BLUESIL RTV 147 A Version: 4.1 Revision date: SAFETY DATA SHEET

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: Product name: BLUESIL RTV 147 A Synonyms, Trade Names: RHODORSIL RTV 147 A Relevant identified uses of the substance or mixture and uses advised against: Identified uses: Moulding diverse objects. Uses advised against: None known. Details of the supplier of the safety data sheet: Manufacturer: BLUESTAR SILICONES Usines Rhône-Alpes 1-55 rue des Frères PERRET F SAINT FONS Cedex Telephone: +33 (0) Fax: +33 (0) fds.sil@bluestarsilicones.com Supplier: Bluestar Silicones (UK) Ltd Wolfe Mead, Farnham Road UK-GU35 0NH Bordon Telephone: +44 (0) Emergency telephone number: +44 (0) SECTION 2: Hazards identification Classification of the substance or mixture: The product has been classified according to the legislation in force. Classification according to Directive 67/548/EEC or 1999/45/EC as amended: Xn; R48/20 Hazard summary: Physical hazards: Health hazards: Inhalation: Eye contact: Skin contact: Ingestion: Other Health Effects: Environmental hazards: Combustible. Quartz : When encapsulated in polymer, it is not expected to pose a health hazard when processed under normal conditions of use. No specific symptoms noted. No specific symptoms noted. No specific symptoms noted. No other information noted. Not regarded as dangerous for the environment. SDS_GB 1/8

2 Label elements: Although classified according to EC criteria, this product is exempt from labelling according to article 23 and Annex 1 (section ) of regulation (CE) n 1272/2008. Safety data sheet available for professional user on request. Other hazards: SECTION 3: Composition/information on ingredients Mixtures: General information: Mixture of Polyorganosiloxanes, fillers, additives. Chemical name Concentration CAS-No. EC No. REACH Notes Registration No. Quartz (SiO2) <35% # Calcium carbonate <5% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has workplace exposure limit(s). PBT: persistent, bioaccumulative and toxic substance. vpvb: very persistent and very bioaccumulative substance. Classification: Chemical name Classification Notes Quartz (SiO2) DPD: Xn; R48/20 CLP: STOT RE 1;H372 Calcium carbonate DPD: Xi; R36 DPD: Directive 67/548/EEC. CLP: Regulation No. 1272/2008.: The full text for all R/H-phrases is displayed in section 16. SECTION 4: First aid measures # General: Get medical attention if symptoms occur. Contaminated clothing to be placed in closed container until disposal or decontamination. Description of first aid measures: Inhalation: Not relevant. Eye contact: Skin contact: Ingestion: Most important symptoms and effects, both acute and delayed: In the event of contact with the eyes, rinse thoroughly with clean water. Continue to rinse for at least 15 minutes. Remove contaminated clothing and shoes. Wash with soap and water. Do not induce vomiting. Rinse mouth thoroughly. None known. Indication of any immediate medical attention and special treatment needed: Hazards: No specific recommendations. Treatment: No specific recommendations. SECTION 5: Firefighting measures General fire hazards: No specific recommendations. SDS_GB 2/8

3 Extinguishing media: Suitable extinguishing media: Unsuitable extinguishing media: Special hazards arising from the substance or mixture: Advice for firefighters: Special Fire Fighting Procedures: Special protective equipment for fire-fighters: Extinguish with foam, carbon dioxide or dry powder. Water spray. None known. Combustible. For further information, refer to section 10: "Stability and Reactivity". Water spray should be used to cool containers. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Environmental precautions: Methods and material for containment and cleaning up: Notification Procedures: Use personal protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Collect spillage. Do not discharge into drains, water courses or onto the ground. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Container must be kept tightly closed. Absorb with sand or other inert absorbent. To clean the floor and all objects contaminated by this material, use an appropriate solvent.(cf. : 9) Flush area with plenty of water. Incinerate in suitable combustion chamber. Caution: Contaminated surfaces may be slippery. For waste disposal, see section 13 of the MSDS. SECTION 7: Handling and storage: Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Specific end use(s): No specific precautions. No special storage precautions noted. Material is stable under normal conditions. Avoid contact with oxidizing agents. Suitable containers: polyethylene. Plastic lined steel drum. No specific recommendations. SECTION 8: Exposure controls/personal protection Control parameters: Occupational exposure limits: Exposure controls: Appropriate engineering controls: Quartz : When encapsulated in polymer, it is not expected to pose a health hazard when processed under normal conditions of use. No special precautions. Individual protection measures, such as personal protective equipment: General information: Eye/face protection: No specific precautions. Safety Glasses SDS_GB 3/8

4 Skin protection: Hand protection: Other: Respiratory Protection: Hygiene measures: Environmental Controls: Use protective gloves made of: Nitrile. Polyvinyl chloride (PVC). Rubber or plastic. No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. No specific precautions. Provide eyewash station and safety shower. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance: Physical State: Liquid Form: Viscous. Color: Beige. Odor: Faint Odor Threshold: ph: Not applicable Freezing point: Boiling Point: Flash Point: 280 C (Closed cup according to method Afnor T ) Evaporation Rate: Flammability (solid, gas): Flammability Limit - Upper (%) : Flammability Limit - Lower (%) : Vapor pressure: Vapor density (air=1): Relative density: Approximate 1,24 (20 C) Solubility(ies): Solubility in Water: Practically Insoluble Solubility (other): Acetone.: Very slightly soluble. Alcohol: Very slightly soluble. Diethylether.: Dispersible Aliphatic hydrocarbons.: Dispersible Aromatic hydrocarbons.: Dispersible Chlorinated solvents.: Dispersible Partition coefficient (n-octanol/water): Autoignition Temperature: Decomposition Temperature: Viscosity: Approximate mm2/s (25 C) Explosive properties: Oxidizing properties: According to the data on the components Not considered as oxidizing. (evaluation by structure-activity relationship) SDS_GB 4/8

5 SECTION 10: Stability and reactivity Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible materials: Hazardous decomposition products: Not relevant. Stable No other information noted. Strong oxidizing agents. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. Amorphous silica. SECTION 11: Toxicological information Information on likely routes of exposure Inhalation: Ingestion: Skin contact: Eye contact: Information on toxicological effects: Acute Toxicity: Oral: Dermal: Specified substance(s): Quartz (SiO2) Calcium carbonate Inhalation: Repeated dose toxicity: Skin corrosion/irritation: Serious eye damage/eye irritation: Respiratory or skin sensitization: SDS_GB 5/8

6 Germ cell mutagenicity: In vitro: In vivo: Carcinogenicity: Reproductive toxicity: Specific target organ toxicity - single exposure: Specific target organ toxicity - repeated exposure: Aspiration hazard: Other adverse effects: None known. SECTION 12: Ecological information Toxicity: Acute toxicity: Fish: Aquatic invertebrates: Chronic Toxicity: Fish: Aquatic invertebrates: Toxicity to Aquatic Plants: Persistence and degradability: Biodegradation: BOD/COD ratio: Specified substance(s): Quartz (SiO2) Calcium carbonate Not applicable Bioaccumulative potential: Specified substance(s): SDS_GB 6/8

7 Quartz (SiO2) Calcium carbonate Mobility in soil: Known or predicted distribution to environmental compartments: Quartz (SiO2) Calcium carbonate Results of PBT and vpvb assessment: Other adverse effects: None Reported None known. SECTION 13: Disposal considerations Waste treatment methods: General information: Disposal Methods: The user's attention is drawn to the possible existence of local regulations regarding disposal. Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Incinerate in suitable combustion chamber. Contaminated packages should be as empty as possible. Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Recycle following cleaning or dispose of at an authorised site. European Waste Codes: SECTION 14: Transport information This material is not subject to transport regulations. Environmental hazards: Special precautions for user: Not regulated. No special precautions. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: National Regulations: Chemical safety assessment: SECTION 16: Other information Revision Information: Key literature references and sources for data: Not relevant. Wording of the R-phrases and H-statements in section 2 and 3: H372 Causes damage to organs through prolonged or repeated exposure. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R36 Irritating to eyes. SDS_GB 7/8

8 Training information: Inventory Status Australia AICS: Canada DSL Inventory List: EU EINECS List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Issue Date: SDS No: Disclaimer: The information given is based on data available for the material, the components of the material, and similar materials. The information is believed to be correct. It is given in good faith. This information should be used to make an independent determination of the methods to safeguard workers and the environment. SDS_GB 8/8