PT Technologies Europe ISSUED BY: RL ISSUE DATE: ISSUE NO: 12 MSDS: 301(B) Product Name: PF Bucket Wipe

Transcription

1 S A F E T Y D A T A S H E E T according to Regulation (EC) No. 1907/2006 (REACH) 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PF Bucket Wipe 1.1. Use of the substance/preparation (industrial, occupational, consumer): occupational Purpose of the product: solvent impregnated degreasing wipe 1.2. Manufacturer: Meenane, Watergrasshill, Co. Cork, Ireland. Tel: Fax: info@pttechnologies.com Web: Person responsible: Technical Manager 1.4. Emergency telephone number: UK National Poisons Information Service +44 (0) HAZARDS IDENTIFICATION R 66 Repeated exposure may cause skin dryness or cracking 2.1. Additional information on the risks to human health and the environment: Eye contact: May cause irritation, tearing and redness. Does not injure eye. Skin contact: Prolonged or repeated contact with skin may cause defatting or dryness of skin. Continued dryness may cause dermatitis. Inhalation: Excessive inhalation of vapours can cause irritation of the respiratory tract, nausea, dizziness or headache. Wipes prevent this occurrence. Material can form flammable mixtures at or above flash point or can burn given a source of ignition. 3. COMPOSITION/INFORMATION ON INGREDIENTS Name CAS number EC number REACH number Concentration (%) Hazard letter(s) R-phrases Orange Terpenes* < 5 Xi 36/38 Alkanes, C11-15-iso-* < 55 Xn * Substance classified by manufacturer 4. FIRST AID MEASURES GENERAL INSTRUCTIONS: In case of symptoms, call a physician immediately. NOTES TO THE PHYSICIAN: See instructions on the label. Symptoms: None Treatment: no special recommendations INGESTION: - Uncharacteristic way of exposure INHALATION: - If affected by vapours, get to fresh air. - If breathing is difficult, seek medical attention SKIN CONTACT: - Remove contaminated clothing. - Wash skin with large quantities of soap and water for at least 15 minutes.

2 4.4. EYE CONTACT: - Flush with water for at least 15 minutes while holding the eyelids apart. - In case of symptoms, call a physician immediately. 5. FIRE-FIGHTING MEASURES 5.1. Suitable extinguishing media: CO2, dry chemical, foam Extinguishing media unsuitable for safety reasons: No special recommendations Special protective equipment for fire-fighters: Wear full protective clothing and self-contained breathing apparatus Hazardous combustion products: In case of thermal decomposition: COx Other information: Class B fire procedures. 6. ACCIDENTAL RELEASE MEASURES 6.1. PERSONAL PRECAUTIONS: Keep unnecessary and unprotected people away. Only well-trained personnel wearing suitable protective clothing and equipment are to remain in the area of the accident ENVIRONMENTAL PRECAUTIONS: No special recommendations METHODS FOR CLEANING UP: Land Spill: transfer to suitable, properly labelled, sealable waste containers for disposal. See Section 13 for disposal methods. Water Spill: Remove from surface. 7. HANDLING AND STORAGE 7.1. Handling: Precautions for safe handling: No special recommendations available. Precautions for preventing fire and explosion: Keep away from open flames, heat and other ignition sources Storage: Conditions for safe storage: Store in original, sealed and labelled container only. Keep containers closed when not in use. Storage temperature: Ambient Incompatible materials: Keep away from heat and ignition sources. Type of material used in the packaging/containers: No special recommendations Specific uses: No special recommendations available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Exposure limit values: Does not contain substances above concentration limits fixing an occupational exposure limit (91/322/EEC, 98/24/EC, 2000/39/EC). Observe the federal, state and local environmental exposure limits Occupational exposure controls: According to relevant legislation (see Section 15) in the case of hazardous materials with no occupational exposure limit value the employer is to maintain concentrations at the technically achievable lowest level where the hazardous substance poses no harm to workers Specific conditions for work: Normal room ventilation is adequate. Use fans or other mechanical ventilation in enclosed areas where large quantities of product are used.

3 8.4. Personal protection measures: 1. Respiratory protection: Not required under normal conditions. 2. Skin protection: Not required under normal conditions. 3. Hand protection: Solvent resistant gloves are recommended where prolonged skin exposure is expected. 4. Eye protection: Not required under normal conditions Environmental exposure controls: No special procedures recommended. The requirements described in Section 8 are applicable only under normal circumstances of use and handling. If conditions differ from normal or work is carried out under extreme conditions consult an expert before deciding upon other necessary precautions and further protective measures. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Physical and chemical properties: Parameter Test method Remarks 1. Physical state: Cloth wipes 2. Colour: white 3. Odour: slight citrus odour 4. Melting point: - 5. Density (at 20 C): - 6. Solubility/Miscibility (at 20 C): Non soluble 7. Boiling point: - 8. Viscosity (at 25 C): - 9. Ignition temperature: Flash point: 61 o C (Tag Closed Cup) (impregnating substance) 11. Self-ignition temperature: Approx. > 210 o C 12. Flammability: Wipes will burn if lit, avoid contact with naked flame. 13. Vapour Pressure: Vapour Density (Air= 1): Specific Gravity (Water = 1): Percentage Volatility: VOC content: 2295 grams/400 wipe bucket 1912 grams/250 wipe bucket 1148 grams /150 wipe bucket 99 grams/24 wipe flat pack 6.9 grams/single wipe sachet 9.2. Other information: No data available.

4 10. STABILITY AND REACTIVITY Stability: 1. Stable at normal temperature and under normal conditions. 2. Hazardous decomposition products: carbon monoxide, carbon dioxide. 3. Hazardous reactions, materials to avoid: strong oxidizing agents. 4. Hazardous polymerisation: will not occur. 11. TOXICOLOGICAL INFORMATION Acute toxicity (LC 50 ): No data available Other information: Acute effects: Inhalation: Vapour concentrations above recommended exposure levels may be irritating to the eyes and the respiratory tract, may cause headaches or dizziness. Wipes prevent this occurrence. Skin contact: Low order of toxicity. Frequent or prolonged contact may dry the skin, leading to discomfort and dermatitis. Eye contact: Will cause eye discomfort but will not injure eye tissue. Ingestion: Minimal toxicity. Sensitization: Sensitizing effects not known. Subacute to chronic toxicity: not known CMR effects: Carcinogenity: not known Reproductive toxicity: not known Mutagenicity: not known Summary of CMR properties for substances subject to registration: - Effects observed in laboratory animal tests: not known The product is not considered to be a health hazard under normal circumstances of use. 12. ECOLOGICAL INFORMATION Ecotoxicity: No acute toxicity to aquatic organisms is expected at the maximum water solubility of this product. Mobility: This product has low solubility. Solvent content is not expected to migrate from wipe cloth. Persistence and degradability: This product is not expected to biodegrade readily. Bioaccumulative potential: no data available. Results of PBT assessment: no data available. Other adverse effects: no data available. 13. DISPOSAL CONSIDERATIONS Handle and dispose of waste in accordance with national and local regulations. European waste code: Packaging: by authorized disposal company. 14. TRANSPORT INFORMATION Not dangerous goods in sense of the transport regulations Land transport: 1. ADR/RID class: - 2. UN number: - 3. Packing group: Marine transport: 1. IMDG class: - 2. UN number: - 3. Packing group: - 4. Marine pollutant: Air transport: 1. ICAO/IATA class: - 2. UN number: - 3. Packing group: -

5 15. REGULATORY INFORMATION Chemical Safety Assessment: Labelling: Hazard symbol(s): No hazard symbol required. Risk phrases indicating the nature of special risks attributed to the substance/preparation: R 66 Repeated exposure may cause skin dryness or cracking Safety phrases indicating the safety advice concerning the substance/preparation: S 35 This material and it s container must be disposed of in a safe way S 37 Wear suitable gloves Authorisations/Restrictions on use: National and European Union regulations: 1. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC 2. Commission Directive 2001/58/EC of 27 July 2001 amending for the second time Directive 91/155/EEC defining and laying down the detailed arrangements for the system of specific information relating to dangerous preparations in implementation of Article 14 of European Parliament and Council Directive 1999/45/EC and relating to dangerous substances in implementation of Article 27 of Council Directive 67/548/EEC (safety data sheets) 3. Commission Directive 2004/73/EC of 29 April 2004 adapting to technical progress for the twenty-ninth time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances 4. Commission Directive 2001/60/EC of 7 August 2001 adapting to technical progress Directive 1999/45/EC of the European Parliament and of the Council concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations 5. Commission Directive 2006/15/EC of 7 February 2006 establishing a second list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC and amending Directives 91/322/EEC and 2000/39/EC 6. Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations 7. Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at work (fourteenth individual Directive within the meaning of Article 16(1) of Directive 89/391/EEC)

6 16. OTHER INFORMATION Full text of R-phrases referred to in Section 2 and 3 of the safety data sheet: R 36/38 - Irritating to eyes and to skin. R 65 Harmful: may cause lung damage if swallowed R 66 repeated exposure may cause skin dryness or cracking Training advice: - Recommended restrictions on use (non-statutory recommendations by the supplier): - Sources of key data used to compile the safety data sheet: - This safety data sheet has been compiled on the basis of the information provided by the manufacturer. The information, data and recommendations contained herein are provided in good faith, obtained from reliable sources and believed to be true and accurate as of the date issued; however, no representation is made as to the comprehensiveness of the information. The SDS shall be used only as a guide for handling the product; in the course of handling and using the product other considerations may arise or be required. Since the conditions or the handling, the storage and the disposal of this product are beyond the control of the manufacturer, the distributor or the preparer of this SDS, no warranty, expressed or implied, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. No responsibility is assumed regarding the accuracy, completeness or suitability of all or any of the information contained herein or the results to be obtained from the use thereof at the time of use. In no way shall the manufacturer, the distributor or the preparer of the SDS be liable for any claims, losses or damages of third parties, personal injury, property damage, lost profits or any special, direct, indirect, incidental, consequential or exemplary damages resulting from the use of or reliance upon such information. Users are cautioned to determine the appropriateness and applicability of the above information to their particular circumstances and purposes and assume all risk associated with the use of this product. It is the responsibility of the user to fully comply with local, national and international regulations concerning the use of this product. Abbreviations and acronyms: CMR effects: carcinogenity, mutagenicity and reproductive toxicity. PBT: persistent, bioaccumulative and toxic. N.d.: not determined. N.a.: not applicable.