Extreme Green 16 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Transcription

1 SECTION 1: Identification 1.1. Identification Product form : Mixture Product name : Extreme Green 16 Product code : M Recommended use and restrictions on use 1.3. Supplier JR Simplot Company P.O. Box Boise, ID T Emergency telephone number Emergency number : CHEMTREC SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Acute toxicity (oral) Category 4 Skin corrosion/irritation Category 1A H302 H314 Full text of H statements : see section 16 Harmful if swallowed Causes severe skin burns and eye damage 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) Not applicable : H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage : P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash hands, forearms and face thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P312 - If swallowed: Call a poison center/doctor/ if you feel unwell P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor/ P321 - Specific treatment (see... on this label) P330 - Rinse mouth P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/container to... in accordance with local/regional/national regulations 07/03/2018 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification Full text of hazard classes and H-statements : see section 16 Not classified SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove person to fresh air and keep comfortable for breathing. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. Allow victim to breathe fresh air. Allow the victim to rest. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a poison center or doctor/physician. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Immediately call a poison center or doctor/physician. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and symptoms Symptoms/injuries Symptoms/injuries after ingestion 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Based on available data, the classification criteria are not met. Harmful if swallowed. : Causes severe skin burns and eye damage. Not expected to present a significant hazard under anticipated conditions of normal use. : Swallowing a small quantity of this material will result in serious health hazard. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures : Thermal decomposition generates : Corrosive vapors Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". : Ventilate area. 07/03/2018 EN (English US) 2/7

3 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections : Recover mechanically the product. On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Dispose of materials or solid residues at an authorized site. See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact during pregnancy/while nursing. : Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Store in a well-ventilated place. Keep cool. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. Storage temperature : >= 25 (5-42) C SECTION 8: Exposure controls/personal protection 8.1. Control parameters Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves Eye protection: Chemical goggles or face shield. Chemical goggles or safety glasses. Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask : Do not eat, drink or smoke during use. 07/03/2018 EN (English US) 3/7

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold : Solid : Green ph : <= 2 Melting point : Characteristic odour Freezing point : <= 0 C Boiling point : >= 100 C Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties : None : Non flammable. : Soluble in water VOC content : <= 10 g/l SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapors Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapors. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Extreme Green 16 ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation mg/kg body weight : Causes severe skin burns and eye damage. ph: <= 2. ph: <= 2 07/03/2018 EN (English US) 4/7

5 Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries Symptoms/injuries after ingestion SECTION 12: Ecological information Toxicity Ecology - general Ecology - water Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met. Harmful if swallowed. : Causes severe skin burns and eye damage. Not expected to present a significant hazard under anticipated conditions of normal use. : Swallowing a small quantity of this material will result in serious health hazard. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. : Toxic to aquatic life Persistence and degradability Extreme Green 16 Persistence and degradability Persistence and degradability Bioaccumulative potential Extreme Green 16 Bioaccumulative potential Bioaccumulative potential Mobility in soil Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to... : Avoid release to the environment. 07/03/2018 EN (English US) 5/7

6 SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT : No supplementary information available. TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: CAS No % International regulations CANADA Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List) EU-Regulations National regulations US State regulations SECTION 16: Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H-phrases: H302 H314 NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard Harmful if swallowed Causes severe skin burns and eye damage : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. : None 07/03/2018 EN (English US) 6/7

7 HMIS III Rating Health Flammability Physical Personal Protection : 2 Moderate Hazard - Temporary or minor injury may occur : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : C C - Safety glasses, Gloves, Synthetic apron SDS US (GHS HazCom 2012) Disclaimer: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION HEREIN PROVIDED. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement. 07/03/2018 EN (English US) 7/7