1.4. Emergency telephone number Emergency number : SGS Country Organisation/Company Address Emergency number Comment
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1 Date of issue: Revision date: Supersedes: Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixtures Name : HYPRO TECHNICAL Product code : HY011 Type of product : Technical product Product group : Blend 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Function or use category : Industrial use : Industrial For professional use only : Oxidizing agents, 55/999 Others Uses advised against 1.3. Details of the supplier of the safety data sheet SOPURA Rue de Trazegnies, COURCELLES - BELGIUM T sales@sopura.com 1.4. Emergency telephone number Emergency number : SGS Country Organisation/Company Address Emergency number Comment Ireland National Poisons Information PO Box Beaumont Road Centre 9 Dublin ' Beaumont Hospital (public, 8am - 10pm, 7/7) United Kingdom National Poisons Information Service (Belfast Centre) Royal Victoria Hospital SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Grosvenor Road BT12 6BA Belfast (UK only, Monday to Friday, to hours) Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Serious eye damage/eye irritation, Category 2 Full text of H statements : see section 16 H319 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : Hydrogen peroxide solution : H319 - Causes serious eye irritation : P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear eye protection, protective clothing, protective gloves EN (English) SDS Ref.: /6
2 P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Hydrogen peroxide solution (CAS No) (EC no) (EC index no) (REACH-no) <= 7 Ox. Liq. 1, H271 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Oral), H302 Skin Corr. 1A, H314 Specific concentration limits: Name Product identifier Specific concentration limits Hydrogen peroxide solution (CAS No) (EC no) (EC index no) (REACH-no) Full text of H-statements: see section 16 ( 5 =<C < 8) Eye Irrit. 2, H319 ( 8 =<C < 50) Eye Dam. 1, H318 (C >= 35) STOT SE 3, H335 ( 35 =<C < 50) Skin Irrit. 2, H315 ( 50 =<C < 70) Skin Corr. 1B, H314 ( 50 =<C < 70) Ox. Liq. 2, H272 (C >= 70) Skin Corr. 1A, H314 (C >= 70) Ox. Liq. 1, H271 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Heating may cause an explosion Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. DO NOT fight fire when fire reaches explosives. Evacuate area. : Do not enter fire area without proper protective equipment, including respiratory protection EN (English) SDS Ref.: /6
3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. No open flames. No smoking. Use special care to avoid static electric charges For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials Maximum storage period 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Hazardous waste due to potential risk of explosion. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Keep away from sources of ignition - No smoking. No open flames. No smoking. : Wash hands, forearms and face thoroughly after handling. : Proper grounding procedures to avoid static electricity should be followed. : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, Heat sources. Keep container closed when not in use. Keep in fireproof place. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. Heat sources. : 18 months SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Colourless liquid EN (English) SDS Ref.: /6
4 Colour Odour Odour threshold : Colourless. ph : 2,3 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability : characteristic. : Non flammable : Heating may cause an explosion. Heating may cause an explosion. Extreme risk of explosion by shock, friction, fire or other sources of ignition Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity ph: 2,3 : Causes serious eye irritation. ph: 2,3 Based on available data, the classification criteria are not met EN (English) SDS Ref.: /6
5 STOT-single exposure STOT-repeated exposure Aspiration hazard Potential adverse human health effects and symptoms. SECTION 12: Ecological information Toxicity Persistence and degradability HYPRO TECHNICAL Persistence and degradability Hydrogen peroxide solution ( ) Persistence and degradability Bioaccumulative potential HYPRO TECHNICAL Bioaccumulative potential Hydrogen peroxide solution ( ) Log Pow -1,57 Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose in a safe manner in accordance with local/national regulations. : Hazardous waste due to potential risk of explosion. : Avoid release to the environment. ADR IMDG IATA ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available EN (English) SDS Ref.: /6
6 14.6. Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Ox. Liq. 1 Oxidising Liquids, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A H271 May cause fire or explosion; strong oxidiser H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H319 Causes serious eye irritation H332 Harmful if inhaled Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: Eye Irrit. 2 H319 Calculation method applicable for regions : GB - United Kingdom;IE - Ireland SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) SDS Ref.: /6
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