SAFETY DATA SHEET Swarfega Powerwash Pato & Driveway Cleaner

Transcription

1 Revision Date 15/02/2011 SAFETY DATA SHEET According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identfer Product name Product No. SPBQ5LB, SWPD27QP, SWPD2LBSFX, SWPD5LB 1.2. Relevant identfed uses of the substance or mixture and uses advised against Identfed uses Detergent Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number Deb Ltd Denby Hall Way Denby Derbyshire DE5 8JZ Main Tel Technical Tel Natonal Poisons Informaton Service SECTION 2: HAZARDS IDENTIFICATION 2.1. Classifcaton of the substance or mixture Classifcaton (1999/45/EEC) Xi;R36/38. Environment The product does not meet the requirement for classifcaton as an environmental hazard in accordance with directve 1999/45/EEC 2.2. Label elements Detergent Labelling Labelling < 5% EDTA and salts thereof amphoteric surfactants non-ionic surfactants catonic surfactants Risk Phrases Safety Phrases Irritant R36/38 Irritatng to eyes and skin. S2 Keep out of the reach of children. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S46 If swallowed, seek medical advice immediately and show this container or label. S64 If swallowed, rinse mouth with water (only if the person is conscious). 1 / 8

2 2.3. Other hazards This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures TETRASODIUM ETHYLENE DIAMINE TETRAACETATE 1-5% CAS-No.: EC No.: Registraton Number: Classifcaton (EC 1272/2008) Acute Tox. 4 - H302 Eye Dam. 1 - H318 Classifcaton (67/548/EEC) Xn;R22 Xi;R41 SODIUM HYDROXIDE 1-5% CAS-No.: EC No.: Classifcaton (EC 1272/2008) Skin Corr. 1A - H314 Classifcaton (67/548/EEC) C;R35 ETHANEDIOL < 1% CAS-No.: EC No.: Classifcaton (EC 1272/2008) Acute Tox. 4 - H302 Classifcaton (67/548/EEC) Xn;R22 ALKYL BENZYL DIMETHYL AMMONIUM CHLORIDE < 1% CAS-No.: EC No.: Classifcaton (EC 1272/2008) Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Aquatc Acute 1 - H400 Classifcaton (67/548/EEC) Xn;R21/22. C;R34. N;R50. The Full Text for all R-Phrases and Hazard Statements are Displayed in Secton 16. SECTION 4: FIRST AID MEASURES 4.1. Descripton of frst aid measures Inhalaton Move the exposed person to fresh air at once. Get medical atenton if any discomfort contnues. Ingeston NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical atenton. Skin contact Remove afected person from source of contaminaton. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical atenton if irritaton persists afer washing. Eye contact Remove victm immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifing the eye lids. Contnue to rinse for at least 15 minutes and get medical atenton Most important symptoms and efects, both acute and delayed 2 / 8

3 Inhalaton. Irritaton of nose, throat and airway. Ingeston May cause discomfort if swallowed. May cause stomach pain or vomitng. Skin contact Skin irritaton. Eye contact Irritaton of eyes and mucous membranes Indicaton of any immediate medical atenton and special treatment needed No recommendaton given, but frst aid may stll be required in case of accidental exposure, inhalaton or ingeston of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extnguishing media Extnguishing media This product is not fammable. Use fre-extnguishing media appropriate for surrounding materials Special hazards arising from the substance or mixture Hazardous combuston products None under normal conditons Advice for frefghters Special Fire Fightng Procedures No specifc fre fghtng procedure given. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautons, protectve equipment and emergency procedures Wear protectve clothing as described in Secton 8 of this safety data sheet Environmental precautons Collect and dispose of spillage as indicated in secton 13. Avoid discharge to the aquatc environment Methods and material for containment and cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not let washing down water contaminate ponds or waterways Reference to other sectons For personal protecton, see secton 8. For waste disposal, see secton 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautons for safe handling Avoid spilling, skin and eye contact Conditons for safe storage, including any incompatbilites Store in closed original container at temperatures between 0 C and 40 C. Storage Class Chemical storage Specifc end use(s) The identfed uses for this product are detailed in Secton 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name ETHANEDIOL SODIUM HYDROXIDE STD TWA - 8 Hrs STEL - 15 Min WEL mg/m3(sk) mg/m3(sk) WEL 2 mg/m3 Notes WEL = Workplace Exposure Limit. 3 / 8

4 Ingredient Comments EU = Indicatve Values according to Commission Directve 91/322/EEC. TETRASODIUM ETHYLENE DIAMINE TETRAACETATE (CAS: ) DNEL Industry Inhalaton. Short Term Systemic Efects 2.8 mg/m3 Consumer Inhalaton. Short Term Systemic Efects 1.7 mg/m3 Consumer Oral Long Term Systemic Efects 28 mg/kg/day PNEC Freshwater 2.8 mg/l Marinewater 0.28 mg/l Intermitent release 1.6 mg/l STP 57 mg/l Soil 0.95 mg/kg 8.2. Exposure controls Protectve equipment Engineering measures Provide adequate ventlaton. Observe Occupatonal Exposure Limits and minimise the risk of inhalaton of vapours. Respiratory equipment No specifc recommendaton made, but respiratory protecton may stll be required under exceptonal circumstances when excessive air contaminaton exists. Hand protecton Use suitable protectve gloves if risk of skin contact. Eye protecton If risk of splashing, wear safety goggles or face shield. Other Protecton Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shif and before eatng, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Informaton on basic physical and chemical propertes Appearance Liquid Colour Reddish. Odour Characteristc. Solubility Soluble in water. Inital boiling point and boiling range Meltng point ( C) Relatve density Deg C Vapour pressure Evaporaton rate ph-value, Conc. Soluton Viscosity Decompositon temperature ( C) Odour Threshold, Lower Odour Threshold, Upper 4 / 8

5 Flash point Auto Igniton Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partton Coefcient (N-Octanol/Water) Explosive propertes Oxidising propertes Does not meet the criteria for oxidising Other informaton Not relevant SECTION 10: STABILITY AND REACTIVITY Reactvity Reacton with: Acids Chemical stability Stable under normal temperature conditons Possibility of hazardous reactons Conditons to avoid Avoid excessive heat for prolonged periods of tme. Avoid frost Incompatble materials Materials To Avoid Strong acids Hazardous decompositon products None under normal conditons. SECTION 11: TOXICOLOGICAL INFORMATION Informaton on toxicological efects Acute toxicity: Based on available data the classifcaton criteria are not met. Skin Corrosion/Irritaton: Slightly irritatng. Serious eye damage/irritaton: Based on available data the classifcaton criteria are not met. Respiratory or skin sensitsaton: Based on available data the classifcaton criteria are not met. Germ cell mutagenicity: Based on available data the classifcaton criteria are not met. Carcinogenicity: Does not contain any substances known to be carcinogenic. Reproductve Toxicity: Does not contain any substances known to be toxic to reproducton. Specifc target organ toxicity - single exposure: 5 / 8

6 Not classifed as a specifc target organ toxicant afer a single exposure. Specifc target organ toxicity - repeated exposure: Not classifed as a specifc target organ toxicant afer repeated exposure. Aspiraton hazard: Not antcipated to present an aspiraton hazard based on chemical structure. Inhalaton May cause irritaton to the respiratory system. Ingeston May cause discomfort if swallowed. Skin contact Irritatng to skin. Eye contact Irritatng to eyes. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product components are not classifed as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging efect on the environment. The product does not meet the requirement for classifcaton as an environmental hazard in accordance with directve 1999/45/EEC Toxicity The product does not meet the requirement for classifcaton as an environmental hazard in accordance with directve 1999/45/EEC Persistence and degradability Degradability The surfactant(s) contained in this preparaton complies(comply) with the biodegradability criteria as laid down in Regulaton (EC) No.648/2004 on detergents. Data to support this asserton are held at the disposal of the competent authorites of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer Bioaccumulatve potental Bioaccumulatve potental No data available on bioaccumulaton. Partton coefcient Mobility in soil Mobility: The product is soluble in water. The product is non-volatle Results of PBT and vpvb assessment None known Other adverse efects None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. No specifc disposal method required. Recover and reclaim or recycle, if practcal. SECTION 14: TRANSPORT INFORMATION General Road Transport Notes The product is not covered by internatonal regulaton on the transport of dangerous goods (IMDG, IATA, ADR/RID). Not Classifed 6 / 8

7 Rail Transport Notes Sea Transport Notes UN number UN proper shipping name Transport hazard class(es) Transport Labels Packing group Environmental hazards Not classifed. Not classifed. No transport warning sign required. Environmentally Hazardous Substance/Marine Pollutant No Special precautons for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulatons/legislaton specifc for the substance or mixture EU Legislaton Dangerous Substance Directve 67/548/EEC. Dangerous Preparatons Directve 1999/45/EC. Regulaton (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registraton, Evaluaton, Authorisaton and Restricton of Chemicals (REACH), establishing a European Chemicals Agency, amending Directve 1999/45/EC and repealing Council Regulaton (EEC) No 793/93 and Commission Regulaton (EC) No 1488/94 as well as Council Directve 76/769/EEC and Commission Directves 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulaton (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classifcaton, labelling and packaging of substances and mixtures, amending and repealing Directves 67/548/EEC and 1999/45/EC, and amending Regulaton (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION General informaton Only trained personnel should use this material. Revision Comments Revision of informaton Revision Date 15/02/2011 Risk Phrases In Full R34 Causes burns. R35 Causes severe burns. R22 Harmful if swallowed. R21/22 Harmful in contact with skin and if swallowed. R36/38 Irritatng to eyes and skin. R41 Risk of serious damage to eyes. R50 Very toxic to aquatc organisms. 7 / 8

8 Hazard Statements In Full H318 Causes serious eye damage. H319 Causes serious eye irritaton. H314 Causes severe skin burns and eye damage. H315 Causes skin irritaton. H302 Harmful if swallowed. H312 Harmful in contact with skin. H400 Very toxic to aquatc life. Notes for Risk Phrases and Hazard Statements in Full The full text for Risk Phrases and Hazard Statements in secton 16 relates to the reference numbers in sectons 2 and 3 and not necessarily the fnished product classifcaton. Disclaimer This informaton relates only to the specifc material designated and may not be valid for such material used in combinaton with any other materials or in any process. Such informaton is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representaton is made to its accuracy, reliability or completeness. It is the user's responsibility to satsfy himself as to the suitability of such informaton for his own partcular use. 8 / 8