MATERIAL SAFETY DATA SHEET ADAMS FLEA & TICK COLLAR FOR DOGS. 1. Product and Company Identification
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1 1 Flammability Health 2 Instability Special Hazard Date Created: 12/07/ Product and Company Identification Product Code: AD Product Name: Manufacturer Information Company Name: Distributed by: Emergency Contact: Farnam Companies, Inc. 301 West Osborn Road Phoenix, AZ CHEMTREC (800) Alternate Emergency Contact: District of Columbia (202) Information: Farnam Companies, Inc. (800) Preparer Name: Additional Identity Information SFaith/Regulatory Small dog ( ), Large dog ( ) Hazardous Components (Chemical Name) CAS # 1. Propoxur Composition/Information on Ingredients Concentration OSHA PEL ACGIH TLV 10.0 % No data. 0.5 mg/m3 3. Hazards Identification Emergency Overview KEEP OUT OF REACH OF CHILDREN PRECAUTIORY STATEMENT EMERGENCY OVERVIEW: Caution: Do not allow children to play with this collar. Do not open protective pouch until ready to use. Dust will form on this collar during storage. Do not get dust or collar in mouth; harmful if swallowed. Do not get in eyes; will cause temporary pupillary constriction. The dust released by this collar is a cholinesterase inhibitor. Wash hands thoroughly with soap and water after handling. Route(s) of Entry: Inhalation? No Skin? Yes Eyes? Yes Ingestion? N.A. Potential Health Effects (Acute and Chronic) Due to product form, method of use, and use history, human intoxication has not been reported. However, Propoxur is a cholinesterase inhibitor that may produce the following symptoms: headache, nausea, vomiting, diarrhea, tightness in chest, ataxia, anorexia, tearing, sweating, salivation, pin-point pupils, pulmonary edema, cyanosis, convulsions. Recommended Exposure Limits Not established except for Propoxur: 0.5 mg/m3 (OSHA PEL & ACGIH TLV). LD 50 / LC 50 Oral: LD50 (rat): >68 mg/kg (Propoxur) Dermal: LD50 (rabbit): >2.000 mg/kg (Propoxur) Inhalation: LC50 (rat): 0.5 mg/l (4 hour study) (Propoxur)
2 Signs and Symptoms Of Exposure Skin Irritation: Minimally irritating. Eye Irritation: Mildly irritating. Sensitizer: Not a sensitizer. Medical Conditions Generally Aggravated By Exposure MATERIAL SAFETY DATA SHEET 4. First Aid Measures Emergency and First Aid Procedures Eye: Hold eye open and rinse slowly and gently for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. Ingestion: Call a poison control center or doctor immediately for treatment advice. Have a person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison center or doctor. Do not give anything by mouth to an unconscious person. Inhalation: Remove victim to fresh air. 2 Note to Physician Contains an N-methyl carbamate that inhibits cholinesterase. Atropine is antidotal only if symptoms of cholinesterase inhibition are present. Flammability Classification: Flash Pt: 5. Fire Fighting Measures Combustible solid Explosive Limits: Autoignition Pt: LEL: No data. UEL: No data. Fire Fighting Instructions Normal procedures. Do not allow fire fighting water to escape into water-ways or sewers. Flammable Properties and Hazards None known. Hazardous Combustion Products Highly irritating methyl isocyanate gas and fumes of hydrogen chloride can be formed during burning. Extinguishing Media Water fog, foam, CO2. Unsuitable Extinguishing Media None known Additional Fire Fighting Information Firefighters should wear full protective clothing including self-contained breathing apparatus. 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled Because of individual packaging, possibilities of a release or spill are remote. However, should one occur, place in container for proper disposal. Do not allow large quantities to enter waterways. Additional Accidental Spill Information Absorbents: None necessary due to product form.
3 7. Handling and Storage Precautions To Be Taken in Handling Wash hands and face thoroughly with soap and water after handling product. If collar is temporarily removed, wrap in paper or plastic; do not allow children to have access to collar. Precautions To Be Taken in Storing Store in original unopened container away from children. Do not open protective pouch until ready to use. Other Precautions If extensive exposure is anticipated, users and handlers should wear a MSHA/NIOSH approved organic vapor/dust/pesticide respirator, impervious gloves, goggles, and other appropriate clothing to prevent skin contact. 8. Exposure Controls/Personal Protection Respiratory Equipment (Specify Type) If extensive exposure is anticipated, users and handlers should wear a NIOSH approved organic vapor/dust/pesticide respirator. Eye Protection Protective Gloves Other Protective Clothing If extensive exposure is anticipated, users and handlers should wear impervious gloves, goggles, and other appropriate clothing to prevent skin contact. Engineering Controls (Ventilation etc.) Natural ventilation is sufficient. Work/Hygienic/Maintenance Practices Wash hands before eating, drinking, smoking, or using restroom. Physical States: Melting Point: Boiling Point: Autoignition Pt: Flash Pt: Specific Gravity (Water = 1): Vapor Pressure (vs. Air or mm Hg): Vapor Density (vs. Air = 1): Evaporation Rate (vs Butyl Acetate=1): 9. Physical and Chemical Properties [ ] Gas [ ] Liquid [ X ] Solid C mpa at 20.0 C Solubility in Water: Solubility Notes 0.2 at 20.0 C Slightly soluble in water (0.2% at 20C). Percent Volatile: N.A. Appearance and Odor Plastic strips with powdery surface, faint phenolic odor. 3
4 10. Stability and Reactivity Stability: Conditions To Avoid - Instability None known Incompatibility - Materials To Avoid Strong acids, strong oxidizers. Unstable [ ] Stable [ X ] Hazardous Decomposition Or Byproducts Methyl isocyanate gas, toxic fumes of C1, oxides of nitrogen can be formed on burning. Hazardous Polymerization: Will occur [ ] Will not occur [ X ] Conditions To Avoid - Hazardous Polymerization 11. Toxicological Information CHRONIC TOXICITY [Specific to Active Ingredient(s)] In a combined chronic/carcinogenicity toxicity study, rats were fed doses at a maximum 5,000 ppm ( mg/kg/day) for up to 2 years. The NOEL was 200 ppm (8.2 mg/kg/day for males and 11.0 mg/kg/day for females) based on reduced weight gain and urinary bladder hyperplasia. Propoxur is highly toxic to honey bees. DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)] In a developmental toxicity study in rabbits, animals were orally dosed at concentrations up to 30 mg/kg/day. The NOEL for maternal and developmental toxicity was 10 mg/kg/day based on fetal body weight. MUTAGENICITY [Specific to Active Ingredient(s)] The weight of evidence suggests that Propoxur is not a mutagen. 4 Chronic Toxicological Effects Carcinogenicity/Other Information ACCORDING TO CALIFORNIA PROPOSITION 65, THIS PRODUCT CONTAINS PROPOXUR, A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. Hazardous Components (Chemical Name) CAS # 1. Propoxur Carcinogenicity: NTP IARC ACGIH OSHA A3 NTP? No IARC Monographs? No OSHA Regulated? No 12. Ecological Information ENVIRONMENTAL FATE [Based on (RS)-Methoprene Technical] Hydrolysis: T1/2 > 4 weeks (Methoprene). Photolysis: T1/2 < 10 hours (Methoprene). Soil half life: ~ 10 days (Methoprene). Water solubility: < 2 ppm (Methoprene). Propoxur is highly toxic to bees. ECOTOXICITY [Active Ingredients Only] Acute Toxicity: Propoxur: Fish:LC50 (trout): 3.7 ppm (96 hour study). Aquatic invertebrates: Daphnia: EC50: 0.15 mg/l (48-hr). S-Methoprene: Fish: LC50 (trout): 760 ppb, (bluegill): > 370 ppb. Aquatic invertebrates: LC50 (Daphnia): 360 ppb. Highly toxic to Daphnia.
5 13. Disposal Considerations Waste Disposal Method Do not reuse container or collar. Dispose of in trash. Do not contaminate water, feed or food by disposal. If household waste, wrap and put in trash. For larger quantities: dispose of at a state/epa approved hazardous waste facility. RCRA Waste ID Code: U Transport Information LAND TRANSPORT (US DOT) DOT Proper Shipping Name Not regulated as hazardous by D.O.T. Additional Transport Information Freight classification: Collars, animal insect repellent, in individual retail containers in boxes: NMFC Sub 1 Class 100. In individual paper and foil laminated pouches other than individual retail containers, in boxes: NMFC Sub 2 Class Regulatory Information 16. Other Information CERCLA (Superfund): Reportable Quantity (RQ): Propoxur = 100 lb. RCRA: Not regulated in this product form. Propoxur - U411. Company Policy or Disclaimer The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification. 5
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Safety Data Sheet 1452SYM
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*MATERIAL SAFETY DATA SHEET*
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SAFETY DATA SHEET <TITLE >
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S A F E T Y D A T A S H E E T
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Issue Date: 31-Oct-2012 Revision Date: 02-Nov-2012 Version 1 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION. Physical State Liquid
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