SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Transcription

1 January 29, 2013 SDS No. P110215E-5 1 / 7 SAFETY DATA SHEET Date January 29, CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: TAFMER DF605 COMPANY IDENTIFICATION: Mitsui Elastomers Singapore Pte Ltd. 3 HarbourFront Place, #10-01 HarbourFront Tower 2, Singapore Telephone: Telefax: Elastomers Division Mitsui Chemicals, Inc. Shiodome City Center 1-5-2, Higashi-Shimbashi, Minato-ku Tokyo , Japan Telephone: Telefax: HAZARDS IDENTIFICATION GHS CLASSIFICATION: This material is not classified for any hazards of GHS. GHS LABEL ELEMENTS: PICTOGRAMS : Not required. SIGNAL WORD : Not required. HAZARD STATEMENTS : Not required. PRECAUTIONARY STATEMENTS: Although none of hazard statements are applicable, this product should be handled with following precautions. Prevention: DO NOT handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use only in a well-ventilated area and DO NOT breathe dust. Use appropriate personal protective equipment as required. Wash hands, face, and other body parts as necessary after handling. Avoid release to the environment.

2 January 29, 2013 SDS No. P110215E-5 2 / 7 Response: If exposed or concerned, or if you feel unwell: Get medical advice/attention. Storage: Avoid direct sunlight, open flame, ignition or other direct heat sources. Store in well ventilated and sheltered area. Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. Do not reuse the container for any other purpose. Dispose of in accordance with applicable laws and regulations. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION: Can burn in fire. Vapors or dust may be ignited by static electricity and other ignition sources. Product is non-biodegradable. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name % CAS No. Ethylene α-olefin copolymer > FIRST AID MEASURES INHALATION: If exposed to excessive levels of fumes or dust, remove casualty to fresh air area. Get medical attention if cough or other symptoms develop. EYE CONTACT: Immediately flush eyes with plenty of water for several minutes. Part eyelids with fingers to assure complete flushing. Check for and remove contact lenses if easily possible. Get medical attention if irritation persists. SKIN CONTACT: Immediately remove contaminated clothing and shoes. Flush skin with large amount of water, clean off with soap and water. Get medical attention if symptoms develop. If molten polymer contact the skin, cool immediately with cold water. Do not attempt to peel polymer from the skin. Get medical attention for thermal burn. INGESTION: Do NOT induce vomiting. Rinse mouth with water. Never give

3 January 29, 2013 SDS No. P110215E-5 3 / 7 anything by mouth to an unconscious person. Keep the affected person warm and at rest. Get medical attention immediately. MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED: Fumes from heated molten polymer may cause irritation to eye and respiratory tract. SPECIAL PROTECTIVE ACTIONS FOR FIRST-AIDERS: Wear appropriate personal protective equipment such as respirator, goggles, protective gloves, etc. if necessary. NOTE TO PHYSICIAN: Treat symptomatically. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: water jet, water fog, dry chemical, CO 2, foam. UNSUITABLE EXTINGUISHING MEDIA: Not specified. SPECIAL HAZARDS: Can burn in fire. Vapors or dust may be ignited by static electricity or other ignition sources. FIRE FIGHTING INSTRUCTIONS: Keep unnecessary and unprotected personnel away. Shut off supply if possible. Remove containers/material to safe place if possible. Keep surrounding areas cool by spraying water. Fight fire from an upwind position. FIRE FIGHTING EQUIPMENT: Respiratory and eye protection required for fire-fighting personnel. Full protective equipment and self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. HAZARDOUS COMBUSTION PRODUCTS: Carbon oxides. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Keep unnecessary and unprotected personnel away. Wear appropriate personal protective equipment as specified in Section 8. Keep in upwind position, evacuate from downwind.

4 January 29, 2013 SDS No. P110215E-5 4 / 7 ENVIRONMENTAL PRECAUTIONS: Product is non-biodegradable. Do not let this material enter the environment. Do not flush or dump into sewer, river or any part of water course. CONTAINMENT/CLEAN-UP METHODS: Vacuum or sweep up material and place in a disposal container. Use non-sparking tools and equipment. If molten polymer is spilled, allow to cool and solidify before proceeding with disposal methods. 7. HANDLING AND STORAGE HANDLING Preventive Measures: Use the material only in well-ventilated area. Keep away from heat, sparks, and flame. Use explosion-proof electrical equipment. Take precaution against build-up of electrostatic charges. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Wear appropriate personal protective equipment. Avoid dust formation. Provide hand and eye wash station near work area. Wash body parts thoroughly after handling. Ventilation: Use only under local exhaust or general ventilation. Safe Handling Advice: Do not handle until all safety precautions have been read and understood. Take precaution against build-up of electrostatic charges. Avoid dust formation. Do not breathe dust. STORAGE Storage Conditions: Protect from direct sunlight. Store in well-ventilated and sheltered are. Keep dry. Store indoor. Packaging Material: Polybag, flexible intermediate bulk container (FIBC), etc. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS: ACGIH-TLV: Not established. OSHA-PEL : Not established.

5 January 29, 2013 SDS No. P110215E-5 5 / 7 ENGINEERING CONTROLS: Provide general ventilation. Use closed system or local exhaust ventilation. Provide safety shower and eye wash station near work area. PERSONAL PROTECTIVE EQUIPMENT Respiratory protection : Dust respirator. Hand protection : Protective gloves. Eye protection : Safety glasses, goggles. Skin and body protection : Safety helmet, protective clothing, safety shoes. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE : Solid. APPEARANCE : Clear to white pellet. ODOR : Odorless or polyolefin odor. ph : Not applicable. BOILING POINT MELTING POINT VICAT SOFTENING POINT : < 50 o C 1) FLASH POINT : > 200 o C 1) AUTOIGNITION TEMPERATURE FLAMMABLE LIMITS VAPOR PRESSURE VAPOR DENSITY SPECIFIC GRAVITY : ) SOLUBILITY : Insoluble in water. 1) Log Pow DECOMPOSITION TEMPERATURE 10. STABILITY AND REACTIVITY STABILITY : Stable under normal storage and handling. HAZARDOUS REACTIONS : Dust may be ignited by static electricity or other sources of ignition. CONDITIONS TO AVOID : Heat, moisture, sunlight. MATERIALS TO AVOID : Strong oxidizing material, reducers, etc. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides.

6 January 29, 2013 SDS No. P110215E-5 6 / TOXICOLOGICAL INFORMATION ACUTE TOXICITY: Oral LD 50 >2000 mg/kg(calculated value)[not classified] Skin LD 50 >2000 mg/kg(calculated value)[not classified] Inhalation Not available. SKIN CORROSION/IRRITATION SERIOUS EYE DAMAGE/EYE IRRITATION RESPIRATORY SENSITIZATION SKIN SENSITIZATION GERM CELL MUTAGENICITY CARCINOGENICITY REPRODUCTIVE TOXICITY SPECIFIC TARGET ORGAN TOXICITY: Single Exposure Repeated Exposure ASPIRATION HAZARD 12. ECOLOGICAL INFORMATION HAZARDOUS TO THE AQUATIC ENVIRONMENT (ACUTE): Not available. HAZARDOUS TO THE AQUATIC ENVIRONMENT (CHRONIC): Not available. 13. DISPOSAL CONSIDERATIONS WASTE FROM RESIDUES: Whatever cannot be saved for recovery may be burned in an approved incinerator or disposed in approved waste facility. Ensure compliance with local, state, federal and national regulations. CONTAMINATED PACKAGING: Empty the container completely before disposal.

7 January 29, 2013 SDS No. P110215E-5 7 / TRANSPORT INFORMATION UN number UN class : None. : Not regulated. 15. REGULATORY INFORMATION INVENTORY STATUS X: All components of this product comply with the inventory requirements administered by the governing country(s). United States : TSCA Inventory [X] European Union : EINECS [X] ELINCS [ ] NLP [ ] Australia : AICS [X] Canada : DSL [X] NDSL [ ] China : IECSC [X] Japan : ENCS [X] Korea : KECI [X] New Zealand : NZIoC [X] Philippine : PICCS [X] 16. OTHER INFORMATION References: 1) Typical In-house data Classification system: Classification according to JIS Z 7252:2009/SS586 Classification of chemicals based on Globally Harmonized System of Classification and Labeling of Chemicals (GHS). To the best of our knowledge, the information contained herein is accurate at the time of preparation. However, we cannot assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.