SAFETY DATA SHEET LIQUID HARDENER.

Transcription

1 Revision Date 11/08/2011 Revision 11 Supersedes date 08/06/2011 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. X Relevant identified uses of the substance or mixture and uses advised against Identified uses Hardener Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number +44 (0) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture ITW DEVCON BAY 150 SHANNON INDUSTRIAL ESTATE SHANNON CO CLARE IRELAND T: +353 (0) F: 353(0) Classification (1999/45/EEC) Xn;R21. C;R34.. N;R51/ Label elements Contains Labelling NONYL PHENOL TRIETHYLENETETRAMINE Risk Phrases Safety Phrases 2.3. Other hazards Corrosive Harmful Dangerous for the environment R21 R34 Harmful in contact with skin. Causes burns. May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S26 S45 S36/37/39 S61 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Wear suitable protective clothing, gloves and eye/face protection. Avoid release to the environment. Refer to special instructions/safety data sheets. 1 / 7

2 This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 2-PIPERAZIN-1-YLETHYLAMINE 1-10% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Classification (67/548/EEC) C;R34 Xn;R21/22 R52/53 NONYL PHENOL 1-10% CAS-No.: EC No.: Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Xn;R22. C;R34. N;R50/53. TRIETHYLENETETRAMINE 30-60% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Classification (67/548/EEC) C;R34 Xn;R21 R52/53 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Do not breathe vapour/spray. Avoid contact with eyes. Inhalation Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Contact physician if discomfort continues. Ingestion Do not induce vomiting. Drink plenty of water. Get medical attention. Skin contact Remove affected person from source of contamination. Wash skin thoroughly with soap and water for several minutes. Contact physician if irritation persists. Eye contact Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. Contact physician if irritation persists Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure Indication of any immediate medical attention and special treatment needed 2 / 7

3 No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Fire can be extinguished using: Water. Foam, carbon dioxide or dry powder Special hazards arising from the substance or mixture Specific hazards Avoid breathing fire vapours Advice for firefighters Special Fire Fighting Procedures Keep up-wind to avoid fumes. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-figthers Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate ventilation Environmental precautions Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. Containers with collected spillage must be properly labelled with correct contents and hazard symbol Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Use only in well-ventilated areas. Avoid contact with skin and eyes. Avoid eating, drinking and smoking when using the product. Do not use in confined spaces without adequate ventilation and/or respirator. Do not eat, drink or smoke when using the product Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Process conditions Provide eyewash, quick drench. 3 / 7

4 Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment If ventilation is insufficient, suitable respiratory protection must be provided. Hand protection Use protective gloves made of: Rubber or plastic. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Hygiene measures Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before leaving work place. Skin protection Avoid contact with skin. Wear apron or protective clothing in case of contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Amber. Odour Amine. Solubility Soluble in water. Initial boiling point and boiling range 232 Melting point ( C) n/a Relative density ºC Vapour density (air=1) >1 Vapour pressure <10mmHg 21.1 Evaporation rate <<1 (butyl acetate =1) ph-value, Conc. Solution 20 ºC Flash point ( C) > Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity Strong oxidising agents. Acids Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not available Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time. Avoid exposure to high temperatures or direct sunlight Incompatible materials Materials To Avoid Avoid contact with oxidising agents. Avoid contact with acids Hazardous decomposition products Fire or high temperatures create: Nitrous gases (NOx). Oxides of: Carbon monoxide (CO). Carbon dioxide (CO2). Vapours/gases/fumes of: Ammonia or amines. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxic Dose 1 - LD 50 2, 000 mg/kg (oral rat) Ingestion Corrosive. Even small amounts may cause serious damage. 4 / 7

5 Skin contact Causes burns. Corrosive. Prolonged contact causes serious tissue damage. May be absorbed through the skin. May cause sensitisation by skin contact. Risk of sensitisation or allergic reactions among sensitive individuals. Eye contact Causes burns. Risk of serious damage to eyes. Health Warnings This substance is corrosive. This chemical may cause skin/eye irritation and burns (corrosive). Route of entry Inhalation. Skin absorption. Ingestion. Target Organs Prolonged or repeated exposure may cause: May cause damage to the liver and kidneys. Respiratory system, lungs Central nervous system Name Toxic Dose 1 - LD 50 2-PIPERAZIN-1-YLETHYLAMINE mg/kg (oral rat) SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Avoid releasing to the environment. The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment Toxicity Acute Fish Toxicity Very toxic to aquatic organisms Persistence and degradability Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: Do not discharge into drains, water courses or onto the ground Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not available. SECTION 13: DISPOSAL CONSIDERATIONS General information When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Waste Class SECTION 14: TRANSPORT INFORMATION General No other information noted UN number UN No. (ADR/RID/ADN) 2735 UN No. (IMDG) 2735 UN No. (ICAO) UN proper shipping name Proper Shipping Name AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S (TRIETHYLENETETRAMINE, NONYL PHENOL) 5 / 7

6 14.3. Transport hazard class(es) ADR/RID/ADN Class 8 ADR/RID/ADN Class Class 8: Corrosive substances. ADR Label No. 8 IMDG Class 8 ICAO Class/Division 8 Transport Labels CORROSIVE Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group II II II Environmental hazards Environmentally Hazardous Substance/Marine Pollutant Special precautions for user EMS Emergency Action Code F-A, S-B 2X Hazard No. (ADR) 80 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No information required. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Water hazard classification WGK Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date 11/08/2011 Revision 11 Supersedes date 08/06/2011 Date 21/07/ / 7

7 Risk Phrases In Full R34 R22 R21/22 R21 R52/53 R50/53 Hazard Statements In Full H302 H312 H314 H317 H412 Causes burns. Harmful if swallowed. Harmful in contact with skin and if swallowed. Harmful in contact with skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause sensitisation by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful to aquatic life with long lasting effects. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 7 / 7