Material Safety Data Sheet Prime 20 Fast Hardener

Transcription

1 Conforms to ANSI Z Standard (United States, Canada). 1. Material Safety Data Sheet Prime 20 Fast Hardener Product and company identification Common name Material uses Supplier/Manufacturer Prime 20 Fast Hardener Epoxy curing agent. Gurit (Canada) inc. Usine de pré-imprégné 175 rue Péladeau Magog, QC J1X 5G9 Tel In case of emergency CANUTEC (613) MSDS authored by Kemika XXI Inc /20/ Physical state Hazards identification Routes of entry Potential acute health effects Eyes Skin Inhalation Ingestion Medical conditions aggravated by overexposure Liquid. (Fluid.) See toxicological information (section 11) Odor Characteristic. Color Yellow. (Light.) Hazard status This material is classified hazardous under OSHA regulations in the United States and the WHMIS Controlled Product Regulation in Canada. Emergency overview DANGER! CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS KIDNEYS, LIVER, RESPIRATORY TRACT, SKIN, EYE, LENS OR CORNEA. MAY BE HARMFUL IF SWALLOWED. COMBUSTIBLE LIQUID AND VAPOR. VAPOR MAY CAUSE FIRE. Potential chronic health effects Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Keep away from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Dermal contact. Eye contact. Inhalation. Ingestion. Corrosive to eyes. Corrosive to the skin. May cause sensitization by skin contact. Corrosive to the respiratory system. May be harmful if swallowed. May cause burns to mouth, throat and stomach. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or prolonged exposure to the substance can produce lung damage. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to the substance can produce target organ damage. Date of issue 10/20/2006 Page 1/7

2 3. Composition/information on ingredients Name United States CAS number 2-Piperazin-1-ylethylamine P-tert-butylphenol Trimethylhexamethylenediamine M-xylene-alpha,alpha'-diamine Canada Name CAS number % 2-Piperazin-1-ylethylamine P-tert-butylphenol Trimethylhexamethylenediamine M-xylene-alpha,alpha'-diamine Eye contact Skin contact Inhalation Ingestion First aid measures Notes to physician 5. Fire-fighting measures Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 20 minutes. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get medical attention immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. No specific antidote. Medical staff must contact Poison Control Center. Flammability of the product Products of combustion Extinguishing media Combustible. These products are carbon oxides, nitrogen oxides. Suitable Use dry chemical, carbon dioxide, water spray (fog) or foam. Not suitable Do not use water jet. Special exposure hazards Combustible liquid and vapor. Vapor may cause flash fire. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel away. Use suitable protective equipment. Do not touch or walk through spilled material. Environmental precautions Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials) and use a nonsparking or explosion-proof means to transfer material to a sealable, appropriate container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Date of issue 10/20/2006 Page 2/7 %

3 7. Handling Storage. Handling and storage Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use only with adequate ventilation. Do not breathe vapor or mist. Keep away from heat, spar and flame. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Wash thoroughly after handling. Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Exposure controls/personal protection Product name M-xylene-alpha,alpha'-diamine Product name M-xylene-alpha,alpha'-diamine United States Exposure limits ACGIH TLV (United States, 1/2005). Skin CEIL 0.1 mg/m 3 Form All forms. NIOSH REL (United States, 12/2001). Skin CEIL 0.1 mg/m 3 Form All forms. OSHA PEL 199 (United States, 3/199). Skin CEIL 0.1 mg/m 3 Form All forms. Canada Exposure limits ACGIH TLV (United States, 1/2005). Skin CEIL 0.1 mg/m 3 Form All forms. Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Personal protection equipments Eyes Safety glasses. Skin Respiratory Hands Synthetic apron. Vapor respirator. Nitrile gloves. HMIS Code/Personal protective equipment Personal protection in case of a large spill Hygiene measures G Safety glasses, goggles or face shield. Impervious gloves. Full suit. HAZMAT boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear (Tychem-BR No from Dupont). Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. Date of issue 10/20/2006 Page 3/7

4 9. Physical and chemical properties Physical state Flash point Auto-ignition temperature Color Odor Liquid. (Fluid.) Closed cup 92 C (197.6 F).(Pensky-Martens.) 315 C (599 F) Yellow. (Light.) Characteristic. Boiling/condensation point 220 C (42 F) Melting/freezing point Weighted average C (0.1 F) Relative density 0.96 (Water = 1) Vapor density The highest known value is 4.4 (Air = 1) (2-Piperazin-1-ylethylamine). Evaporation rate (2-Piperazin-1-ylethylamine) compared with Butyl acetate. Solubility Insoluble in cold water, hot water. 10. Stability and reactivity Stability and reactivity Incompatibility with various substances The product is stable. Reactive with oxidizing materials and acids. Hazardous polymerization Will not occur. Conditions of reactivity Flammable in the presence of the following materials or conditions open flames, sparks and static discharge. Slightly flammable in the presence of the following materials or conditions heat. 11. Toxicological information Toxicity data Product/ingredient name Test Result Route Species 2-Piperazin-1-ylethylamine LD mg/kg Oral chicken P-tert-butylphenol LD50 LD mg/kg 150 mg/kg Oral Dermal Mammal Mammal Trimethylhexamethylenediamine LD mg/kg Oral Rat M-xylene-alpha,alpha'-diamine LD mg/kg Oral Rat Acute Effects Eyes Skin Inhalation Ingestion Potential chronic health effects Target organs Corrosive to eyes. Corrosive to the skin. May cause sensitization by skin contact. Corrosive to the respiratory system. May be harmful if swallowed. May cause burns to mouth, throat and stomach. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Contains material which causes damage to the following organs kidneys, liver, upper respiratory tract, skin, eye, lens or cornea. Date of issue 10/20/2006 Page 4/7

5 12. Ecological information Product/ingredient name Ecotoxicity data Species Period Result 2-Piperazin-1-ylethylamine Pimephales promelas (LC50) 96 hour(s) 2190 mg/l P-tert-butylphenol Daphnia magna (EC50) Pimephales promelas (LC50) 4 hour(s) 96 hour(s) 3.9 mg/l 5.14 mg/l Environmental precautions Products of degradation Toxicity of the products of biodegradation 13. Disposal considerations Waste disposal 14. Transport information AERG 153 Regulatory information UN / IMDG / IATA Classification Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. These products are carbon oxides and water, nitrogen oxides. The products of degradation are less toxic than the product itself. The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. Proper shipping name Class UN number PG Label POLYAMINES, LIQUID, CORROSIVE, N.O.S. (2-Piperazin-1-ylethylamine, P-tert-butylphenol) UN2735 II DOT Classification POLYAMINES, LIQUID, CORROSIVE, N.O.S. (2-Piperazin-1-ylethylamine, P-tert-butylphenol) UN2735 II CORROSIVE TDG Classification POLYAMINES, LIQUID, CORROSIVE, N.O.S. (2-Piperazin-1-ylethylamine, P-tert-butylphenol) UN2735 II 15. Regulatory information United States HCS Classification U.S. Federal regulations Combustible liquid Corrosive material Sensitizing material Target organ effects TSCA (a) PAIR P-tert-butylphenol TSCA (b) inventory All components listed. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/311/312 hazardous chemicals 2-Piperazin-1-ylethylamine; P-tertbutylphenol; M-xylene-alpha,alpha'-diamine SARA 311/312 MSDS distribution - chemical inventory - hazard identification 2-Piperazin- 1-ylethylamine Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; P-tert-butylphenol Immediate (acute) health hazard; M-xylene-alpha,alpha'- Date of issue 10/20/2006 Page 5/7

6 State regulations Canada WHMIS (Canada) diamine Immediate (acute) health hazard Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 311 No products were found. Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. Pennsylvania RTK 2-Piperazin-1-ylethylamine (generic environmental hazard); M-xylene-alpha,alpha'-diamine (generic environmental hazard) Massachusetts RTK 2-Piperazin-1-ylethylamine; M-xylene-alpha,alpha'-diamine New Jersey 2-Piperazin-1-ylethylamine; P-tert-butylphenol; Trimethylhexamethylenediamine; M-xylene-alpha,alpha'-diamine California prop. 65 No products were found. Class B-3 Combustible liquid with a flash point between 37. C (100 F) and 93.3 C (200 F). Class D-2B Material causing other toxic effects (Toxic). Class E Corrosive material International lists DSL All components listed. This product has been classified in accordance with the hazard criteria of the Canadian CPR and the United States OSHA. This MSDS contains all the information required by the CPR and OSHA, the American National Standard Institute (ANSI) Z Other information Label requirements (U.S.A.) This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS KIDNEYS, LIVER, RESPIRATORY TRACT, SKIN, EYE, LENS OR CORNEA. MAY BE HARMFUL IF SWALLOWED. COMBUSTIBLE LIQUID AND VAPOR. VAPOR MAY CAUSE FIRE. Hazardous Material Information System (U.S.A.) HMIS RATING Health * 3 Fire hazard Physical Hazard 2 0 Personal protection G HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate 1- Slight 0- Minimal See section for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health Flammability Reactivity Special Date of issue 10/20/2006 Page 6/7

7 References Date of issue Version Prime 20 Fast Hardener ANSI Z400.1, MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/-64, 31 December 197. Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version /20/ Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 10/20/2006 Page 7/7