: CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted
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1 Date of issue: 03/12/2014 Revision date: 01/04/2015 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Biscover LV 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer: Bisco, Inc W Irving Park Road, Schaumburg, IL USA , during normal business hours EC Representative: Bisico France, 120, allée de la Coudoulette, Lançon de Provence, France Telephone: Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Skin Irrit. 2 H315 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS02 : Flammable ; Irritant GHS07 : H225 - Highly flammable liquid and vapour H315 - Causes skin irritation : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P280 - Wear protective gloves, eye protection P370+P378 - In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 01/04/2015 EN (English) 1/6
2 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC ethanol (CAS No) F+; R12 Dipentaerythritol pentaacrylate (CAS No) Xi; R36 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] ethanol (CAS No) Flam. Liq. 2, H225 Dipentaerythritol pentaacrylate (CAS No) Skin Irrit. 2, H315 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Assure fresh air breathing. Allow the victim to rest. : Immediately call a POISON CENTER or doctor/physician. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Obtain medical attention if pain, blinking or redness persist. : Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Causes severe skin burns and eye damage. Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Explosion hazard : Highly flammable liquid and vapour. : May form flammable/explosive vapour-air mixture Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 01/04/2015 EN (English) 2/6
3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Handle empty containers with care because residual vapours are flammable. : Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No naked lights. No smoking. Use only non-sparking tools. : Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof place. Keep container tightly closed. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. Heat sources Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or face shield. Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Highly flammable liquid and vapour Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information 01/04/2015 EN (English) 3/6
4 SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame Incompatible materials Strong acids. Strong bases Hazardous decomposition products Thermal decomposition generates : Corrosive vapours. fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity Persistence and degradability Biscover LV Persistence and degradability Not established Bioaccumulative potential Biscover LV Bioaccumulative potential Not established Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Additional information : Handle empty containers with care because residual vapours are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 01/04/2015 EN (English) 4/6
5 14.1. UN number UN-No. (ADR) : 1170 UN-No. (IMDG) : 1170 UN-No.(IATA) : 1170 UN-No.(ADN) UN-No. (RID) : UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) : ETHANOL (ETHYL ALCOHOL) / ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 3 Hazard labels (ADR) : 3 : IMDG Transport hazard class(es) (IMDG) : 3 IATA Transport hazard class(es) (IATA) : 3 ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) : 3 Danger labels (RID) : 3 : Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : II supplementary information available Special precautions for user Overland transport Classification code (ADR) : F1 Special provisions (ADR) : 144, 601 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 01/04/2015 EN (English) 5/6
6 Vehicle for tank carriage : FL Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) EAC code : D/E : 2YE Transport by sea Air transport Inland waterway transport Not subject to ADN Rail transport Classification code (RID) Carriage prohibited (RID) : F Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no substance on the REACH candidate list National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Other information ne. Full text of R-, H- and EUH-phrases: Flam. Liq. 2 Flammable liquids, Category 2 H225 Highly flammable liquid and vapour SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 01/04/2015 EN (English) 6/6
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