: ecement Try-In Paste

Transcription

1 Date of issue: 26/11/2014 Revision date: 01/04/2015 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : ecement Try-In Paste 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer: Bisco, Inc W Irving Park Road, Schaumburg, IL USA , during normal business hours EC Representative: Bisico France, 120, allée de la Coudoulette, Lançon de Provence, France Telephone: Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 Eye Irrit. 2 H315 H319 Resp. Sens. 1 H334 STOT SE 3 H335 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Irritant ; Senstizer : Glass filler GHS08 : H315 - Causes skin irritation H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation : P264 - Wash hands thoroughly after handling P280 - Wear protective gloves, eye protection P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose in a safe manner in accordance with local/national regulations 01/04/2015 EN (English) 1/6

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Glass filler (CAS No) Xi; R36/37/38 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Glass filler (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 STOT SE 3, H335 Full text of R- and H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 01/04/2015 EN (English) 2/6

3 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing mist, vapours. : Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : In case of inadequate ventilation wear respiratory protection. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Tooth colored Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) n flammable Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 01/04/2015 EN (English) 3/6

4 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Glass filler ( ) LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) LC50 inhalation rat (Dust/Mist - mg/l/4h) LC50 inhalation rat (Vapours - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Glass filler ( ) LOAEL (oral, rat) LOAEL (dermal, rat/rabbit) LOAEL (inhalation, rat, gas) LOAEL (inhalation, rat, vapour) LOAEL (inhalation, rat, dust/mist/fume) Specific target organ toxicity (repeated exposure) Glass filler ( ) LOAEL (oral, rat, 90 days) LOAEL (dermal, rat/rabbit, 90 days) LOAEL (inhalation, rat, gas, 90 days) LOAEL (inhalation, rat, vapour, 90 days) LOAEL (inhalation, rat,dust/mist/fume, 90 days) Aspiration hazard Potential adverse human health effects and symptoms : Causes skin irritation. Causes skin irritation : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. : May cause respiratory irritation. mg/kg bodyweight mg/kg bodyweight ppmv/4h mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day : Based on available data, the classification criteria are not met. 01/04/2015 EN (English) 4/6

5 SECTION 12: Ecological information Toxicity Persistence and degradability ecement Try-In Paste Persistence and degradability Bioaccumulative potential ecement Try-In Paste Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment 01/04/2015 EN (English) 5/6

6 Marine pollutant Other information supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Not subject to ADN Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no substance on the REACH candidate list National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Other information ne. Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Resp. Sens. 1 Sensitisation Respiratory, category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation H319 Causes serious eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation R36/37/38 Xi Irritating to eyes, respiratory system and skin Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 01/04/2015 EN (English) 6/6