SAFETY DATA SHEET Nitoflor FC150 Hardener

Transcription

1 Revision Date: 21 November 2012 Revision: 1 SAFETY DATA SHEET Nitoflor FC150 Hardener SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Name Nitoflor FC150 Hardener 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Hardener component of two part epoxy system 1.3. Details of the supplier of the safety data sheet Supplier: 1.4. Emergency telephone number FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3TL Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Environment Xn;R20/22. C;R34. R43. R52/53. The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Contains: Labelling BENZYL ALCOHOL ISOPHORONEDIAMINE m-xylylenediamine 1,3-BENZENEDIMETHANAMINE POLYMER WITH BISPHENOL-A-EPICHLORHYDRIN MW<700 Risk Phrases Safety Phrases Corrosive Harmful R20/22 Harmful by inhalation and if swallowed. R34 R43 Causes burns. May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S25 S26 Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 1 / 8

2 S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S51 Use only in well-ventilated areas. S60 This material and its container must be disposed of as hazardous waste. P5 Contains epoxy constituents. See information supplied by the manufacturer Other hazards This product does not contain any PBT or vpvb Substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures BENZYL ALCOHOL 30-60% CAS-No.: EC No.: Registration Number: xxxx Acute Tox. 4 - H332 Xn;R20/22 ISOPHORONEDIAMINE 10-30% CAS-No.: EC No.: Registration Number: xxxx Acute Tox. 4 - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 C;R34 Xn;R21/22 R43 R52/53 m-xylylenediamine 10-30% CAS-No.: EC No.: Registration Number: xxxx Acute Tox. 4 - H332 Skin Corr. 1B - H314 Aquatic Chronic 3 - H412 Xn;R20/22. C;R34. R52/53. SALICYLIC ACID 1-5% CAS-No.: EC No.: Skin Irrit. 2 - H315 Eye Dam. 1 - H318 STOT Single 3 - H335 Xn;R22. Xi;R41,R37/38. 2 / 8

3 1,3-BENZENEDIMETHANAMINE POLYMER WITH BISPHENOL-A-EPICHLORHYDRIN MW< % CAS-No.: EC No.: Skin Corr. 1A - H314 Skin Sens. 1 - H317 Xn;R22. C;R35. R43. The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General Information Immediately remove any clothing soiled by the product. Inhalation. Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Ingestion DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Remove victim immediately from source of exposure. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Get medical attention immediately! Provide rest, warmth and fresh air. Skin Contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing. Eye Contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed General Information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Ingestion May cause chemical burns in mouth and throat. Skin Contact Chemical burns. Eye Contact Corneal damage Indication of any immediate medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing Media Extinguish with foam, carbon dioxide, dry powder or water fog. Unsuitable Extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous Combustion Products When heated, toxic and corrosive vapours/gases may be formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. 3 / 8

4 Specific Hazards Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx) Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. Protective Measures In Fire Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not allow ANY environmental contamination Methods and material for containment and cleaning up Ventilate well. Wear necessary protective equipment. Stop leak if possible without risk. DO NOT touch spilled material! Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer Reference to other sections For personal protection, see section 8. Collect and dispose of spillage as indicated in section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Corrosive storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes m-xylylenediamine WEL WEL = Workplace Exposure Limit. Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective Equipment Engineering Measures Provide adequate general and local exhaust ventilation. Respiratory Equipment If ventilation is insufficient, suitable respiratory protection must be provided. It is recommended to use respiratory equipment with combination filter, type A2/P2. 4 / 8

5 Hand Protection Use protective gloves. Viton rubber (fluor rubber). Nitrile. Eye Protection Use approved safety goggles or face shield. Other Protection Nitoflor FC150 Hardener Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Immediately remove contaminated clothing. Hygiene Measures DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Liquid Yellow Amine. Initial Boiling Point and Boiling >200 C Range: Relative Density C Immiscible with water Vapour Pressure 0.01 kpa 20 C Viscosity 200 mpas 25 C Flash Point ( C) >100 C Auto Ignition Temperature ( C) 380 C Flammability Limit - Lower(%) 1.2 Flammability Limit - Upper(%) Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Acids. Alkalis. Oxidising materials Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Reaction with: Acids. Alkalis. Oxidising materials. Hazardous Polymerisation Will not polymerise Conditions to avoid No further relevant information available Incompatible materials Materials To Avoid Strong oxidising substances Hazardous decomposition products When heated, toxic and corrosive vapours/gases may be formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation Harmful by inhalation. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. 5 / 8

6 Ingestion. Harmful if swallowed. May cause chemical burns in mouth, oesophagus and stomach. Skin Contact Causes burns. Harmful in contact with skin. May cause sensitisation by skin contact. Eye Contact Causes burns. Target Organs Skin Eyes Respiratory system, lungs SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment Toxicity Acute Fish Toxicity Ecotoxic to fish/daphnia/algae Persistence and degradability Degradability: There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative Potential: No data available on bioaccumulation Mobility in soil Mobility: The product is immiscible with water and will sediment in water systems Results of PBT and vpvb assessment This product does not contain any PBT or vpvb Substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General Information When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Incinerate in suitable combustion chamber. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 2735 UN No. (IMDG) 2735 UN No. (ICAO) UN Proper shipping name Proper Shipping Name AMINES, LIQUID, CORROSIVE, N.O.S. (ISOPHORONEDIAMINE) 14.3 Transport hazard class(es) ADR/RID/ADN Class Class 8: Corrosive substances. ADR Label No. 8 IMDG Class 8 ICAO Class/Division 8 Transport Labels 6 / 8

7 14.4. Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group II II II Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user IMDG Code Segregation Group 18. Alkalis EMS F-A, S-B Emergency Action Code 2X Hazard No. (ADR) 80 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not relevant. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. National Regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations No Workplace Exposure Limits 2005 (EH40) Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION General Information The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. Revision Comments This is first issue. Revision Date 21 November 2012 Revision 1 7 / 8

8 Risk Phrases In Full R34 R35 R20/22 R22 R21/22 R52/53 R37/38 R43 R41 Hazard Statements In Full H318 H314 H315 H332 H302 H312 H412 H317 H335 Nitoflor FC150 Hardener Causes burns. Causes severe burns. Harmful by inhalation and if swallowed. Harmful if swallowed. Harmful in contact with skin and if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system and skin. May cause sensitisation by skin contact. Risk of serious damage to eyes. Causes serious eye damage. Causes severe skin burns and eye damage. Causes skin irritation. Harmful if inhaled. Harmful if swallowed. Harmful in contact with skin. Harmful to aquatic life with long lasting effects. May cause an allergic skin reaction. May cause respiratory irritation. Disclaimer The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 8 / 8