorting instructions UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. Corrosive liquid, n.o.s. CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. UN 1760 CORROSIVE LIQUID, N.O.S. (Sodium hydroxide, Disodium trioxosilicate), 8, II, (E) UN 1760 CORROSIVE LIQUID, N.O.S., 8, II Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) EN (English) 6/9

7 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information II II II II II No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) C9 Special provisions (ADR) 274 Limited quantities (ADR) 1l Excepted quantities (ADR) E2 Packing instructions (ADR) P001, IBC EN (English) 7/9

8 Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage MP15 T11 TP2, TP27 L4BN AT Transport category (ADR) 2 Hazard identification number (Kemler No.) 80 Orange plates Tunnel restriction code (ADR) EAC code APP code E 2X B - Transport by sea Special provisions (IMDG) 274 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Stowage and segregation (IMDG) Properties and observations (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) 1 L E2 P001 IBC02 T11 TP2, TP27 F-A S-B B Clear of living quarters. Causes burns to skin, eyes and mucous membranes. E2 Y840 PCA limited quantity max net quantity (IATA) 0.5L PCA packing instructions (IATA) 851 PCA max net quantity (IATA) 1L CAO packing instructions (IATA) 855 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) 30L A3 8L C9 Special provisions (ADN) 274 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 1 L E2 T Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) PP, EP C9 Special provisions (RID) 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) 1L E2 P001, IBC02 MP15 T EN (English) 8/9

9 Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) Transport category (RID) 2 Colis express (express parcels) (RID) TP2, TP27 L4BN CE6 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Full text of H- and EUH-statements Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Met. Corr. 1 Corrosive to metals, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour H290 May be corrosive to metals H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H373 May cause damage to organs through prolonged or repeated exposure SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 9/9