1. Substance/preparation and manufacturer/supplier identification

Transcription

1 Safety data sheet Page: 1/9 1. Substance/preparation and manufacturer/supplier identification Lumina Royal Exterior Indigo 5803H Use: Colorants for industrial use Manufacturer/supplier: BASF Philippines, Inc. 11/F HHIC Building, 1128 University Parkway, North Bonifacio, Global City, Taguig, Metro Manila, PHILIPPINES Telephone: Telefax number: Emergency information: National emergency number: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: No need for classification according to GHS criteria for this product. Label elements and precautionary statement: The product does not require a hazard warning label in accordance with GHS criteria. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered.

2 Page: 2/9 3. Composition/information on ingredients Chemical nature Mica group minerals metal oxides modified with: Polymer 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Note to physician: Symptoms: No significant reaction of the human body to the product known. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Specific hazards: No particular hazards known. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

3 Page: 3/9 6. Accidental Release Measures Personal precautions: Avoid dust formation. Environmental precautions: Do not empty into drains. Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Pick up with suitable appliance and dispose of. 7. Handling and Storage Handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Avoid contact with the skin, eyes and clothing. Protection against fire and explosion: No special precautions necessary. Storage Further information on storage conditions: No special precautions necessary. 8. Exposure controls and personal protection Components with occupational exposure limits Mica-group minerals, ; TWA value 3 mg/m3 (ACGIHTLV), Respirable fraction TWA value (OEL (PH)) Titanium dioxide, ; TWA value 10 mg/m3 (ACGIHTLV) TWA value 15 mg/m3 (OEL (PH)) Tin oxide (SnO2), ; TWA value 2 mg/m3 (ACGIHTLV) Measured as: tin (Sn) Silica, amorphous, fumed, cryst.-free, ; TWA value 0.8 mg/m3 (OEL (PH)) The exposure limit is calculated from the equation, 80mg/m3)/(%SiO2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits.

4 Page: 4/9 Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Due to the colouring properties of the product closed work clothes should be used, to avoid stains during manipulation. Hands and/or face should be washed before breaks and at the end of the shift. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: powder The colour is derived from the trade name. odourless ph value: 4-8 (4 %(m)) (as suspension) Melting point: > 1,200 C Boiling point: not applicable, solid with a melting temperature over 300 C Flash point: Evaporation rate: The product is a non-volatile solid. Flammability (solid/gas): not flammable Lower explosion limit:

5 Page: 5/9 Upper explosion limit: Ignition temperature: Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Self ignition: not self-igniting Self heating ability: It is not a substance capable of spontaneous heating. Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: not applicable Density: g/cm3 (approx. 20 C) Relative density: (approx. 20 C) Bulk density: approx. 0.5 kg/l Relative vapour density (air): The product is a non-volatile solid. Solubility in water: insoluble Hygroscopy: Non-hygroscopic Solubility (quantitative) : not available Partitioning coefficient n-octanol/water (log Pow): Viscosity, dynamic: 10. Stability and Reactivity Conditions to avoid: Avoid dust formation. Avoid deposition of dust. No special precautions other than good housekeeping of chemicals. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: No substances known that should be avoided.

6 Page: 6/9 Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. LC50 (by inhalation): LD50 (dermal): Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Respiratory/Skin sensitization Assessment of sensitization: The chemical structure does not suggest a sensitizing effect. Germ cell mutagenicity Assessment of mutagenicity: No data was available concerning mutagenic activity. The chemical structure does not suggest a specific alert for such an effect. Carcinogenicity Assessment of carcinogenicity: Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The product has not been tested. The statement has been derived from the properties of the individual components. Information on: Titanium dioxide Assessment of carcinogenicity:

7 Page: 7/9 IARC (International Agency for Research on Cancer) has classified this substance as group 2B (The agent is possibly carcinogenic to humans). In long-term studies in rats in which the substance was given by inhalation, a carcinogenic effect was observed. Tumors were only observed in rats after chronic inhalative exposure to high concentrations which caused sustained lung inflammation. In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed. Dermal exposure is not expected to be carcinogenic Reproductive toxicity Assessment of reproduction toxicity: No reliable data are available concerning reproduction toxicity. Developmental toxicity Assessment of teratogenicity: No reliable data was available concerning teratogenicity. Specific target organ toxicity (single exposure): Remarks: No data available. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Prolonged or repeated exposure may cause pulmonary problems. The product has not been tested. The statement has been derived from the properties of the individual components. Aspiration hazard No aspiration hazard expected. 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: At the present state of knowledge, no negative ecological effects are expected. The product has not been tested. The statement has been derived from the properties of the individual components. Toxicity to fish: LC50 (96 h), Fish Aquatic invertebrates: LC50 (48 h), daphnia Aquatic plants: EC50 (72 h), algae

8 Page: 8/9 Microorganisms/Effect on activated sludge: EC50 (0.5 h), bacteria Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity. Mobility Assessment transport between environmental compartments: No data available. Bioaccumulation potential Assessment bioaccumulation potential: The product will not be readily bioavailable due to its consistency and insolubility in water. The product has not been tested. The statement has been derived from the properties of the individual components. Other adverse effects The product contains: tin The product contains heavy metals, which are firmly built in a matrix and are therefore not bioavailable. Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. Other ecotoxicological advice: The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. The product has not been tested. The statement has been derived from the properties of the individual components. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents.

9 Page: 9/9 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Other regulations Registration status: PICCS, PH released / listed 16. Other Information Recommended use: pigment Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.