ZODIAQ Quartz Surfaces
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1 This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : MSDS Number : Manufacturer : DuPont Building Innovations 1007 Market Street Wilmington, DE Product Information : Medical Emergency : (outside the U.S ) Transport Emergency : CHEMTREC: (outside the U.S ) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview The product as such is not hazardous. The hazards of this product are associated mainly with its processing. Operations such as sawing, routing, drilling and sanding can generate dust. Dust generated during handling of Quartz Surfacing Products can contain particles of crystalline silica (quartz). Overexposure to airborne quartz can cause silicosis. Warning symptoms: Symptoms of silicosis include coughing, difficulty breathing, wheezing and progressive impairment of lung function. Potential Health Effects Eyes Quartz : Dust contact with the eyes can lead to mechanical irritation. Inhalation Quartz : Gross overexposure may cause: Breathing difficulties, Fever, Cough, Lung damage, May be fatal if inhaled in large quantities.. Repeated exposure 1 / 8
2 Quartz : DuPont has classified this material as a known human carcinogen. May cause cancer after repeated inhalation of spray or dust. Adverse effects from repeated inhalation may include: Chronic lung disease with alterations in lung function or difficulty breathing Target Organ Quartz : Lungs Carcinogenicity Material IARC NTP OSHA Quartz 1 X Cristobalite 1 X SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Concentration Quartz % Non regulated ingredients 7 % SECTION 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion General advice : Move to fresh air. : Never give anything by mouth to an unconscious person. 2 / 8
3 SECTION 5. FIREFIGHTING MEASURES Flammable Properties Flash point : does not flash Suitable extinguishing media : The product itself does not burn. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Firefighting Instructions : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Spill Cleanup Accidental Release Measures : Wear personal protective equipment. SECTION 7. HANDLING AND STORAGE Handling (Personnel) : Provide for appropriate exhaust ventilation and dust collection at machinery. Avoid dust formation. Wash hands before breaks and at the end of workday. Storage : None. No special restrictions on storage with other products. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls : Provide appropriate exhaust ventilation at places where dust is formed. 3 / 8
4 Personal protective equipment Respiratory protection Hand protection Eye protection : In case of insufficient ventilation, wear suitable respiratory equipment. : Additional protection: Protective gloves : Safety glasses Exposure Guidelines Exposure Limit Values Quartz PEL: (OSHA) 2.4 millions of particles per cubic foot of air TWA Respirable. equation, 250/(%SiO2+5), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. PEL: (OSHA) 0.1 mg/m3 TWA Respirable. equation, 10/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. PEL: (OSHA) 0.3 mg/m3 TWA Total dust. equation, 30/(%SiO2+2), using a value of 100% SiO2. Lower values of % SiO2 will give higher exposure limits. TLV (ACGIH) mg/m3 TWA Respirable fraction. AEL * (DUPONT) 0.01 mg/m3 12 hr. TWA Respirable dust. AEL * (DUPONT) 0.02 mg/m3 8 hr. TWA Respirable dust. Cristobalite PEL: (OSHA) 5 mg/m3 8 hr. TWA Respirable fraction. PEL: (OSHA) 15 mg/m3 8 hr. TWA Total dust. 4 / 8
5 PEL: (OSHA) 0.05 mg/m3 8 hr. TWA Respirable dust. PEL: (OSHA) 1.2 millions of particles per cubic foot of air TWA Respirable. equation, 125/(%SiO2+5), using a value of 100% SiO2. Lower values of % SiO2 will give higher exposure limits. PEL: (OSHA) 0.05 mg/m3 TWA Respirable. equation, 5/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. PEL: (OSHA) 0.15 mg/m3 TWA Total dust. equation, 15/(%SiO2+2), using a value of 100% SiO2. Lower values of % SiO2 will give higher exposure limits. TLV (ACGIH) 0.05 mg/m3 8 hr. TWA Respirable fraction. TLV (ACGIH) mg/m3 TWA Respirable fraction. AEL * (DUPONT) 0.01 mg/m3 12 hr. TWA Respirable dust. AEL * (DUPONT) 0.02 mg/m3 8 hr. TWA Respirable dust. * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : solid Color : various Odor : none Density : g/cm3 Water solubility : insoluble 5 / 8
6 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : None reasonably foreseeable. Hazardous decomposition products Hazardous reactions : Other decomposition products: No decomposition if used as directed. : None reasonably foreseeable. SECTION 11. TOXICOLOGICAL INFORMATION Quartz Oral LD50 : > 11,000 mg/kg, rat Bloody nasal discharge Weight loss Skin irritation : No skin irritation, rabbit Eye irritation : No eye irritation, rabbit Skin sensitization : Does not cause skin sensitisation., guinea pig Repeated dose toxicity : Inhalation rat Target Organs: Lungs Fluid retention in lungs (pulmonary oedema), lung effects, Inflammation, Chronic lung disease, Fibrosis Carcinogenicity : Human carcinogen. An increased incidence of tumours was observed in laboratory animals. An increased risk of cancer in humans has been shown in workplacebased studies. SECTION 12. ECOLOGICAL INFORMATION 6 / 8
7 Additional ecological information : This product has no known ecotoxicological effects. SECTION 13. DISPOSAL CONSIDERATIONS Waste Disposal : Can be landfilled or incinerated, when in compliance with local regulations. Environmental Hazards : Empty containers should be taken to local recyclers for disposal. SECTION 14. TRANSPORT INFORMATION Not classified as dangerous in the meaning of transport regulations. SECTION 15. REGULATORY INFORMATION HSNO (NZ) Status : Exempt SARA 313 Regulated Chemical(s) California Prop. 65 PA Right to Know Regulated Chemical(s) NJ Right to Know Regulated Chemical(s) : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. : WARNING! This product contains a chemical or chemicals known to the State of California to cause cancer.quartz, Cristobalite : Substances on the Pennsylvania Hazardous Substances List present at a concentration of 1% or more (0.01% for Special Hazardous Substances): Quartz, Cristobalite : Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): Quartz, Cristobalite SECTION 16. OTHER INFORMATION Before use read DuPont's safety information. 7 / 8
8 Registered trademark of E.I. du Pont de Nemours and Company The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Significant change from previous version is denoted with a double bar. 8 / 8
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