: DWT 1108L Metal Scavenger
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1 Date of issue: 05/19/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : : DWT 1108L Metal Scavenger 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Dober Chemical Corp Katherine's Crossing Suite 100 Woodridge, IL US T F regulatory@dobergroup.com Emergency telephone number : Water Treatment Agent Emergency number : / ChemTel SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Corr. 1A H314 Full text of H-phrases: see section Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS05 : H314 - Causes severe skin burns and eye damage : P260 - Do not breathe dust/fume/gas/mist/vapours/spray P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor P321 - Specific treatment (see First aid measures on this label) P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) 05/19/2015 EN (English) Page 1
2 SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification Sodium trithiocarbonate (CAS No) Skin Corr. 1B, H314 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. : Causes severe skin burns and eye damage Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapours Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 05/19/2015 EN (English) 2/6
3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. No smoking. : Wash hands, forearms and face thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Comply with applicable regulations. : Keep only in the original container in a cool, well-ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters DWT 1108L Metal Scavenger ACGIH : Sources of ignition. Direct sunlight. OSHA Sodium trithiocarbonate ( ) ACGIH OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection Other information : Wear protective gloves/protective clothing/eye protection/face protection protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : red Odour : Sulfur Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point Freezing point : 0 C Boiling point Flash point : 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : 2.33 kpa 05/19/2015 EN (English) 3/6
4 Relative vapour density at 20 C : 1 Relative density : Density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products : g/ml : Water: Not available : Not Available. Fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms : Causes severe skin burns and eye damage. ph: ph: : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity 05/19/2015 EN (English) 4/6
5 12.2. Persistence and degradability DWT 1108L Metal Scavenger Persistence and degradability Bioaccumulative potential DWT 1108L Metal Scavenger Bioaccumulative potential Mobility in soil Other adverse effects Effect on the global warming Other information : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information UN-No.(DOT) : UN UN proper shipping name Proper Shipping Name (DOT) : Corrosive liquid, basic, inorganic, n.o.s. (Sodium Trithiocarbonate) Transport hazard class(es) Department of Transportation (DOT) Hazard Classes Hazard labels (DOT) : 8 : 8 - Corrosive : Packing group Packing group (DOT) : III Environmental hazards Marine pollutant(dot) : No SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory 05/19/2015 EN (English) 5/6
6 This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA Sodium trithiocarbonate ( ) Listed on the Canadian DSL (Domestic Sustances List) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm SECTION 16: Other information Other information : None. Full text of H-phrases:: Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Corr. 1B Skin corrosion/irritation, Category 1B H314 Causes severe skin burns and eye damage NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. : COR - Corrosive HMIS III Rating Health : 2 - Temporary or minor injury may occur Flammability : 0 Physical : 0 Personal Protection : C Dober SDS US To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 05/19/2015 EN (English) 6/6
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