MATERIAL SAFETY DATA SHEET

Transcription

1 Fiber ProTector - Water Based MSDS Date: 7/16/2013 secrlon l: PRoDUcr AND company tdenttfrcatton Product name Product use Supplier Transport Emergency Fiber ProTector - Water Based Fabric Protection Fiber ProTector America, LLC I I OO Jones Street Little Rock, AR Te! Fax CHEMTREC: (outside the U.S t SECTION 2: COMPOSITTON/INFORMATION on INGREDIENTS Component CAS-No. Concentration Water 7732-tA-S 74-At% Fruor,nated Acrylic copolymer l9-26% Tetramethyl succinonitrile 3333-s2-5 o.oo3 - o.o1% SECTION 3: HAZARDS IDENT F CATION Emergency Overview The hazards of this product are associated mainly with its processing. lnhalation of decomposition products in high concentration may cause shortness of breath (lung oedema). l-nhalation of aerosot or fine splay 1nlsi may cause serious respiratory problems. Potentia! Health Effects Eyes : May cause eye irritation. May cause: Tearing, Redness, Discomfort. Inhalation lngestion lnhalation of decomposition products in high concentration may cause shortness of breath (lung oedema). lnhalation of aerosol or fine spray mist may cause serious respiratory problems. May cause: Kidney effects, altered blood chemistry, nasal irritation, inflammation with redness, tenderness, or swelling. lnformation given is based on data obtained from similar product. Page 1 of 6

2 Fiber ProTector - Water Based MSDS Date: 7/16/2013 Carcinogenicity None of the components present in this materiat at concentrations equal to or greater than O.l% are listed by IARC, NTP, or OSHA, as a carcinogen. SECTION 4: FIRST AID MEASURES Skin contact Eye contact lnhalation lngestion General advice Wash off immediately with soap and plenty of water. Wash contaminated clothing before re-use. Rinse immediately with plenty of water for at least l5 minutes. Seek medical advice. Move to fresh air. Oxygen or artificia! respiration if needed. Symptoms may be delayed. Call a physician immediately. Call a physician or poison control centre immediately. lf swallowed, DO NOT induce vomiting unless directed to do so by medica! personnel. Never give anything by mouth to an unconscious person. When symptoms persist or in all cases of doubt seek medical advice. SECTION 5: FIREFIGHTING MEASURES Flammable Properties Flash point does not flash Thermal decomposition > 200 0c (> 392 0F) To avoid thermal decomposition, do not overheat. Thermal decomposition can lead to release of irritating gases and vapors. Fire and Explosion Hazard Suitable extinguishing media Firefighting lnstructions The product itself does not burn. Hazardous decomposition products formed under fire conditions. Hazardous combustion products: Hydrogen fluoride Carbon dioxide (CO2) Carbon monoxide other hazardous decomposition products may be formed. Use extinguishing measures that are appropriate to loca! circumstances and the surrounding environment. Wear self-contained breathing apparatus for firefighting if necessary. Evacuate personnel to safe areas. Do not allow run-offfrom firefighting to enter drains or watercourses. SECTION 6: ACCIDENTAL RELEASE MEASURES NOTE: Review FIRE FIGHTING MEASURES and'handling (PERSONNEL) sections before proceeding with clean up. use appropriate PERSoNAL PRorEcrlvE EQUIPMENT during clean up. Page 2 of 5

3 Fiber ProTector - Water Based MSDS Date: l/16/2013 Safeguards (Personnel) Spill Cleanup : Evacuate personnel to safe areas. Use personat protective equipment. Ventilate the area. : Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universa! binder, sawdust). pick up and transfer to properly labeled containers. Accidental Release Measures : Do not discharge to streams, ponds, takes, or sewers. Avoid subsoil penetration. SECTION 7: HANDLING AND STORAGE Handling (Personnel) Handling (Physical Aspects) Storage Storage temperature Avoid formation of respirable particles. Do not breathe vapor or mist. Avoid contact with skin, eyes, and clothing. Wash hands before breaks and immediately after handling the product. Wash contaminated clothing before re-use. To avoid thermal decomposition, do no overheat. Therma! decomposition can lead to release of irritating gases and vapors Do not spray near open flame or heated surface. Keep tightly closed in a dry, cool, and well-ventilated place. Perishable if frozen oc (4t - to4 of) SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTTON Engineering controls Persona! protective equipment Respiratory protection Hand protection Eye protection Skin and body protection Exposure Guidelines Exposure Limit Values Tetramethyl succinonitrile PEL: TLV Use only in area provided with appropriate exhaust ventilation. Use an airless flow type of spray applicator. Keep spraying pressure below 6O psi. ln case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Additional protection:!mpervious gloves Wear safety glasses or coverall chemical splash goggles. Lightweight protective clothing (OSHA) 0.5 ppm 3 mglm3 8 hr. TWA Skin designation (ACGIH) 0.5 ppm TWA Skin designation Page 3 of 6

4 Fiber ProTector - Water Based MSDS Date: Z/16/2013 SECTION 9: PHYSICAL AND CHEMTCAL properttes Form Color ph Eoiling point % Volatile Water solubility liquid clear, to opaque, yellow 4-6 lo0 oc (2l2oF) at 760 mm Hg 74-81% dispersible SECTION lo: STABILITY AND REACTIVITY Stability conditions to avoid Hazardous decomposition products : Stable under normal conditions. : To avoid thermal decomposition, do not overheat. : carbon dioxide, carbon monoxide, Hydrogen fluoride lncompletely burned carbon products Other hazardous decomposition products may be formed. SECTION I I: TOXICOLOGICAL INFORMATTON lnhalation 4 h ALC Oral LD5O Skin irritation Eye irritation Sensitization Repeated dose toxicity 4.7 mg/, rat >5,OOO mglkg, rat No skin irritation, rabbit slight irritation, rabbit Did not cause sensitization on laboratory animals, mouse Oral - gavage rat Abnormal increase in white blood cells, nasal effects, kidney effects, increased kidney weight. lnformation given is based on data obtained from similar product. Mutagenicity Reproductive toxicity Teratogenicity Further information Test on bacterial or mammalian cell cultures did not show mutagenic effects. No toxicity to reproduction Animal testing showed no developmental toxicity. lnformation given is based on data obtained from similar product. Page 4 of 5

5 Fiber ProTector - Water Based MSDS Date: ZllG/ZOl3 Tetramethyl succinonitrile Dermal LD5O : >50.t mglkg, rabbit Loss of appetite Lethargy Convulsions Pathologic changes Lung effects Liver effects Can be absorbed through skin. SECTION I 2: ECOLOGICAL INFORMATION Aquatic Toxicity 48 h EC50 : Daphnia magna (Water Flea) > t2o mgll lnformation given is based on data obtained from similar product. Tetramethyl succinonitrile 96 h LC5O : Pimephales promelas (Fathead Minnow) 16.4 mgll SECTION I 3: DISPOSAL CONSIDERATTONS Waste Disposa! : ln accordance with local and national regulations. SECTION I4: TRANSPORT INFORMATION Not classified as dangerous in the meaning of transport regulations. SECTION l5: REGLATORY INFORMATION TSCA Status TSCA Status Listed This materia! contains one or more substances, which are subject to a TSCA Se tion 5 Consent Order or Significant New Use Rule (SNUR). This material contains one or more substances which requires export notification under TSCA Section I 2(b) and 40 CFR Pafi 7O7 Subpart D: Fluorinated Acry!ic Copolymer SARA 3t 3 Regulated Chemica!(s) Title lll hazard classification California Prop.55 SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title lll, Section 313. A ute Health Hazard: Yes Chronic Health Hazard: Yes Fire: No neactiviti/physical hazard: No Pressure: No Chemicals known to the State of California to cause cancer, birth defects or any other harm: none known Page 5 of 5

6 Fiber ProTector - Water Based MSDS Date: 7/16/2013 SECTION I6: OTHER INFORMATION Health Flammability Reactivity/Physical hazard PPE HMIS I o o Personal Protection rating to be supplied by user depending on use conditions. Th-e information provided in this safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of lts publication. The information given is designed only as guidance Tor safe handling, use, proce-ssing, storage, transportation, disposal, and reliase and is not to be consfdered a warranty or quat-ity specification. The information related only to the specific material designated and may not be vilid for suth material used in combination with any other materials or in any procesl, unless specified in the text. Page 6 of 6