NON HAZARDOUS INGREDIENTS HELD AS TRADE SECRETS

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1 MATERIAL SAFETY DATA SHEET Zircon Industries, Inc Commerce Parkway #9 Cleveland, OH (216) phone (800) emergency RDS38 SECTION I Product Identity RDS38 Road Dust Stabilizer Chemical Family: inorganic Salt RTECS Number: EV Revision Date: 4/01/2014 SECTION II Ingredients Water Calcium Chloride Additives Ingredients CAS 62-64% 36-38% NON HAZARDOUS INGREDIENTS HELD AS TRADE SECRETS SECTION 111 NFPA Ratings (Scale 0-4): Hazard Identification Health = 1 Fire = 0 Reactivity = 0 Emergency Overview: Odorless liquid, colorless to light yellow. May cause skin and eye irritation. Avoid repeated or prolonged contact with eyes, skin, and clothing. Keep container tightly closed. Wash thoroughly after handling. Use only with adequate ventilation. Potential Health Effects: Inhalation: Short term effects: May cause irritation Skin contact: Eye contact: Ingestion: Long term effects: May cause perforation ofthe nose and bleed Short term effects: May cause irritation, possibly severe Long term effects: Same effects as short term exposure Short term effects: May cause irritation. Additional effects may include tearing Long term effects: Same effects as short term exposure Short term effects: May cause nausea

Page 2 SECTION IV Inhalation: Skin contact: Eye contact: Ingestion: First Aid Measures Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration.

2 Page 2 SECTION IV Inhalation: Skin contact: Eye contact: Ingestion: First Aid Measures Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately. Remove contaminated clothing and shoes immediately. Wash affected area with soap or mild detergent and large amounts ofwater until no evidence of chemical remains (at least minutes). In case of burns, cover area with sterile, dry dressing. Bandage securely, but not too tightly. Get medical attention immediately. Wash eyes immediatelywith large amounts ofwater or normal saline solution, occasionally lifting upper and lower lids until no evidence of chemical remains (approximately minutes). Get medical attention immediately. Treat symptomatically and supportively. Get medical attention immediately. If vomiting occurs, keep head lower than hips to prevent aspiration. NOTE TO PHYSICIANS: Antidote - no specific antidote. Treat symptomatically and supportively. SECTION V Fire Fighting Measures Fire and Explosion Hazard: Negligible fire hazard when exposed to heat or flame. Extinguishing Media: Dry chemical, carbon dioxide, water spray or regular foam. For larger fires, use water spray, fog or regular foam. Firefighting: Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends oftanks. Extinguish fire using agent suitable for type of surrounding fire. Cool containers with flooding amounts of water from as far a distance as possible. Avoid breathing corrosive vapors; keep upwind. SECTION VI Accidental Release Measures Occupational spill: Do not touch spilled material. Stop leak if you can do it without risk. For small spills, take up with sand or other absorbent material and place into containers for later disposal. Keep unnecessary people away. Isolate hazard area and deny entry.

3 Page 3 Soil spill: Dig holding area such as lagoon, pond or pit for containment. Dike flow of spilled material using soil or sandbags or foamed barriers such as polyurethane or concrete. Use cement powder or fly ash to absorb liquid mass. Neutralize spill with slaked lime, sodium bicarbonate or crushed limestone. Water spill: Neutralize with agricultural lime, slaked lime, crushed limestone, or sodium bicarbonate. Use mechanical dredges or lifts to extract immobilized masses of pollution and precipitates. Add suitable agent to neutralize spilled material to ph-7. SECTION VII Handling and Storage Observe all federal, state and local regulations when storing this substance. Store in a tightly closed container. Store away from incompatible substances. SECTION VIII Exposure Controls, Personal Protection No occupational exposure limits established by OSHA/ACGIH/NIOSH. Ventilation: Provide local exhaust ventilation system. Eye Protection: Employee must wear safety glasses with splash shields or safety goggles to prevent contact with this substance. Emergency Wash Facilities: Where there is any possibility that an employee's eyes and/or skin may be exposed to this substance, the employer should provide an eye wash fountain and quick drench shower within the immediate work area for emergency use. Clothing: Employee must wear appropriate protective (impervious) clothing and equipment to prevent repeated or prolonged skin contact with this substance. Gloves: Employee must wear appropriate protective gloves, such as rubberized or latex coated canvas gauntlets, to prevent contact with this substance.

Page 4 Respirator: The following respirators are recommended based on information found in the physical data, toxicity and health effects sections.

4 Page 4 Respirator: The following respirators are recommended based on information found in the physical data, toxicity and health effects sections. They are ranked in order from minimum to maximum respiratory protection. The specific respirator selected must be based on contamination levels found in the work place, must be based on the specific operation, must be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH/MSHA). Mist respirator with a full face piece. Any air purifying full face piece respirator with a high efficiency particulate filter. Any powered air purifying respirator with a tight fitting face piece and high efficiency particulate filter. Any type 'C supplied air respirator with a full face piece operated in pressure demand or other positive pressure mode or with a full face piece, helmet or hood operated in continuous flow mode. Any self contained breathing apparatus with a full face piece operated in pressure demand or other positive pressure mode. For Fire Fighting and other immediately dangerous to Life or Health conditions: Any self contained breathing apparatus that has a full face piece and is operated in a pressure demand or other positive pressure mode. Any supplied air respirator that has a full face piece and is operated in a pressure demand or other positive pressure mode in combination with an auxiliary self contained breathing apparatus operated in pressure demand or other positive pressure mode. SECTION IX Description: Molecular weight: Boiling point: Melting point: Specific gravity: PH: Water solubility: Solvent solubility: SECTION X Physical and Chemical Properties Odorless, colorless to slightly yellow liquid for pure salt 224 degrees F(118 degrees C) for 38% solution NA degrees C for 38% solution Miscible with water in all proportions Miscible in alcohol, acetic acid, and acetone Stability and Reactivity Stable under normal temperatures and pressures. Conditions to avoid: Flammable, poisonous gases may accumulate in tanks and hopper cars. Metals: Methyl vinyl ether: Corrosive May initiate exothermic polymerization

5 Page 5 SECTION XI Toxicity data: Toxicological Information Anhydrous Calcium Chloride: TD LO: 112/kg, oral, 20 weeks, rat LD LO: 274 mg/kg, subcutaneous, dog LD 50:1000 mg/kg, oral, rat LD 50:264 mg/kg, intraperitoneal, rat See Registry of Toxic Effects of Chemical Substances (RTLECS) file for mutagenic and tumorigenic data. Local effects: - eye, mucous membrane and skin irritant Health effects - moderately toxic by ingestion. Slightly toxic by dermal absorption. Carcinogen status: OSHA - No NTP-No LARC-No SECTION XII ECOLOGICAL INFORMATION Product will not biodegrade or bioaccumulate. SECTION XIII DISPOSAL INFORMATION Observe all federal, state, and local regulations when disposing ofthis substance. SECTION XIV Shipping name: ID number: Hazard class: Packing group: Labeling: DEPARTMENT OFTRANSPORTATION (DOT) Not regulated Packing Authorizations: Exceptions: Non-bulk pack: Bulk pack: Quantity limitations: Passenger aircraft: Cargo aircraft: Vessel stowage: Emergency guide:

6 Page 6 SECTION XV OSHA safety: SARA Title III: TSCA status: CERCLA: EINECS status: OSHA safety: California #65: WHMIS class: REGULATORY INFORMATION No Section 311: acute hazard Yes No Yes No No ingredients found on the list D2B SECTION XVI OTHER INFORMATION Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. This information relates to the specific product designated and may not be valid for such product used in combination with any other materials or in any other processes. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability, or completeness. It is the users' responsibility to satisfy themselves as to the suitability and completeness of such information for their own particular use. We do not accept liability for any loss or damage that may occur from the use of this information, nor do we offer warranty against patent infringement. Zircon Industries, Inc. reserves the right to refuse shipment of this product to any consumer who fails to demonstrate the ability to consistently handle and use it safely and in compliance with all applicable laws, rules, and regulations. Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling systems that come in contact with it. Customers are responsible for compliance with local, state and federal regulations that may be pertinent in the storage, application, and disposal of this product. s ZIRCON INDUSTRIES, INC. (800)

TETRA Potassium Formate Solid File: MSDS: OG-111

TETRA Potassium Formate Solid File: MSDS: OG-111 SECTION 1: CHEMICAL PRODUCT - COMPANY IDENTIFICATION 25025 IH-45 rth The Woodlands, Texas 77380 (713) 367-1983 (800) 327-7817 (800) 424-9300 - CHEMTREC (24 Hours Emergency Response) SUBSTANCE: Potassium