Safety Data Sheet. 1 Identification of substance. 2 Composition/Data on components. 3 Hazards identification. Page 1/8.
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1 Page 1/8 1 Identification of substance Product details Article Code: ; Application: for laboratory and industrial use Manufacturer/Supplier: HORIBA Instruments (Singapore) Pte Ltd 83 Science Park Drive #02-02A, The Curie, Singapore Contact No.: Composition/Data on components Chemical characterization: Mixture Not a hazardous product according to GHS classification Components: Water >98% Potassium chloride <1% Sodium hydroxide <0.2% 3 Hazards identification Classification US OSHA Hazard Communication Standard (29 CFR ) EU CLP Classification - Regulation (EC) No. 1272/2008 Physical hazards Health hazards Environmental hazards Classification according to EU Directives 67/548/EEC or 1999/45/EC Symbol(s) None R-phrase(s) None For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16 NFPA ratings (scale 0-4) Health = 0 Fire = 0 Reactivity = 0
2 Page 2/8 Label Elements None required Signal Word Hazard Statements Precautionary Statements Other Hazards 4 First Aid Measures Eye Contact Skin Contact Ingestion Inhalation Protection of First-aiders Most Important Symptoms/Effects Notes to Physician Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention if irritation persists. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Move to fresh air. Get medical attention immediately if symptoms occur. No special precautions required. None reasonably foreseeable. Treat symptomatically 5 Firefighting Measures Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing Media Which Must Not be Used for Safety Reasons. Specific Hazards Arising from the Chemical None reasonably foreseeable Hazardous Combustion Products None under normal use conditions Advice for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
3 Page 3/8 6 Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Use personal protective equipment. Environmental Precautions Should not be released into the environment. Methods and Material for Containment and Cleaning Up Sweep up or vacuum up spillage and collect in suitable container for disposal. Reference to Other Sections Refer to protective measures listed in Sections 8 and Handling And Storage Precautions for Safe Handling Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation. Conditions for Safe Storage, Including any Incompatibilities Store at room temperature. Keep container tightly closed. Specific End Uses ph buffer / standard 8 Exposure Controls/Personal Protection Biological Limit Values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies. Monitoring Methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application of exposure to chemical and biological agents. Predicted No Effect Concentration (PNEC). Engineering Measures None under normal use conditions. Personal Protective Equipment Eye & Face Protection Safety glasses with side- Hand Protection Protective gloves Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitization effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.
4 Page 4/8 Skin and body protection Respiratory Protection Wear protective gloves/clothing No protective equipment is needed under normal use conditions. Hygiene Measures Environmental Exposure Controls Handle in accordance with good industrial hygiene and safety practice. 9 Physical And Chemical Properties Appearance Physical State Odor Odor Threshold ph Melting Point/Range Boiling Point/Range Flash Point Evaporation Rate Flammability (solid, gas) Flammability or explosive limits Upper Lower Vapor Pressure Specific Gravity / Density Bulk Density Water Solubility Solubility in other solvents Partition Coefficient (noctanol/water) Clear Liquid None C / 32 F 100 C / 212 F 1.01 Soluble in water Estimated Estimated Method - Liquid (Air = 1.0) Liquid Autoignition Temperature Decomposition temperature Viscosity Explosive Properties Oxidizing Properties Other information Sensitivity to Static Discharge Sensitivity to Mechanical Impact
5 Page 5/8 10 Stability And Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Hazardous Polymerization Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products None known, based on information available Stable under normal conditions. Hazardous polymerization does not occur. None under normal processing. None known None known None under normal use conditions 11 Toxicological Information Acute Toxicity Oral Dermal Inhalation Skin corrosion/irritation Serious Eye Damage/Eye Irritation Respiratory or Skin Sensitization Respiratory Skin Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicity STOT - single exposure Not listed STOT - repeated exposure Target Organs Aspiration hazard Symptoms / effects, both acute and delayed
6 Page 6/8 12 Ecological Information Persistence and Degradability Bioaccumulative Potential Mobility in Soil Results of PBT and vpvb Assessment Other adverse effects Endocrine Disruptor Information Persistent Organic Pollutant Ozone Depletion Potential for assessment This product does not contain any known or suspected endocrine disruptors This product does not contain any known or suspected substance This product does not contain any known or suspected substance 13 Disposal Considerations Waste from Residues / Unused Products Contaminated Packaging Other Information Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use empty containers. Solutions with high ph-value must be neutralized before discharge. Waste codes should be assigned by the user based on the application for which the product was used. 14 Transport Consideration DOT Not regulated UN Number UN proper shipping name Transport Hazard Class(es) Packing Group IMDG/IMO Not regulated UN Number UN proper shipping name Transport Hazard Class(es) Packing Group ADR Not regulated UN Number UN proper shipping name Transport Hazard Class(es) Packing Group
7 Page 7/8 IATA Not regulated UN Number UN proper shipping name Transport Hazard Class(es) Packing Group Environmental hazards No hazards identified Special Precautions for User No special precautions required Transport in Bulk According to Annex II of MARPOL73/78 and the IBC Code, packaged goods Other Information 15 Regulatory Information U.S. Federal Regulations TSCA 12(b) SARA 313 Clean Air Act U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Other International Regulations Canada WHMIS Hazard Class Non-controlled This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Mexico - Grade European Union This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Chemical safety assessment Chemical Safety Assessment/Reports (CSA/CSR) are not required for mixtures
8 Page 8/8 16 Other information HORIBA, Ltd. provides the information contained herein in good faith but makes no representation as to its comprehensives or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. HORIBA, Ltd. MAKES NO REPRESENTATION OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MARCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMOTION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, HORIBA, Ltd. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. Division issuing MSDS: Water Quality Instruments division. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organization ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent
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