Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard (). Material Safety Data Sheet 1. Product and company identification Common name Material uses Hydroponic nutrients. Supplier/Manufacturer Technaflora Plant Products Ltd River Place,11 Mission, B.C. Canada, V4S A2 Tel / In case of emergency CHEMTREC, U.S. (8) International (73) Physical state Hazards identification Hazard status This material is classified as hazardous under OSHA regulations. Emergency overview CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. Do not ingest. Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Routes of entry Dermal contact. Eye contact... Potential acute health effects Potential chronic health effects Medical conditions aggravated by overexposure Liquid. See toxicological information (section 11) 3. Name Moderately irritating to eyes. Moderately irritating to the skin. Moderately irritating to the respiratory system. May be harmful if swallowed. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation. Composition/information on ingredients CAS number Diphosphoric acid, tetrapotassium salt % Date of issue 9/12/211 Page 1/5

2 4. Eye contact contact First aid measures Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur. Wash with soap and water. Get medical attention if symptoms occur. Notes to physician If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms appear. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. No specific antidote. Medical staff must contact Poison Control Center. 5. Fire-fighting measures Flammability of the product Products of combustion Extinguishing media Special exposure hazards Special protective equipment for fire-fighters Suitable Not suitable 6. Accidental release measures May be combustible at high temperature. These products are nitrogen oxides, phosphates. Some metallic oxides. Use an extinguishing agent suitable for the surrounding fire. None known. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. 7. Handling Storage 8. Handling and storage Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Exposure controls/personal protection Product name Diphosphoric acid, tetrapotassium salt Exposure limits ACGIH TLV (). TWA 5 mg/m 3 8 hour(s). Form Dust ACGIH TLV (). TWA 5 mg/m 3 8 hour(s). Form Dust Engineering measures Personal protection No special ventilation requirements. Good general ventilation should be sufficient to control airborne levels. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Date of issue 9/12/211 Page 2/5

3 Respiratory Hands Safety glasses. Lab coat. A respirator is not needed under normal and intended conditions of use. Natural rubber (latex). HMIS Code/Personal protective equipment B Personal protection in case Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSHapproved of a large spill Hygiene measures self-contained breathing apparatus or equivalent and full protective gear. Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. 9. Physical and chemical properties Physical state ph Boiling/condensation point Melting/freezing point Liquid. Acidic. The lowest known value is 1 C (212 F) (Water). May start to solidify at C (32 F) based on data for Water. Relative density Vapor pressure Weighted average 1.3 (Water = 1) The highest known value is 2.3 kpa (17.5 mm Hg) (at 2 C) (Water). Vapor density The highest known value is.62 (Air = 1) (Water). Evaporation rate.36 (Water) compared with Butyl acetate. Solubility Easily soluble in methanol, acetone. Partially soluble in cold water, hot water. 1. Stability and reactivity Stability and reactivity Incompatibility with various substances The product is stable. Reactive with reducing materials, organic materials, acids and alkalis. Hazardous polymerization Will not occur. Conditions of reactivity Slightly flammable in the presence of the following materials or conditions open flames, sparks and static discharge. Non-flammable in the presence of the following materials or conditions heat. 11. Toxicological information Toxicity data Product/ingredient name Test Result Route Species >2 mg/kg >464 mg/kg Oral Dermal Rat Rabbit Diphosphoric acid, tetrapotassium salt >464 mg/k Dermal Rabbit 2217 mg/kg 3 mg/kg Oral Dermal Rat Rabbit Acute Effects Moderately irritating to eyes. Moderately irritating to the skin. Moderately irritating to the respiratory system. May be harmful if swallowed. Date of issue 9/12/211 Page 3/5

4 Potential chronic health effects Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. 12. Ecological information Ecotoxicity data Product/ingredient name Species Period Result Fish (LC5) 96 hour(s) >91 mg/l Environmental precautions Products of degradation 13. Disposal considerations Waste disposal 14. Transport information NAERG Not applicable. Regulatory information 15. SARA 313 UN/ IMDG/ IATA DOT Regulatory information HCS Classification U.S. Federal regulations Form R - Reporting requirements Supplier notification No known significant effects or critical hazards. These products are nitrogen oxides, phosphates. Some metallic oxides. The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. Not regulated. Irritating material TSCA All components listed. SARA 32/34/311/312 extremely hazardous substances No products were found. SARA 32/34 emergency planning and notification No products were found. SARA 32/34/311/312 hazardous chemicals SARA 311/312 MSDS distribution - chemical inventory - hazard identification Ammonium Nitrate Fire hazard, reactive Clean Water Act (CWA) 37 No products were found. Clean Water Act (CWA) 311 No products were found. Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Pennsylvania RTK (environmental hazard, generic environmental hazard) Massachusetts RTK New Jersey California prop. 65 No products were found. Date of issue 9/12/211 Page 4/5

5 International lists This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). 16. Other information Label requirements (U.S.A.) MAY BE HARMFUL IF SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. Hazardous Material Information System (U.S.A.) HMIS RATING Health 1 Fire hazard Physical Hazard Personal protection B HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate 1- Slight - Minimal See section 8 for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health 1 Flammability Reactivity Special References ANSI Z4.1, MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. Date of issue Date of previous issue 9/12/211 6/3/26 Date of previous issue 7/15/24 Version 3 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 9/12/211 Page 5/5