MATERIAL SAFETY DATA SHEET

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1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Name of chemical material, etc.: ECO BLUE Company Name: Yamato Protec Corp. Address: Shiroganedai, Minato-ku, Tokyo, Japan Telephone number: (Navi dial) Department in charge: Technical support office Suggestion and limit on use: Experimental liquid for foam extinguishing equipments 2. Hazards Identification Classification: Important hazard: Characteristic hazard: GHS classification: Important sign: Hazard statements: 3. Composition, information on ingredients Substance or mixture: Name: Name Blue colorant (edible) Concentratio n range <0.01 % Mixture ECO BLUE CAS registry number Company secret GHS classification PRTR Law classified chemical Official gazette notification reference number Company secret Chemical property (Formula) Company secret 1/6

2 4. First aid measures After inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. After skin contact: Immediately wash skin with plenty of water. After eye contact: Immediately flush opened eyes with running water for at least 15 minutes. Get medical attention if necessary. After swallowing: Rinse mouth. Give plenty of water to drink and get medical advice. Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed: No further relevant information available. Most important symptoms and effects: No further relevant information available. Indication of any immediate medical attention and special treatment needed: No further relevant information available. Information for doctors:. 5. Fire-fighting measures Suitable Extinguishing agent: Prohibited extinguishing agent: Specific hazards: Specific methods of firefighting: Protection of firefighters: No specific measures are required as the product is not flammable.. Not classified Accidental release measures Personal precautions, protective equipment and emergency measures: Precautions for safe handling: May stain clothes. Environmental precautions: The agent is blue liquid. Decolor with oxidation decoloring as necessary. Collection and neutralization: Dispose of appropriately in accordance with related statements Methods and materials for containment and cleaning up: Refer to 13. Disposal considerations Equipment: Special equipment is not needed. Secondary disaster: secondary disaster. 2/6

3 7. Handling and storage Handling Design of technical systems: Ventilation/exhaustion: Statements: May stain clothes. Contact avoidance: Safety statements: Storage Design of technical systems: Substance avoiding contaminating: Storage condition: Keep container sealed. Do not mix with water or other agent. Packaging & container: Products container, applicable tank. Do not store the agent in container that cannot be sealed. 8. Exposure Controls and Personal Protection Permissible exposure limit (PEL): Threshold limit value (TVL): Personal protective equipment Breathing equipment: Protection of hands: Protection of eyes: Protection of skin and body:.. Wear impermeable gloves. Wear an appropriate eye protector. Wear appropriate protective clothing. 9. Physical/chemical properties Appearance: Blue transparent liquid Odor: 20 C: 7.0 Viscosity@ 20 C: 1.0 cp Boiling point/ Boiling range : 100 C Melting point/ Melting range: Decomposition temperature: Flash point: 3/6

4 Autoignition temperature: Flammability (solid, gaseous): Explosion limits: Vapor 20 C: Vapor density (Air=1): Evaporation rate: C (Relative gravity): 1.00 Solubility: Easily soluble in water Log P OW: 10. Stability and reactivity Stability: Reactivity: Possibility of hazardous reactions: Stable under normal handling conditions. Stable under normal handling conditions. No hazardous reactions under normal handling conditions. 11. Toxicological Information Hazard information: About indigocarmine Acute toxicity: LD 50 Oral - rat mg/kg Subacute toxicity: abnormality was confirmed after hypodermic injection of water solution of the dye with 250 mg/kg, twice a day for 3days. Reference Japanese Standard of Food Additives Carcinogenicity: The dye was given to mouse 1 mg/day for 500~700 days. No carcinogenicity was confirmed. However, fibrosarcoma was reported after long term of hypodermic injection of the dye. Reproductive toxicity: Positive in in vitro chromosomal aberration test. Negative in Ames test. Reference Hayashi et.al., Genes and Environment 22,27-44(2000) 4/6

5 12. Ecological information Ecotoxicity: Persistence/degradability: Bioaccumulation: Mobility in soil: Others Other adverse effect BOD : 1mg/L (3% aq.) Following JIS K COD : 2mg/L (3% aq.) Following JIS K Disposal considerations Waste The agent is blue liquid. Decolor with oxidation decoloring as necessary. Uncleaned packagings: Dispose after discharged the containing. Others: Dispose of appropriately in accordance with related laws, regulations and municipal requirements. 14. Transport information UN number: Name: UN hazardous class: UN packing group: Marine pollutant: Domestic regulation in Japan: Land transport regulation Aviation regulation Maritime regulation 5/6

6 15. Applicable laws and regulations Fire Service Act: Industrial Safety and Health Act: Poisonous and Deleterious Substances Control Act: Law concerning Pollutant Release and Transfer Register (PRTR Law): Others: 16. Other Information This MSDS is based on our present knowledge. However, Yamato Protec Corporation makes no warranty of any kind with respect to the information and data contained herein concerning the risk or hazardous nature. Thus, prior to the use of this product, you are requested to investigate the latest rules, ordinances and regulations of the country, region and related authorities, and follow them preferentially. You should be aware that all chemical substances may have potential unknown risk or hazards, which differs depending on the service environment as well as the condition and period of storage. It is thus recommended to handle the product under the supervision of a person having expertise or experience, during the usage as well as storage and disposal. Since the information provided herein relates only to normal use, in case of handling it under any special condition, you are requested to use it on your own responsibility after taking appropriate measures suitable to your service conditions. 6/6

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