BLUESIL WR 68 Version: 6.0 Revision date: SAFETY DATA SHEET
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1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: Product name: BLUESIL WR 68 Synonyms, Trade Names: RHODORSIL HYDROFUGEANT 68 Additional identification: Chemical name: Siloxanes and Silicones, Me hydrogen, Me group-terminated CAS-No.: Relevant identified uses of the substance or mixture and uses advised against: Identified uses: Non-stick coating. Uses advised against: None known. Details of the supplier of the safety data sheet: Manufacturer: BLUESTAR SILICONES Usines Rhône-Alpes 1-55 rue des Frères PERRET F SAINT FONS Cedex Telephone: +33 (0) Fax: +33 (0) fds.sil@bluestarsilicones.com Supplier: Bluestar Siliconi Italia S.P.A. via Archimede, 602 I Caronno Pertusella Telephone: +39 (02) Fax: +39 (02) Emergency telephone number: + 33 (0) SECTION 2: Hazards identification Classification of the substance or mixture: The product has not been classified as hazardous according to the legislation in force. Hazard summary: Physical hazards: Health hazards: Inhalation: Eye contact: Skin contact: Ingestion: Other Health Effects: Combustible liquid. Chemical compounds containing silicon - hydrogen bonds (SiH). During Storage, This product may generate hydrogen gas. For further information, refer to section 10: "Stability and Reactivity". No specific symptoms noted. Slightly irritating. No specific symptoms noted. No specific symptoms noted. No other information noted. SDS_IT 1/8
2 Environmental hazards: Not regarded as dangerous for the environment. Label elements: The product does not need to be labeled in accordance with EC directives or respective national laws. Other hazards: SECTION 3: Composition/information on ingredients Substances: General information: INDEX No.: - CAS-No.: EC No.: - REACH Registration No.: Purity: Synonyms: - SECTION 4: First aid measures General: Get medical attention if symptoms occur. Contaminated clothing to be placed in closed container until disposal or decontamination. Description of first aid measures: Inhalation: Not relevant. Eye contact: Skin contact: Ingestion: Most important symptoms and effects, both acute and delayed: In the event of contact with the eyes, rinse thoroughly with clean water. Continue to rinse for at least 15 minutes. Remove contaminated clothing and shoes. Wash contact areas with soap and water. Do not induce vomiting. Rinse mouth thoroughly. None known. Indication of any immediate medical attention and special treatment needed: Hazards: Treatment: SECTION 5: Firefighting measures General fire hazards: Extinguishing media: Suitable extinguishing media: Unsuitable extinguishing media: Special hazards arising from the substance or mixture: Foam. Powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Alkaline powders. Combustible liquid. This product may generate hydrogen gas. For further information, refer to section 10: "Stability and Reactivity". Advice for firefighters: SDS_IT 2/8
3 Special Fire Fighting Procedures: Special protective equipment for fire-fighters: Water spray should be used to cool containers. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Environmental precautions: Methods and material for containment and cleaning up: Notification Procedures: Eliminate all sources of ignition. Use personal protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Keep away from Alkalis and caustic products. Collect spillage. Do not discharge into drains, water courses or onto the ground. Explosive; mass explosion hazard. Use explosion-proof electrical/ventilating/lighting/ /equipment. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Container must be kept tightly closed. Suitable containers: equipped with a degassing device. Absorb with sand or other inert absorbent. Do NOT use products which are basic. To clean the floor and all objects contaminated by this material, use an appropriate solvent.(cf. : 9) Flush area with plenty of water. Incinerate in suitable combustion chamber. Caution: Contaminated surfaces may be slippery. For waste disposal, see section 13 of the MSDS. SECTION 7: Handling and storage: Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Specific end use(s): Use mechanical ventilation in case of handling which causes formation of vapors. Provide electrical earthing of equipment and electrical equipment usable in explosive atmospheres. Nitrogen blanketing of containers is required. Ground container and transfer equipment to eliminate static electric sparks. See Section 8 of the MSDS for Personal Protective Equipment. Do not mix with Incompatible materials. For further information, refer to section 10: "Stability and Reactivity". Avoid discharge into drains, water courses or onto the ground. Store in original tightly closed container. equipped with a degassing device. Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures. Material should be stored under an inert atmosphere. Suitable containers: Steel drums coated with epoxy-resin. SECTION 8: Exposure controls/personal protection Control parameters: Occupational exposure limits: Exposure controls: Appropriate engineering controls: None of the components have assigned exposure limits. Individual protection measures, such as personal protective equipment: General information: Eye/face protection: No specific precautions. Safety Glasses SDS_IT 3/8
4 Skin protection: Hand protection: Other: Respiratory Protection: Hygiene measures: Environmental Controls: Protective gloves are recommended. Rubber gloves are recommended. It is a good industrial hygiene practice to minimize skin contact. Wear suitable protective clothing. Provide sufficient ventilation during operations which cause vapor formation. If ventilation is insufficient, suitable respiratory protection must be provided. Self-contained breathing apparatus. Provide eyewash station and safety shower. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance: Physical State: Form: Color: Odor: Odor Threshold: ph: Freezing point: Boiling Point: Flash Point: Evaporation Rate: Flammability (solid, gas): Flammability Limit - Upper (%) : Flammability Limit - Lower (%) : Vapor pressure: Vapor density (air=1): Relative density: Solubility(ies): Solubility in Water: Solubility (other): Partition coefficient (n-octanol/water): Autoignition Temperature: Decomposition Temperature: Viscosity: Explosive properties: Oxidizing properties: Liquid Viscous. Colourless. Faint Not applicable C (Closed cup according to method Afnor T ) 74 %(V) Hydrogen. 4 %(V) Hydrogen. < 0,1 hpa (20 C) 0,99 (20 C) Approximate Practically Insoluble Acetone.: Miscible (in all proportions). Ethanol.: Miscible (in all proportions). Diethylether.: Miscible (in all proportions). Aliphatic hydrocarbons.: Miscible (in all proportions). Aromatic hydrocarbons.: Miscible (in all proportions). Chlorinated solvents.: Miscible (in all proportions). 400 C Hydrogen. Approximate 25 mm2/s (25 C) According to the data on the components Not considered as oxidizing. (evaluation by structure-activity relationship) SDS_IT 4/8
5 SECTION 10: Stability and reactivity Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible materials: Hazardous decomposition products: No other information noted. Stable During Storage, This product may generate hydrogen gas. No other information noted. Strong oxidizing agents. A fire or explosion hazard arises since highly flammable gas (hydrogen) is released when it is in contact with : Alkalis and caustic products. Chemical compounds with mobile hydrogen, in the presence of metal salts and complexes. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. Amorphous silica. Quantity of hydrogen potentially released (l/kg of product): < 375 SECTION 11: Toxicological information Information on likely routes of exposure Inhalation: Ingestion: Skin contact: Eye contact: Information on toxicological effects: Acute Toxicity: Oral: Dermal: LD 50 (Rat): > mg/kg Inhalation: Repeated dose toxicity: Skin corrosion/irritation: Serious eye damage/eye irritation: SDS_IT 5/8
6 Respiratory or skin sensitization: (Guinea Pig): Not a skin sensitizer. Germ cell mutagenicity: In vitro: In vivo: Bacteria : No mutagenic components identified Carcinogenicity: Reproductive toxicity: Specific target organ toxicity - single exposure: Specific target organ toxicity - repeated exposure: Aspiration hazard: Other adverse effects: SECTION 12: Ecological information Toxicity: Acute toxicity: Fish: Aquatic invertebrates: Chronic Toxicity: Fish: Aquatic invertebrates: SDS_IT 6/8
7 Toxicity to Aquatic Plants: Persistence and degradability: Biodegradation: BOD/COD ratio: The product is not biodegradable. Bioaccumulative potential: Mobility in soil: The product is not bioaccumulating. Known or predicted distribution to environmental compartments: Results of PBT and vpvb assessment: Other adverse effects: SECTION 13: Disposal considerations Waste treatment methods: General information: Disposal Methods: The user's attention is drawn to the possible existence of local regulations regarding disposal. Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Incinerate. European Waste Codes: Unused product: SECTION 14: Transport information This material is not subject to transport regulations. Environmental hazards: Not regulated. Contaminated packages should be as empty as possible. Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Recycle following cleaning or dispose of at an authorised site. Special precautions for user: Transport by air is FORBIDDEN if the packaging has a breathing/venting bung. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: EU Regulations: SDS_IT 7/8
8 Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: None Regulation (EC) No. 850/2004 on persistent organic pollutants: None Regulation (EC) No. 689/2008 Import and export of dangerous chemicals: None Regulation (EC) No. 1907/2006 Annex XIV Substance subject to authorisation: None Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use: None Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work: None Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breast feeding.: None Directive 96/61/EC: concerning integrated pollution prevention and control (IPPC): Article 15, European Pollution Emission Registry (EPER): None Directive 96/82/EC (Seveso II): on the control of major accident hazards involving dangerous substances: None Directive 98/24/EC on the protection of workers from the risks related to chemical agents at work. from the risks related to chemical agents at work.: None National Regulations: Chemical safety assessment: SECTION 16: Other information Revision Information: Key literature references and sources for data: Not relevant. Wording of the R-phrases and H-statements in section 2 and 3: None Training information: Inventory Status Australia AICS: Canada DSL Inventory List: EU EINECS List: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Not in compliance with the inventory. Not in compliance with the inventory. Issue Date: SDS No: Disclaimer: The information given is based on data available for the material, the components of the material, and similar materials. The information is believed to be correct. It is given in good faith. This information should be used to make an independent determination of the methods to safeguard workers and the environment. SDS_IT 8/8
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