: PX Lepto. Safety Data Sheet. H412 - Harmful to aquatic life with long lasting effects

Transcription

1 Date of issue: Version: 4 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : PX Lepto Type of product : Technical product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture : Professional use : For professional use only : Surface disinfectant Uses advised against 1.3. Details of the supplier of the safety data sheet Killgerm Chemicals Limited Wakefield Road Ossett West Yorkshire WF5 9AJ Tel: Technical@killgerm.com 1.4. Emergency telephone number Killgerm: (office hours between and 17.00) National Response Centre: National Poisons Information Service (Birmingham) City Hospital Dudley Road Birmingham, United Kingdom Tel: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information only Skin Corr. 1B H314 Aquatic Chronic 3 H412 Full text of hazard classes and H-statements: see section Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS05 : H314 - Causes severe skin burns and eye damage H412 - Harmful to aquatic life with long lasting effects : P260 - Do not breathe spray P264 - Wash hands thoroughly after handling P273 - Avoid release to the environment EN (English) 1/7

2 P280 - Wear eye protection, protective gloves P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P315 - Get immediate medical advice/attention P405 - Store locked up 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Alcohol Alkoxylate (CAS No) Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Quaternary ammonium compounds, benzyl-c12-16-alkyldimethyl, chlorides (CAS No) (EC no) (REACH-no) N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine (CAS No) (EC no) (REACH-no) Didecyldimethylammonium chloride (CAS No) (EC no) (EC index no) Chlorhexidine digluconate (CAS No) (EC no) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Corr. 1B, H314 Aquatic Acute 1, H Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 <1 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1. H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. : Wash with plenty of soap and water. Take off immediately all contaminated clothing and wash it before reuse. : Immediately rinse with water for a prolonged period while holding the eyelids wide open. Get immediate medical advice/attention. : Do NOT induce vomiting. Rinse mouth. Drink plenty of water. Get medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause respiratory irritation. : Burns. : Causes serious eye damage. : Burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire 5.3. Advice for firefighters : Carbon dioxide. Dry powder. Foam. : Corrosive vapours. EN (English) 2/7

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Evacuate unnecessary personnel. : Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Collect spillage and dispose of in accordance with local and national legislation Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible Reference to other sections For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Hygiene measures : Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Technical measures : Does not require any specific or particular technical measures. Storage conditions : Keep container closed when not in use. Incompatible products : Oxidizing agent. Strong acids. Strong bases. Incompatible materials : Metals. Special rules on packaging : Keep only in original container Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Not required for normal conditions of use : Protective gloves : Safety glasses : Not required for normal conditions of use : Not required for normal conditions of use SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear blue liquid, free from extraneous matter. Colour : Blue. Odour : Eucalyptus Menthol. Odour threshold ph : 7 Relative evaporation rate (butylacetate=1) : As water Melting point Freezing point : As water Boiling point : As water EN (English) 3/7

4 Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 1 Solubility : Miscible with water Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions. Product has a three year shelf life from date of manufacture Possibility of hazardous reactions Conditions to avoid Incompatible materials Metals Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard : Causes severe skin burns and eye damage. ph: 7 : Serious eye damage, category 1, implicit ph: 7 SECTION 12: Ecological information Toxicity Alcohol Alkoxylate ( ) LC50 fish 1 EC50 Daphnia 1 ErC50 (other aquatic plants) > mg/l > mg/l > mg/l Quaternary ammonium compounds, benzyl-c12-16-alkyldimethyl, chlorides ( ) ErC50 (algae) < 10 mg/l EN (English) 4/7

5 12.2. Persistence and degradability Bioaccumulative potential Chlorhexidine digluconate ( ) Log Pow Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA UN number UN proper shipping name CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. Transport document description UN 1760 CORROSIVE LIQUID, N.O.S. (QUATERNARY AMMONIUM COMPOUNDS), 8, III, (E) UN 1760 CORROSIVE LIQUID, N.O.S., 8, III Transport hazard class(es) Packing group III III III Environmental hazards Dangerous for the environment : No Special precautions for user - Overland transport Classification code (ADR) Dangerous for the environment: No Marine pollutant: No : C9 Special provisions (ADR) : 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5l : E1 No supplementary information available : P001, IBC03, LP01, R001 : MP19 : T7 : TP1, TP28 : L4BN : AT Transport category (ADR) : 3 Dangerous for the environment: No EN (English) 5/7

6 Special provisions for carriage - Packages (ADR) : V12 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) EAC code APP code : E : 2X : B - Transport by sea Special provisions (IMDG) : 223, 274 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP28 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A - Air transport PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y841 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 852 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 856 CAO max net quantity (IATA) : 60L Special provisions (IATA) : A3 ERG code (IATA) : 8L Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IBC code : Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substance National regulations Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B EN (English) 6/7

7 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H301 Toxic if swallowed H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects SDS EU This data sheet does not constitute a COSHH assessment. The information contained within this data sheet is strictly for general guidance only and should not be relied upon over and above this. This data sheet is intended to provide general health and safety guidance on the handling, storage and transportation of the preparation. The information provided in this data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted by Killgerm Chemicals Limited for any loss, injury or damage arising from any failure to comply with the information and advice contained within this data sheet and/or failure to comply with the manufacturer s guidelines, product label data and any associated technical usage literature. EN (English) 7/7