: Clever Wash. Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue: 24/06/2015 Revision date: : Version: 1.

Transcription

1 Safety Data Sheet according Date of issue: 24/06/2015 Revision date: : Version: 1.21 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Clever Wash Product group : Blend 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet SoftWash UK Ltd 20 Alderlands Close PE6 0BS Cambridgeshire - United Kingdom T mark@softwashing.uk Emergency telephone number Emergency number : Country Organisation/Company Address Emergency number UNITED KINGDOM National Poisons Information Service Dudley Road (UK only) B18 7QH Birmingham (Birmingham Centre) City Hospital SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1 Skin Irrit. 2 Eye Irrit. 2 Full text of H-phrases: see section 16 H315 H319 Classification according to Directive 67/548/EEC or 1999/45/EC Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : H315 - Causes skin irritation H319 - Causes serious eye irritation : P264 - Wash... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN: Wash with plenty of water/ P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment (see... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse 24/06/2015 EN (English) 1/7

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC quaternary ammonium compounds, benzyl-c8-18- alkyldimethyl, chlorides (CAS No) (EC no) (EC index no) Xn; R21/22 C; R34 N; R50 Amines, C12-14 (even numbered)-alkyldimethyl, N-oxides (CAS No) (EC no) (REACH-no) Xn; R22 Xi; R41 Xi; R38 N; R50 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] quaternary ammonium compounds, benzyl-c8-18- alkyldimethyl, chlorides (CAS No) (EC no) (EC index no) Amines, C12-14 (even numbered)-alkyldimethyl, N-oxides (CAS No) (EC no) (REACH-no) Full text of R- and H-phrases: see section 16 1 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Aquatic Acute 1, H400 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see... on this label). : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 24/06/2015 EN (English) 2/7

3 For emergency responders Protective equipment Emergency procedures : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store aways from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Wash... thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear appropriate mask : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid. Colour : clear. Odour : lemon-like. Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point : < 0 C Freezing point Boiling point : > 100 C Flash point : > 94 C Self ignition temperature Decomposition temperature Flammability (solid, gas) n flammable. Vapour pressure Relative vapour density at 20 C Relative density 24/06/2015 EN (English) 3/7

4 Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : g/m³ : Fully Miscible. : 18 cp 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : Causes skin irritation. ph: : Causes serious eye irritation. ph: :. SECTION 12: Ecological information Toxicity Persistence and degradability Clever Wash Persistence and degradability 24/06/2015 EN (English) 4/7

5 12.3. Bioaccumulative potential Cleverwash Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA UN number No dangerous good in sense of transport regulations UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available 24/06/2015 EN (English) 5/7

6 14.6. Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Not subjected to ADN Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Cleverwash is not on the REACH Candidate List Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ne. Full text of R-, H- and EUH-phrases:: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment AcuteHazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H319 Causes serious eye irritation H400 Very toxic to aquatic life R21/22 Harmful in contact with skin and if swallowed R22 Harmful if swallowed R34 Causes burns R38 Irritating to skin R41 Risk of serious damage to eyes R50 Very toxic to aquatic organisms C Corrosive N Dangerous for the environment Xi Irritant Xn Harmful SDS EU (REACH Annex II) 24/06/2015 EN (English) 6/7

7 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 24/06/2015 EN (English) 7/7