SAFETY DATA SHEET According to Safe Work Australia

Transcription

1 Page 1/6 1. IDENTIFICATION: PRODUCT IDENTIFIER AND CHEMICAL IDENTITY Other Name: Pymatic metered aerosol, Coopermatic, Time Mist Recommended Use of the Chemical and Restriction on Use: Metered insecticide to suit Syncromist and Coopermatic insecticide dispensers Details of Manufacturer or Importer: C.Rudduck Pty Ltd 2/247 Ingles Street Port Melbourne VIC 3207 Phone Number: Emergency telephone number: HAZARDS IDENTIFICATION Hazardous Nature: GHS02 flame Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurized container: may burst if heated. GHS08 health hazard Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. Label Elements Signal Word Danger Hazard Statements H222-H229 Extremely flammable aerosol. Pressurized container: may burst if heated. H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. Precautionary Statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P211 Do not spray on an open flame or other ignition source. P273 Avoid release to the environment. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P405 Store locked up. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50 C/122 F. P501 Dispose of contents/container in accordance with local/regional/national regulations. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Chemical Characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. (Contd. on page 2)

2 Page 2/6 Hazardous Components: Petroleum gases, liquefied Flam. Gas 1, H220; Flam. Liq. 1, H224; Press. Gas, H Naphtha (petroleum), hydrotreated heavy Asp. Tox. 1, H304; H (2-butoxyethoxy)ethyl 6-propylpiperonylether Acute Tox. 3, H331; Aquatic Chronic 2, H411; Acute Tox. 5, H313 Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 4, H FIRST AID MEASURES (Contd. of page 1) 30-60% 10-30% 1-9% 1-3% Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention if breathing problems develop. Skin Contact: In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and soap. Seek medical attention if symptoms occur. Eye Contact: In case of eye contact, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention. Ingestion: If swallowed, do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Do not give anything by mouth to an unconscious person. Seek immediate medical attention. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Carbon dioxide, dry chemical and foam. Specific Hazards Arising from the Chemical Closed containers may explode when exposed to extreme heat. Use water sprays to cool fire exposed containers. Special Protective Equipment and Precautions for Fire Fighters Wear Safe Work Australia approved self-contained breathing apparatus and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: Wear Safe Work Australia approved self-contained breathing apparatus and full protective clothing. Evacuate all non-essential personnel from affected area. Do not breathe vapours. Shut off all possible sources of ignition and increase ventilation. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Environmental Precautions: In the event of a major spill, prevent spillage from entering drains or water courses. Methods and Materials for Containment and Cleaning Up: Stop leak if safe to do so and absorb spill with sand, earth, vermiculite or some other absorbent material. Collect the spilled material and place into a container outdoors, away from ignition sources, until pressure has dissipated. Ensure adequate ventilation. (Contd. on page 3)

3 Page 3/6 7. HANDLING AND STORAGE (Contd. of page 2) Precautions for Safe Handling: Use of safe work practices are recommended to avoid eye or skin contact and inhalation of vapours. Use in a well-ventilated area. DO NOT incinerate or puncture aerosol cans. Food, beverages and tobacco products should not be stored or consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close proximity to points of potential exposure. Conditions for Safe Storage: Store in a cool, dry and well ventilated area. Protect from heat, sparks, open flames and hot surfaces. DO NOT incinerate or puncture aerosol cans. Avoid physical damage to containers. Check regularly for spills and leaks. Store at temperatures below 40 C. Keep away from strong oxidising agents. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Standards (Safe Work Australia): Petroleum gases, liquefied NES 1800 mg/m³, 1000 ppm NES 5 mg/m³ Engineering Contols: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapour below occupational exposure standards. Personal Protective Equipment (PPE): Respiratory Protection: Respiratory protection is not necessary if the ventilation is adequate. Avoid working in and breathing spray mist. Skin Protection: Impermeable gloves and protective clothing. See Australian Standards AS/NZS 2161, and for more information. Eye and Face Protection: Safety glasses with top and side shields or goggles. See Australian Standards AS/NZS 1336 and 1337 for more information. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Form: Aerosol Colour: Clear Odour: Spearmint odour Initial Boiling Point/Boiling Range: Flash Point: Not applicable, as aerosol. Flammability: Extremely flammable aerosol Auto-ignition Temperature: Decomposition Temperature: Explosion Limits: Lower: Upper: Vapour Pressure: psi (Contd. on page 4)

4 Page 4/6 Relative Density: Vapour Density: Solubility in Water: Immiscible VOC: 98 % 10. STABILITY AND REACTIVITY (Contd. of page 3) Possibility of Hazardous Reactions: Hazardous polymerisation will not occur. Chemical Stability: Stable at ambient temperature and under normal conditions of use. Conditions to Avoid: Heat, sparks, open flames and hot surfaces. Incompatible Materials: Strong oxidising agents Hazardous Decomposition Products: 11. TOXICOLOGICAL INFORMATION Toxicity: LD₅₀/LC₅₀ Values Relevant for Classification: Naphtha (petroleum), hydrotreated heavy Oral LD₅₀ >5000 mg/kg (rat) Dermal LD₅₀ >3000 mg/kg (rab) (2-butoxyethoxy)ethyl 6-propylpiperonylether Oral LD₅₀ 7181 mg/kg (rat) Dermal LD₅₀ >2000 mg/kg (rabbit) Inhalation LC₅₀/4 h >5.9 mg/l (rat) Oral LD₅₀ 200 mg/kg mg/kg (rat) Dermal LD₅₀ 300 mg/kg mg/kg (rabbit) Acute Health Effects Inhalation: May cause respiratory irritation, dizziness or headache. Intentional misuse by deliberately inhaling content can be fatal. Skin: May cause skin irritation and defatting. Eye: May cause eye irritation. Ingestion: May cause nausea, abdominal irritation, vomiting and pain. Skin Corrosion / Irritation: Not expected to be a hazard. Serious Eye Damage / Irritation: Not expected to be a hazard. Respiratory or Skin Sensitisation: No sensitising effects known. Germ Cell Mutagenicity: Carcinogenicity: Piperonyl butoxide is classified by IARC as a Group 3 - Not classifiable as to its carcinogenicity to humans. Reproductive Toxicity: Specific Target Organ Toxicity (STOT) - Single Exposure: Not expected to be a hazard. Specific Target Organ Toxicity (STOT) - Repeated Exposure: Not expected to be a hazard. Aspiration Hazard: May be fatal if swallowed and enters airways. (Contd. on page 5)

5 Page 5/6 Chronic Health Effects: Prolonged or repeated exposure may cause dizziness and headache. 12. ECOLOGICAL INFORMATION Ecotoxicity: Aquatic toxicity: Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Persistence and Degradability: No further relevant information available. Bioaccumulative Potential: No further relevant information available. Mobility in Soil: No further relevant information available. 13. DISPOSAL CONSIDERATIONS Disposal Methods and Containers: Dispose according to applicable local and state government regulations. DO NOT incinerate or puncture aerosol cans. Special Precautions for Landfill or Incineration: Please consult your state Land Waste Management Authority for more information. 14. TRANSPORT INFORMATION UN Number ADG, IMDG, IATA 1950 Proper Shipping Name AEROSOLS Dangerous Goods Class ADG Class: 2 5F Gases. IMDG Class: 2.1 Packing Group: Not applicable EMS Number: F-D,S-U Hazchem Code: 2YE Special Provisions: 63, 190, 277, 327 Limited Quantities: See SP 277 Packagings & IBCs - Packing Instruction: P003, LP02 Packagings & IBCs - Special Packing Provisions: PP17, PP87, L2 15. REGULATORY INFORMATION Australian Inventory of Chemical Substances: Petroleum gases, liquefied Naphtha (petroleum), hydrotreated heavy (2-butoxyethoxy)ethyl 6-propylpiperonylether 16. OTHER INFORMATION (Contd. of page 4) Creation Date: (Contd. on page 6)

6 Page 6/6 Prepared by: MSDS.COM.AU Pty Ltd Abbreviations and acronyms: ADG: Australian Dangerous Goods IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals VOC: Volatile Organic Compounds LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent IARC: International Agency for Research on Cancer STEL: Short Term Exposure Limit TWA: Time Weighted Average (Contd. of page 5) Disclaimer This MSDS is prepared in accord with the Safe Work Australia document Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals - December 2011 The information contained in this material safety data sheet is provided in good faith and is believed to be accurate at the date of issuance. C.Rudduck Pty Ltd makes no representation of the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or damage related to the supply or use of the information in this material safety data sheet. MSDS.COM.AU Pty Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own determinations as to the suitability of the information provided to the particular circumstances in which the product is used.