Material Safety Data Sheet

Transcription

1 This Material Safety Data Sheet (MSDS) has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (CFR ). Material Safety Data Sheet Cablelite A Section 1. Chemical product and company identification Product name Supplier Material uses Code Emergency telephone number Emergency overview Cablelite A DSM Desotech Inc St Charles Street Elgin IL Tel +1 (847) UVcurable coatings, inks and matrix materials WW22114 DSM Desotech Inc. +1 (847) (During normal business hours) CHEMTREC (within the USA) (800) (24 hour) CHEMTREC (International) +1 (703) [USA] (24 hour) Section 2. Hazards identification Physical state Odor OSHA/HCS status Hazardous Material Information System (U.S.A.) Potential acute health effects Inhalation Ingestion Skin Eyes Potential chronic health effects Chronic effects Carcinogenicity Liquid. Characteristic. WARNING! MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. Moderately irritating to the eyes, skin and respiratory system. May cause sensitization by skin contact. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Health Flammability Physical hazards PERSONAL PROTECTION The PPE (Personal Protection Equipment) designation in the HMIS is provided for use by employees at supplier sites only. Other users of this product are encouraged to evaluate the hazards of the product and assign PPE that is applicable to their specific situations. Moderately irritating to the respiratory system. No known significant effects or critical hazards. Moderately irritating to the skin. May cause sensitization by skin contact. Moderately irritating to eyes. 1 AG Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. 2 1 No.

2 Cablelite A Page 2/7 Mutagenicity Teratogenicity Developmental effects Fertility effects Medical conditions aggravated by overexposure See toxicological information (Section 11) No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Preexisting skin disorders may be aggravated by overexposure to this product. Section 3. Composition/information on ingredients No. Name CAS number % by weight Multifunctional Acrylate Glycol ether acrylate Multifunctional Acrylate Photoinitiators Additive <0.01 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion Protection of firstaiders Notes to physician Section 5. Firefighting measures Rinse with plenty of running water. Get medical attention if symptoms occur. Take off immediately all contaminated clothing. Wash with soap and water. Get medical attention. If inhaled, remove to fresh air. Get medical attention if symptoms occur. If swallowed, rinse mouth with water (only if the person is conscious). Get medical attention if symptoms occur. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouthtomouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Flammability of the product Hazardous thermal decomposition products Extinguishing media Suitable Special firefighting procedures Protection of firefighters In a fire or if heated, a pressure increase will occur and the container may burst. In case of fire, may produce hazardous decomposition products such as carbon monoxide, carbon dioxide, (dense) black smoke, aldehydes, organic acids, phosphorous oxides. Use water, foam or dry chemical powder. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Wear suitable protective clothing. Selfcontained breathing apparatus.

3 Cablelite A Page 3/7 Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Prevent entry into sewers, basements or confined areas. Dike if necessary. In case of contamination of aquatic environment, inform local authorities. Prevent entry into sewers, basements or confined areas. Dike if necessary. Absorb spill with inert material (e.g. dry sand or earth) and place in a chemical waste container. Recycle, if possible. Avoid release to the environment. This material and its container must be disposed of as hazardous waste. Keep away from sources of ignition. Section 7. Handling and storage Handling Storage Storage temperature Preferably use in closed systems. Use with adequate ventilation. Use suitable protective equipment. Avoid contact with eyes, skin and clothing. Do not allow to enter drains or watercourses. Store in a fireproof location. Keep away from incompatible materials and avoid specific conditions (See section 10). Use appropriate containment to avoid environmental contamination. Store between the following temperatures 15 and 30 C. Section 8. Exposure controls/personal protection Engineering controls Personal protection Eyes Skin Respiratory Hands Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Gas filter mask must be worn. Chemicalresistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Yes. Product name Additive Consult local authorities for acceptable exposure limits. Exposure limits ACGIH TLV (United States, 2/2010). Absorbed through skin. TWA 5 mg/m³ 8 hour(s). OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA 5 mg/m³ 8 hour(s). NIOSH REL (United States, 6/2009). Absorbed through skin. TWA 5 mg/m³ 10 hour(s).

4 Cablelite A Page 4/7 Section 9. Physical and chemical properties Physical state Flash point Color Odor Specific gravity Viscosity Solubility Liquid. Closed cup >93 C (>199.4 F) [Closed cup, ISO 1523] Colorless to Amber. Characteristic Dynamic 8000 to mpa s (8000 to cp) Insoluble in the following materials cold water. Section 10. Stability and reactivity Stability and reactivity Conditions to avoid Materials to avoid Hazardous decomposition products Possibility of hazardous reactions The product is stable. Keep away from heat, sparks and flame. No special recommendations. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. Section 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Glycol ether acrylate LD50 Dermal Rabbit 2540 ul/kg LD50 Oral Rat 4660 ul/kg Multifunctional Acrylate LD50 Dermal Rabbit >2 g/kg LD50 Oral Rat 6200 mg/kg Photoinitiators LD50 Oral Rat >5000 mg/kg Additive LD50 Dermal Rabbit 4000 mg/kg LD50 Oral Mouse 5 g/kg LD50 Oral Rabbit 4 g/kg LD50 Oral Mouse 5000 mg/kg LD50 Oral Rat 2000 mg/kg LC50 Inhalation Dusts and mists Rat > mg/m³ 1 hours Multifunctional acrylate Results from a mouse lymphoma test were positive, indicating that this material may have mutagenic potential. However, an 80 week carcinogenicity study in mice showed no increase of skin or visceral tumors. In addition, an Ames test for mutagenicity was negative. Therefore, there is reason to believe that the mouse lymphoma assay was a false positive Photoinitiator Toxicological Test Data Rabbit, eye irritation DRAIZE MAX=10 Nonirritating Rabbit, primary skin irritation DRAIZE MAX=8 Nonirritating Ames Salmonella Assay (Direct Plate) No increase in mutation frequency Ames Salmonella Assay (Plate with S9) No increase in mutation frequency Chronic Overexposure Effects Routes of exposure to this material include eye and skin contact or inhalation. Contact with the eyes and skin may result in mechanical irritation. In a 90 day study, rats administered this compound exhibited scale formation of the ears and extremities, body weight reduction,

5 Cablelite A Page 5/7 testicular atrophy, increased relative liver and kidney weights and hematological changes. No adverse effects were noted at the lose dose of 100 mg/kg/day. No nervous system effects were noted at any dose. Chronic toxicity Irritation/Corrosion Sensitizer Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity Not available. Not available. Not available. Not available. Not available. Not available. Not available. Section 12. Ecological information Ecotoxicity Aquatic ecotoxicity No known significant effects or critical hazards. Product/ingredient name Result Species Exposure Multifunctional Acrylate LC to 10 mg/l Fish 96 hours Photoinitiators Acute IC50 10 to 100 mg/l Algae 72 hours Acute LC50 10 to 100 mg/l Daphnia 48 hours Acute LC50 10 to 100 mg/l Fish 96 hours Acute LC50 1 to 10 mg/l Fish 48 hours Persistence/degradability Not available. Product/ingredient name Test Result Dose Additive 0 % 28 days Inoculum Other adverse effects Not available. No known significant effects or critical hazards. Section 13. Disposal considerations Waste disposal Consult your local or regional authorities. Waste must be disposed of in accordance with national and local environmental regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

6 Cablelite A Page 6/7 Section 14. Transport information Regulatory information UN number Proper shipping name Class Packing group Label Additional information DOT Classification TDG Classification Not Mexico Classification Not Not ADR/RID Class Not IMDG Class Not IATADGR Class Not Section 15. Regulatory information U.S. Federal regulations Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) SARA 313 Form R Reporting requirements Supplier notification State regulations United States inventory (TSCA 8b) All components are listed or exempted. Product name CAS number Concentration Glycol ether acrylate Glycol ether acrylate SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. Listed Connecticut Carcinogen Reporting None of the components are listed. Connecticut Hazardous Material Survey None of the components are listed. Florida substances None of the components are listed. Illinois Chemical Safety Act None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act None of the components are listed. Louisiana Reporting None of the components are listed. Louisiana Spill None of the components are listed. Massachusetts Spill None of the components are listed. Massachusetts Substances None of the components are listed. Michigan Critical Material None of the components are listed. Minnesota Hazardous Substances None of the components are listed. New Jersey Hazardous Substances The following components are listed GLYCOL ETHERS New Jersey Spill None of the components are listed. New Jersey Toxic Catastrophe Prevention Act None of the components are listed. New York Acutely Hazardous Substances None of the components are listed. New York Toxic Chemical Release Reporting None of the components are listed. Pennsylvania RTK Hazardous Substances The following components are listed GLYCOL ETHERS Rhode Island Hazardous Substances None of the components are listed.

7 Cablelite A Page 7/7 Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Section 16. Other information Label requirements Date of printing Date of issue Date of previous issue Version Notice to reader MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. 4/13/ /13/2011. No previous validation. 1 To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. While this information has been prepared in good faith by technical experts within the above named organization, the final determination of suitability of any material is the sole responsibility of the end user, after proper consultation with the end users' engineering, technical, health and safety professionals. All materials may present unknown hazards, and should be used with caution considering the specific material, other materials that it may or may not be combined with, and any engineering controls and/or process implementation(s) designed for the use of the material in any specific system process. Although certain hazards are described within, these cannot be guaranteed as the only hazards that exist. Sources of key data Literature data and/or investigation reports are available through the manufacturer. Alterations compared to the previous version Alterations compared to the previous version are marked with a little (blue) triangle.