Material Safety Data Sheet

Transcription

1 Product name Product code Synonym Material uses Manufacturer Validation date Print date In case of emergency Material Safety Data Sheet Buffer ph 5.00 Section 1. Product and Company Identification Buffer ph 5.00 BX1655 None. Other non-specified industry Laboratory Reagent EMD Chemicals Inc. P.O. Box Democrat Road Gibbstown, NJ Technical Service Monday - Friday PM 2/26/ /26/ CHEMTREC (USA) CANUTEC (Canada) 24 Hours/Day 7 Days/Week Section 2. Hazards Identification Physical state Liquid. Odor Odorless. OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Emergency overview CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY BE HARMFUL IF INHALED. WARNING This product contains a chemical(s) known to the State of California to cause cancer. Do not ingest. Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Routes of entry Inhalation. Ingestion. Potential acute health effects Eyes Moderately irritating to eyes. Skin Moderately irritating to the skin. Inhalation Moderately irritating to the respiratory system. Ingestion Harmful if swallowed. Carcinogenic effects Mutagenic effects Teratogenicity / Reproductive toxicity Medical conditions aggravated by overexposure See toxicological information (section 11) Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or prolonged exposure to the substance can produce lung damage. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation.

2 Page 2/6 Section 3. Composition/Information on Ingredients United States Name CAS number % by Weight Sodium Hydroxide <1 Potassium Hydrogen Phthalate <1 Dowicide A Water >98 Section 4. First Aid Measures Eye contact Skin contact Inhalation Ingestion Protection of first-aiders Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention. Flush contaminated skin with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouthto-mouth resuscitation. Get medical attention if symptoms occur. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. No action shall be taken involving any personal risk or without suitable training. Section 5. Fire Fighting Measures Flammability of the product No specific hazard. Extinguishing media Suitable Use an extinguishing agent suitable for the surrounding fire. Not suitable None known. Special exposure hazards Not available. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental Release Measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.

3 Page 3/6 Section 7. Handling and Storage Handling Storage Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Section 8. Exposure Controls/Personal Protection Consult local authorities for acceptable exposure limits. Engineering measures No special ventilation requirements. Good general ventilation should be sufficient to control airborne levels. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Personal protection Eyes Skin Respiratory Hands Hygiene measures Color Odor Boiling/condensation point Melting/freezing point Evaporation rate Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Recommended safety glasses with side-shields Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Body Recommended lab coat and gloves Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Section 9. Physical and Chemical Properties Physical state Liquid. Clear. Colorless. Odorless. The lowest known value is 99.9 C (211.8 F) (Water). Section 10. Stability and Reactivity Stability and reactivity Conditions of instability Incompatibility with various substances Hazardous decomposition products Hazardous polymerization May start to solidify at -0.1 C (31.8 F) based on data for Water (Water) compared with(n-butyl Acetate =1) The product is stable. Avoid excessive heat. (Dowicide A) Slightly reactive or incompatible with the following materials oxidizing materials, metals and acids. SOx Will not occur.

4 Page 4/6 Section 11. Toxicological Information Toxicity data Other toxic effects on humans Specific effects Carcinogenic effects Mutagenic effects Teratogenicity / Reproductive toxicity Sensitization Ingestion Inhalation Eyes Skin Hazardous in case of ingestion. Slightly hazardous in case of inhalation. Moderately irritating to the respiratory system. Moderately irritating to eyes. Moderately irritating to the skin. Section 12. Ecological Information Environmental precautions Section 13. Disposal Considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 14. Transport Information Regulatory information UN number Proper shipping name DOT Classification Not available. CHEMICALS, N.O.S. Not - available. PG* Packing group Class PG* Label Additional information Not available.

5 Page 5/6 Section 15. Regulatory Information United States HCS Classification U.S. Federal regulations Canada WHMIS (Canada) CEPA DSL/CEPA NDSL EU regulations Risk phrases International regulations International lists Irritating material TSCA 8(b) inventory Listed SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/311/312 hazardous chemicals SODIUM HYDROXIDE; Dowicide A SARA 311/312 MSDS distribution - chemical inventory - hazard identification SODIUM HYDROXIDE Immediate (Acute) Health Hazard; Dowicide A Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 311 Sodium Hydroxide Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. State regulations Pennsylvania RTK SODIUM HYDROXIDE (environmental hazard, generic environmental hazard) Massachusetts RTK SODIUM HYDROXIDE; Dowicide A New Jersey Buffer ph 5.00 WARNING This product contains a chemical(s) known to the State of California to cause cancer. Ingredient name Cancer Reproductive No significant risk Maximum level acceptable dosage level Dowicide A Yes. No. Yes. No. Not controlled under WHMIS (Canada). CEPA DSL Potassium Hydrogen Phthalate; SODIUM HYDROXIDE; Dowicide A; Water This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. This product is not classified according to EU legislation. Australia (NICNAS) Potassium Hydrogen Phthalate; SODIUM HYDROXIDE; Dowicide A; Water Japan (METI) Potassium Hydrogen Phthalate; SODIUM HYDROXIDE; Dowicide A; Water Japan (MOL) Dowicide A Section 16. Other Information Label requirements Korea (TCCL) Potassium Hydrogen Phthalate; SODIUM HYDROXIDE; Dowicide A; Water Philippines (RA6969) Potassium Hydrogen Phthalate; SODIUM HYDROXIDE; Dowicide A; Water CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY BE HARMFUL IF INHALED. WARNING This product contains a chemical(s) known to the State of California to cause cancer.

6 Page 6/6 Section 16. Other Information National Fire Protection Association (U.S.A.) Health Flammability Instability Special Notice to reader The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.