APOG - AMERICAN PAINT, OIL & GREASE REMOVER

Transcription

1 MATERIAL SAFETY DATA SHEET PRODUCT APOG - AMERICAN PAINT, OIL & GREASE REMOVER NFPA HAZARD RATINGS* Health Fire Stability 1 Slight health hazard 2 Moderately combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Spot and stain removal agent for drycleaning only. Synonyms: American POG, APOG SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Aromatic petroleum distillates Cyclohexanol Amyl alcohol Potassium hydroxide (dilute solution) pentyl acetate 1-methoxy-2-propanol Cyclohexanone Petroleum distillates % <5 <5 <5 < CAS # SECTION 3: PHYSICAL DATA OSHA PEL 500 ppm TWA 50 ppm TWA Not listed 2 mg/m3 Ceiling 100 ppm TWA Not listed 50 ppm TWA 500 ppm TWA LD 50 oral: 4700 mg/kg (rat) dermal: 3480 mg/kg (rat) oral: 2060 mg/kg (rat) dermal: 1300 mg/kg (dog) oral: 3880 mg/kg (rat) dermal: 4.49 ml/kg (rat) oral: 273 mg/kg (rat) dermal: 4200 mg/kg (rabbit) oral: 6500 mg/kg (rat) oral: 6070 mg/kg (rat) dermal: 12 ml/kg (rabbit) oral: 1900 mg/kg (rat) dermal: >1 ml.kg (rabbit) oral: >5000 mg/kg (rat) dermal: >3160 mg/kg (rabbit) Appearance: Light yellow liquid Odor: Nut-like Specific Gravity (20 C): ph (20:80 in IPA/H2O Soln.): Boiling Point: 206 F (96.7 C) Solubility in Water: Slight-forms emulsion Vapor Pressure (mm Hg): No data Vapor Density: Heavier than air SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash Point (Method)( F): 104 (TCC) Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Upper Flammable Limit: No data Lower Flammable Limit: No data Dry chemical, carbon dioxide, water fog or other media for Class B fires. Wear self-contained breathing apparatus. Cool containers with water spray. Vapors may form combustible or explosive mixture with air. Combustible products may be toxic. SECTION 5: REACTIVITY DATA Stability: Stable Conditions to Avoid: Use or storage at temperatures over 120 F. Incompatibility (materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: Strong oxidizers. Burning may produce toxic, irritating vapors. Will not occur. SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Effects of Overexposure: Slight Acute: Chronic: Exposure to high concentrations of vapors may cause headaches, nausea, dizziness, or nose, throat or eye irritation. Contact with eyes, prolonged or repeated contact with skin may cause drying or irritation. Orthodichlorobenzene is reported to cause liver and kidney damage with prolonged or repeated exposure. Carcinogenicity: of the ingredients of this mixture have been identified as a carcinogen or probable carcinogen by ACGIH, IARC or OSHA. *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

2 APOG - American Paint, Oil & Grease Remover EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY 50 pm TWA (cyclohexanol, No components are listed by ACGIH, cyclohexanone), 100 ppm TWA (pentyl Slight eye and skin reported IARC or OSHA. acetate) TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY SYNERGISTIC PRODUCTS No effects reported No effects reported reported reported SPECIAL PROTECTION INFORMATION Respiratory Protection: Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES required when used as directed with adequate ventilation. When cleaning up large spills in confined areas, self-contained breathing apparatus is recommended. Ventilation: Normal industrial ventilation is adequate. Local exhaust at work station is recommended. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Store in closed containers in a well ventilated area. Keep containers closed when not in use. Keep away from heat and open flame. Avoid breathing vapors. Keep from sources of ignition. Soak up on absorbent material (sawdust, etc.) and shovel into containers for disposal. Dispose of in a manner that complies with all local, state and federal regulations for combustible wastes. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Combustible. Keep away from heat and open flames. Use with adequate ventilation. Avoid prolonged breathing of vapors. Avoid contact with skin and eyes. FIRST AID: Remove person overcome by vapors to fresh air. In case of contact with eyes, flush for 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. Call physician immediately. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: Eyes: Skin: Remove person overcome by vapors to fresh air. Flush eyes for 15 minutes with water. Wash off of skin with soap and water. Ingestion: Do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: September 30, 2008 Replaces MSDS of: February 27, 2007

3 MATERIAL SAFETY DATA SHEET PRODUCT BPR - Blood & Protein Remover NFPA HAZARD RATINGS* Health Fire Stability 1 Slight health hazard 1 Slightly combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Stain removal agent for drycleaning and laundry Synonyms: Blood and protein remover SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Ammonium hydroxide (aqua ammonia) Potassium hydroxide (dilute solution) % <1 <2 CAS # OSHA PEL 50 ppm TWA 2 mg/m3 Ceiling LD 50 oral: 350 mg/kg (rat) oral: 273 mg/kg (rat) dermal: 4200 mg/kg (rabbit) SECTION 3: PHYSICAL DATA Appearance: Light yellow liquid Odor: Bland, trace of ammonia Specific Gravity (20 C): ph (Straight): Boiling Point: 212 F Solubility in Water: Miscible Vapor Pressure (mm Hg): No data Vapor Density: Heavier than air SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash Point (Method)( F): >200 (COC) Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Upper Flammable Limit: No data Lower Flammable Limit: No data Dry chemical, carbon dioxide, foam, water fog. Compatible with all types. Avoid directing strong stream of water into material - may cause foaming. Wear self-contained breathing apparatus when fighting fires in confined areas. Exposure to fire or high temperatures may produce noxious, irritating or toxic fumes. Stability: Stable SECTION 5: REACTIVITY DATA Conditions to Avoid: Storage at temperatures above 120 F (48.8 C) Incompatibility (materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: Strong oxidizers Burning produces toxic, irritating fumes Will not occur SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Effects of Overexposure: Low Acute: Chronic: May cause drying or irritation if splashed into eyes or on prolonged or repeated contact with skin. Inhaling vapors may cause temporary discomfort. known Carcinogenicity: Trace component (<0.01%) is listed by ACGIH, IARC and OSHA as suspected carcinogen. *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

4 EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT Slight eye and skin reported TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY BPR - Blood & Protein Remover CARCINOGENICITY Trace component listed by ACGIH, IARC and OSHA SYNERGISTIC PRODUCTS No effects reported No effects reported reported reported Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES SPECIAL PROTECTION INFORMATION Respiratory Protection: required when used as directed with adequate ventilation. Ventilation: Normal industrial ventilation is adequate. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: Store in closed containers at temperatures below 120 F. Do not store in aluminum containers. SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Small spills - flush to sewer with water. Large spills - soak up on absorbent material and transfer to containers for disposal as nonhazardous waste. Nonhazardous. Flush to sewer or dispose of material and container in municipal landfill in compliance with all local, state and federal regulation. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Splashing into eyes or prolonged or repeated contact with skin may cause irritation. FIRST AID: In case of contact, flush eyes for 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: Eyes: Skin: Remove person to fresh air. Flush eyes for 15 minutes with water. Wash off of skin with soap and water. Ingestion: If swallowed, do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: August 25, 2008 Replaces MSDS of: February 27, 2007

5 MATERIAL SAFETY DATA SHEET PRODUCT EASY OUT NFPA HAZARD RATINGS* Health Fire Stability 1 Slight health hazard 2 Moderately combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Spot removal & leveling agent for water sensitive drycleanable fabrics. For use in drycleaning only. Synonyms: SECTION 2: HAZARDOUS INGREDIENTS Chemical Name % CAS # OSHA PEL LD 50 Synthetic isoparaffinic hydrocarbon ppm TWA (recommended) oral: 34.6 g/kg (rat) SECTION 3: PHYSICAL DATA Appearance: Clear, yellow liquid Boiling Point: No data Odor: Bland Solubility in Water: Dispersible Specific Gravity (20 C): Vapor Pressure (mm Hg): No data ph (20:80 in IPA/H 2 O Soln.): Vapor Density: No data SECTION 4: FIRE AND EXPLOSION HAZARD DATA Upper Flammable Limit: No data Flash Point (Method)( F): 157 (PM) Lower Flammable Limit: No data Extinguishing Media: Dry chemical, carbon dioxide, water fog Special Fire Fighting Procedures: Avoid directing strong water stream into product - may generate foam Unusual Fire and Explosion Hazards: High heat may produce noxious decomposition product Stability: Stable SECTION 5: REACTIVITY DATA Conditions to Avoid: High heat Incompatibility (materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: Strong oxidizers, strong alkalis Amines, ammonia, and irritating fumes Will not occur SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Effects of Overexposure: Low Acute: Chronic: Causes drying and irritation in eyes or on prolonged contact with skin. Carcinogenicity: of the ingredients of this mixture have been identified as a carcinogen or probable carcinogen by ACGIH, IARC, or OSHA. *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

6 Easy Out EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY 300 ppm TWA recommended (synthetic isoparaffinic hydrocarbon) Very slight eye and skin reported No components are listed by ACGIH, IARC, or OSHA TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY SYNERGISTIC PRODUCTS effects reported effects reported reported reported SPECIAL PROTECTION INFORMATION Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES Respiratory Protection: required when used as directed with adequate ventilation. When cleaning up large spills in confined areas, self-contained breathing apparatus is recommended. Ventilation: Normal industrial ventilation is adequate. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: Store in plastic or lined metal containers. Use plastic or stainless steel drum pump. SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Small spills may be flushed to sewer with water. Larger spills - soak up on absorbent material and transfer to containers for disposal. Flush to sewer or dispose of material and container in nonhazardous municipal landfill in compliance with all local, state, and federal regulations. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Splashing into eyes or prolonged or repeated contact with skin may cause irritation. FIRST AID: In case of contact with eyes, flush 15 minutes with water. Wash off of skin. If swallowed, do NOT induce vomiting. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: No treatment necessary. Eyes: Flush eyes 15 minutes with water. Skin: Wash off of skin with soap and water. Ingestion: Do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: November 7, 2008 Replaces MSDS of: June 17, 2004

7 MATERIAL SAFETY DATA SHEET PRODUCT HYDRO SPOT NFPA HAZARD RATINGS* Health Fire Stability 1 Slight health hazard 2 Moderately combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Spot and stain removal agent for drycleaning only. Synonyms: SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Terpene hydrocarbons % CAS # OSHA PEL 100 ppm TWA LD 50 oral: 5 g/kg (rat) dermal: 5 g/kg (rabbit) SECTION 3: PHYSICAL DATA Appearance: Yellow-orange liquid Odor: Citrus odor Specific Gravity (20 C): ph (20:80 in IPA/H2O Soln.): Boiling Point: 257 F Solubility in Water: Slight - forms emulsion Vapor Pressure (mm Hg): No data Vapor Density: No data SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash Point (Method)( F): 108 (TCC) Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Upper Flammable Limit: 6.1 (terpene hydrocarbons) Lower Flammable Limit: 0.7 (terpene hydrocarbons) Dry chemical, carbon dioxide, water fog, or other media for Class B fires. Wear self-contained breathing apparatus. Cool containers with water spray. Vapors may form combustible or explosive mixture with air. Combustible products may be toxic. Stability: Stable SECTION 5: REACTIVITY DATA Conditions to Avoid: Use or storage at temperatures over 120 F Incompatibility (materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: Strong oxidizers Burning may produce toxic, irritating vapors. Will not occur. SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Effects of Overexposure: Slight Acute: Chronic: Exposure to high concentrations of vapors may cause headaches, nausea, dizziness, or nose, throat, or eye irritation. Contact with eyes, prolonged or repeated contact with skin may cause drying or irritation. Prolonged or repeated exposure can cause drying, defatting, and dermatitis of skin. Carcinogenicity: of the ingredients of this mixture have been identified as a carcinogen or probable carcinogen by ACGIH, IARC, or OSHA. *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

8 Hydro Spot EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY 100 ppm TWA (terpene hydrocarbons) Slight eye and skin reported No components are listed by ACGIH, IARC or OSHA TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY SYNERGISTIC PRODUCTS No effects reported No effects reported reported reported SPECIAL PROTECTION INFORMATION Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES Respiratory Protection: required when used as directed with adequate ventilation. When cleaning up large spills in confined areas, self-contained breathing apparatus is recommended. Ventilation: Normal industrial ventilation is adequate. Local exhaust at work station recommended. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Store in closed containers in a well ventilated area. Keep containers closed when not in use. Keep away from heat and open flame. Avoid breathing vapors. Keep from sources of ignition. Soak up on absorbent material (sawdust, etc.) and shovel into containers for disposal. Dispose of in manner that complies with all local, state, and federal regulations for combustible wastes. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Combustible. Keep away from heat and open flames. Use with adequate ventilation. Avoid prolonged breathing of vapors. Avoid contact with skin and eyes. FIRST AID: Remove person overcome by vapors to fresh air. In case of contact with eyes, flush for 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. Call physician immediately. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: Remove person overcome by vapors to fresh air. Eyes: Flush eyes 15 minutes with water. Skin: Wash off of skin with soap and water. Ingestion: Do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: November 10, 2008 Replaces MSDS of: March 2, 2004

9 MATERIAL SAFETY DATA SHEET PRODUCT NEUTRA NFPA HAZARD RATINGS* Health Fire Reactivity 1 Slight health hazard 1 Slightly combustible 0 Nonreactive SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO, Inc., 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Synonyms: Soil and stain removal agent for laundry and drycleaning Neutral lubricant State Registry#: MA Prod. # SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Cyclohexanol ethylene glycol monobutyl ether (EB solvent) % 1-5 <5 CAS # OSHA PEL 50 ppm TWA 25 ppm TWA LD 50 oral: 2060 mg/kg (rat) oral: 470 mg/kg (rat) dermal: 200 mg/kg (rabbit) Hexylene glycol < ppm TWA oral: 3.7 g/kg (rat) dermal: 12.0 g/kg (rabbit) SECTION 3: PHYSICAL DATA Appearance: Clear light yellow Boiling Point: 210 F Odor: Bland Solubility in Water: Miscible Specific Gravity (20 C): Vapor Pressure (mm Hg): No data ph (Water Solution): Vapor Density: No data SECTION 4: FIRE AND EXPLOSION HAZARD DATA Upper Flammable Limit: (cyclohexanol) Flash Point (Method)( F): 130 (TCC) Lower Flammable Limit: 1.2 (cyclohexanol) Extinguishing Media: Compatible with all types of fire extinguishers. Special Fire Fighting Procedures: Avoid directing strong stream of water into material - may cause foaming. Unusual Fire and Explosion Hazards: Stability: Stable SECTION 5: REACTIVITY DATA Conditions to Avoid: Incompatibility (materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: Strong oxidizers Burning produces toxic vapors, irritating fumes Will not occur SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Effects of Overexposure: Very low Acute: Chronic: Eye contact may cause irritation and swelling of conjunctiva. Prolonged skin contact may cause redness and swelling at site of contact. Inhalation may cause dizziness. Kidney and liver effects reported in animals (cyclohexanol). Prolonged skin contact may cause dermatitis. Carcinogenicity: of the ingredients of this mixture have been identified as a carcinogen or probable carcinogen by ACGIH, IARC, or OSHA. *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

10 EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY 50 ppm TWA (cyclohexanol), 25 ppm TWA (EB solvent), 25 ppm TWA (hexylene glycol) Slight eye and skin reported Neutra No components are listed by ACGIH, IARC, or OSHA TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY SYNERGISTIC PRODUCTS effects reported effects reported reported reported SPECIAL PROTECTION INFORMATION Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES Respiratory Protection: required when used as directed with adequate ventilation. When cleaning up large spills in confined areas, self-contained breathing apparatus is recommended. Ventilation: Normal industrial ventilation is adequate. Local exhaust at work station is adequate. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: Store in closed containers at temperatures below 50 C. Do not store in unlined metal containers. SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Small spills may be flushed to sewer with water. Large spills - soak up on absorbent material and transfer to containers for disposal as nonhazardous waste. Nonhazardous. Flush small quantities to sewer with water. Soak up large spills on absorbent material and transfer to containers for disposal as nonhazardous waste in compliance with all local, state, and federal regulations. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Splashing in eyes or prolonged or repeated contact with skin may cause irritation. FIRST AID: In case of contact with eyes, flush 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: No treatment necessary. Eyes: Flush eyes 15 minutes with water. Skin: Wash off of skin with soap and water. Ingestion: If swallowed, do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: November 12, 2008 Replaces MSDS of: March 17, 2004

11 MATERIAL SAFETY DATA SHEET PRODUCT PURO NFPA HAZARD RATINGS* Health Fire Stability 2 Moderate health hazard 1 Slightly combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Stain removal agent for use in drycleaning only. Synonyms: Volatile dry solvent, VDS SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Trichloroethylene % <100 CAS # OSHA PEL LD ppm TWA oral: 4920 mg/kg (rat) SECTION 3: PHYSICAL DATA Appearance: Colorless Liquid Odor: Sweet, like ether Specific Gravity (20 C): ph: Not applicable Boiling Point: 189 F Solubility in Water: 20 C Vapor Pressure (mm Hg): 20 C Vapor Density: Heavier than air SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash Point (Method)( F): >230 (TCC) Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Upper Flammable Limit: No data Lower Flammable Limit: No data Self-extinguishing Use water spray to keep fire-exposed containers cool. Wear self-contained breathing apparatus. Vapors may develop a flammable atmosphere in confined areas. May decompose to hydrochloric acid at high temperatures in fire. SECTION 5: REACTIVITY DATA Stability: Hazardous Polymerization: Stable Incompatibility (materials to avoid): Hazardous Decomposition Products: Conditions to Avoid: High temperatures may induce thermal decomposition. Avoid open flames. Welding arcs should not be used. Strong oxidizers. aluminum, or zinc coated containers. Hydrogen chloride, phosgene, and other toxic fumes may be produced on burning vapors. Will not occur. SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Very low: oral LD 50: >4920 mg/kg skin absorption Effects of Overexposure: Acute: Chronic: Contact with eyes, prolonged or repeated contact with skin may cause irritation, redness, and drying. Breathing a high concentration of vapors may cause irritation of the nose and throat, dizziness, nausea, or loss of coordination. Carcinogenicity: Trichloroethylene component rated "2A" IARC - "C" NTP - human carcinogen on CA list *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

12 EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT 50 ppm TWA (trichloroethylene) Slight eye and skin known TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY Puro CARCINOGENICITY Trichloroethylene component rated "2A" IARC - "C" NTP - human carcinogen on CA list SYNERGISTIC PRODUCTS No effects reported No effects reported reported reported SPECIAL PROTECTION INFORMATION Respiratory Protection: Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES required when used as directed with adequate ventilation. When cleaning up large spills in confined area, self-contained breathing apparatus is recommended. Ventilation: Normal industrial ventilation is adequate. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Store in closed containers in a well ventilated area. Aluminum equipment should not be used for storage or transfer. Keep containers closed when not in use. Small spills - wipe up. Large spills - soak up on absorbent material and transfer into resealable containers for disposal. Liquid product or absorbents containing this product must be disposed on in accordance with applicalbe local, state and federal regulations for chlorinated hydrocarbons. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Use with adequate ventilation. Avoid contact with skin and eyes. Avoid prolonged breathing of vapors. Harmful if swallowed. FIRST AID: If overcome be vapors, remove person to fresh air. In case of contact with eyes, flush for 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. Call physician immediately. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: Eyes: Skin: Remove person overcome by vapors to fresh air. Flush eyes for 15 minutes with water. Wash off of skin with soap and water. Ingestion: Do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: November 7, 2008 Replaces MSDS of: November 16, 2007

13 MATERIAL SAFETY DATA SHEET PRODUCT SEMI WET SPOTTER NFPA HAZARD RATINGS* Health Fire Stability 2 Moderate health hazard 1 Slightly combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Stain removal agent for laundry and drycleaning Synonyms: SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Trichloroethylene % <100 CAS # OSHA PEL 50 ppm TWA LD 50 oral: 4920 mg/kg (rat) SECTION 3: PHYSICAL DATA Appearance: Semi-clear water white liquid Odor: Sweet, like ether Specific Gravity (20 C): 1.25 ph (20:80 in IPA/H2O Soln.): Boiling Point: 188 F Solubility in Water: Forms an emulsion Vapor Pressure (mm Hg): 60 mm 20 C Vapor Density: No data SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash Point (Method)( F): >230 (PM) Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Upper Flammable Limit: No data Lower Flammable Limit: No data Self extinguishing Use water spray to keep fire-exposed containers cool. Wear self-contained breathing apparatus. Vapors may develop a flammable atmosphere in confined areas. May decompose to hydrochloric acid at high temperatures in fire. SECTION 5: REACTIVITY DATA Stability: Hazardous Polymerization: Stable Incompatibility (materials to avoid): Hazardous Decomposition Products: Conditions to Avoid: High temperatures may induce thermal decomposition. Avoid open flames. Welding arcs should not be used. Strong oxidizers, aluminum, or zinc coated containers. Hydrogen chloride, small amounts of phoscene, irritating fumes at high temperatures. Will not occur. SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Very low: oral LD 50: above 4920 mg/kg skin absorption Effects of Overexposure: Acute: Chronic: Contact with eyes, prolonged or repeated contact with skin may cause irritation, redness, and drying. Breathing high concentration of vapors may cause irritation of the nose and throat, dizziness, nausea or loss of coordination. Carcinogenicity: Trichloroethylene component rated "2A" IARC - "C" NTP - human carcinogen on CA list *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

14 Semi Wet Spotter EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY 50 ppm TWA (trichloroethylene) Slight eye and skin reported Trichloroethylene component rated "2A" IARC - "C" NTP - human carcinogen on CA list TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY SYNERGISTIC PRODUCTS No effects reported No effects reported reported reported SPECIAL PROTECTION INFORMATION Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES Respiratory Protection: required when used as directed with adequate ventilation. When cleaning up large spills in confined areas, self-contained breathing apparatus is recommended. Ventilation: Normal industrial ventilation is adequate. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Store in closed containers in a well ventilated area. Aluminum equipment should not be used for storage or transfer. Keep containers closed when not in use. Small spills - wipe up. Large spills - soak up on absorbent material and transfer into resealable containers for disposal. Liquid product or absorbents containing this product must be disposed of in accordance with applicable local, state, and federal regulations for chlorinated hydrocarbons. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Use with adequate ventilation. Avoid contact with skin and eyes. Avoid prolonged breathing of vapors. Harmful if swallowed. FIRST AID: If overcome by vapors, remove person to fresh air. In case of contact with eyes, flush for 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: Remove person overcome by vapors to fresh air. Eyes: Flush eyes 15 minutes with water. Skin: Wash off of skin with soap and water. Ingestion: Do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does contain some components which are under the reporting requirements of SARA Title III, Section 313. If you are required to report discharges using Form R, SARA Title III, Section 313, information is available on amounts of reportable components. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: November 7, 2008 Replaces MSDS of: November 16, 2007

15 MATERIAL SAFETY DATA SHEET PRODUCT Super Tan + NFPA HAZARD RATINGS* Health Fire Stability 1 Slight health hazard 1 Slightly combustible 0 Stable SECTION 1: PRODUCT INFORMATION Manufacturer: ADCO Cleaning Products LLC, 900 W. Main, Sedalia, MO (660) EMERGENCY TELEPHONE NUMBERS: CHEMTREC (800) HRS 7 DAYS A WEEK; ADCO (800) (8-5 M-F) Intended Product Use: Stain removal agent for laundry and drycleaners Synonyms: SECTION 2: HAZARDOUS INGREDIENTS Chemical Name Citric acid (dilute solution) % CAS # OSHA PEL LD 50 oral: 975 mg/kg (rat) SECTION 3: PHYSICAL DATA Appearance: Clear, water-white to pale yellow liquid Odor: Sharp, sweet odor Specific Gravity (20 C): ph (Straight): 2-3 Boiling Point: 212 F Solubility in Water: Miscible Vapor Pressure (mm Hg): No data Vapor Density: Heavier than air SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash Point (Method)( F): >230 (PM) Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Upper Flammable Limit: No data Lower Flammable Limit: No data Dry chemical, carbon dioxide, foam, water fog - Compatible with all types Avoid directing strong water stream into material - may cause foaming. Wear self-contained breathing apparatus when fighting fires in confined areas. Stability: Stable SECTION 5: REACTIVITY DATA Conditions to Avoid: Storage at temperatures above 120 F (48.8 C) Incompatibility (materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: Strong oxidizers Burning produces toxic, irritating fumes Will not occur. SECTION 6: HEALTH HAZARD DATA Toxicity (Estimated): Effects of Overexposure: Very low Acute: Chronic: May cause drying or irritation if splashed into eyes or on prolonged or repeated contact with skin. Carcinogenicity: of the ingredients of this mixture have been identified as a carcinogen or probable carcinogen by ACGIH, IARC, or OSHA. *Hazard ratings and other information are based on latest available information from tests on product or ingredients of mixtures. The data and evaluations are accurate to the best of ADCO's knowledge. No guarantee or liability is expressed or implied.

16 EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT listed by OSHA Slight eye and skin known TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY Super Tan + CARCINOGENICITY No components are listed by ACGIH, IARC, or OSHA SYNERGISTIC PRODUCTS No effects reported No effects reported reported reported Based on known toxicity of components. No test data available on mixture. SECTION 7: PREVENTATIVE MEASURES SPECIAL PROTECTION INFORMATION Respiratory Protection: required when used as directed with adequate ventilation. Ventilation: Normal industrial ventilation is adequate. Protective Gloves: Ordinarily not needed. Use chemically resistant gloves when contact is prolonged or frequent. Eye Protection: Use goggles or face mask if splashing is likely. Other protection equipment ordinarily not needed. Availability of eye washes and adequate ventilation in work areas recommended. STORAGE AND HANDLING: SPILL OR LEAK PROCEDURES: WASTE DISPOSAL METHOD: Store at temperatures below 120 F. Do not store or dispense in aluminum or iron equipment. Use glass, plastic, or stainless steel liners and containers. Clean up spills on walkways to prevent slick spots. Small spills may be flushed to sewer with water. Large spills - soak up on absorbent material and transfer to containers for disposal as nonhazardous waste. Flush small quantities to sewer or dispose of material in container in municipal landfill in compliance with all local, state, and federal regulations. RECOMMENDED PRECAUTIONARY LABELING: CAUTION: Splashing into eyes or prolonged or repeated contact with skin may cause irritation. FIRST AID: In case of contact with eyes, flush for 15 minutes with water. Wash off of skin with soap and water. If swallowed, do NOT induce vomiting. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. This product is intended for professional use only by trained personnel. Inhalation: Eyes: Skin: Remove victim to fresh air Flush eyes for 15 minutes with water. Wash off of skin with soap and water. Ingestion: Do NOT induce vomiting. SECTION 8: FIRST AID IF SYMPTOMS PERSIST, SEEK MEDICAL ASSISTANCE SECTION 9: SARA TITLE III NOTE: This product does not contain any components which are under the reporting requirements of SARA Title III, Section 313. SECTION 10: PREPARATION DATE This information is provided for guidance only based on information we have compiled. No guarantee of accuracy or completeness is expressed or implied. ADCO RESEARCH DEPARTMENT Prepared by: Julie D. Hirner Date: November 7, 2008 Replaces MSDS of: January 16, 2008