Safety data sheet according to 1999/155 EWG last changed by 2001/58/EG

Transcription

1 1. SUBSTANCE/ PREPARATION AND COMPANY IDENTIFICATION: 1.1. Identification of the substance or preparation Product name : ROYAL BLOOD Chemical characterization : lubricant 1.2. Use of the Substance/Preparation Recommended use : - Lubricant - For industrial use only Company/Undertaking Identification Boss Industrieschmierstoffe Elisabethenstr. 14 Tel.:07432 / Fax :07432 / Abt. Entwicklung / technischer Service Dipl. Ing. (FH) Frank Werner Tel.: 0049/ (0) address: info@boss-oil.de Albstadt 2. COMPOSITION / INFORMATION ON INGREDIENTS: Chemical characterisation: Preparation of mineral oil (IP 346 DSMO < 3 %), Additive Substance name Concentration Classification R-phrase(s) (CAS-No. / EC-No. / Annex-1) (W/W) Polyolefine Xn R65, R66 Additional tip: the text of the hazardous phrases is to be taken in chapter HAZARDS IDENTIFICATION: To people: See point 11 and 15. Preparation is classified as hazardous in the sense of directive 1999/45/EC Xn harmful May cause lung damage if swallowed Repeated exposure may cause skin dryness or cracking See point 12: Product can compose a film on the water surface, which can prevent oxygen exchange.

2 4. FIRST AID MEASURES: 4.1. Inhalation Harmful if inhaled. If the person exposed to oil mist or vapour has fatigue or nausea, he shall be moved into fresh air. If symptoms persist, call a physician Eye contact Rinse immediately with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist Skin contact Wash the skin with plenty of water and soap. If skin irritation persists, consult a physician Ingestion Do not induce vomiting. Rinse mouth. Consult a physician (risk of aspiration into lungs especially if nausea or irritation occurs) 4.5. Information to doctor or other trained persons giving first aid Aspiration into lungs can cause chemical pneumonitis Additional information If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. 5. FIRE-FIGHTING MEASURES: 5.1. Suitable extinguishing media - water spray - Foam - Dry chemical - Carbon dioxide (CO2) 5.2. Extinguishing media which shall not be used for safety reasons Straight Streams of Water 5.3. Special exposure hazards in a fire In case of fire hazardous decomposition products may be produced such as: Carbon monoxide, Sulfuroxide, Smoke, Fume. Incomplete combustion products Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Fire Fighters should consider protective equipment indicated in Section Other information Evacuate area. Prevent runoff from fire control or dilution from entering streams. Sewers, or drinking water supply. Fire Fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus. Use water spray to cool fire exposed surfaces and to protect personnel.

3 6. ACCIDENTAL RELEASE MEASURES: 6.1. Notification Procedures In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulation Protective Measures Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required due to toxicity or flammability of the material. See section 5 for fire fight information. See the hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for Personal Protective Equipment Spill Management Land Spill: Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material an transfer to containers. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land Spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in case of water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken Environmental precautions Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. 7. HANDLING AND STORAGE: 7.1. Handling Avoid breathing mists or vapours. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This materials is a static accumulator. Provide suitable mechanical equipment for the safe handling of drums and heavy packages Storage Do not store in open or unlabelled containers. Store in dry place at room temperature. The protective measures as usual in the mineral oil industry have to be observed. Adequate ventilation in working area may be necessary Specific use(s) For further information, please contact: Supplier

4 8. EXPOSURE CONTROLS / PERSONAL PROTECTION: 8.1. Exposure Limit Values Exposure limits/standards (Note : Exposure limits are not additive) Source Form Limit / Standard Limit / Standard Note Polyolefine Aerosols TWA 1 mg/m 3 N/A (thoracic fraction) Polyolefine Aerosol TLV-ACGIH 5mg/m 3 N/A (Thoracic fraction) Source Note: limits/standards shown for guidance only. Follow applicable regulations. Engineering Controls The level of protection and types of controls necessary will vary depending upon potential exposure condition. Control measures to consider: Adequate ventilation should be provided whenever the material is heated or mists are generated. Personal Protection Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: Particulate air purifying respirator approved for dust / oil mist is recommended. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection an breakthrough times for your use conditions. Inspect and replace worn or damage gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No Skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.

5 Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. 9. PHYSICAL AND CHEMICAL PROPERTIES: 9.1. General Information (appearance, odour) Appearance : Liquid Colour : blue Odour : mild 9.2. Important health safety and environmental information Boiling point/boiling range : Remarks: no data available Flash point : > 160 C Flammability : Remarks: no data available Explosive properties : Explosion danger: Remarks: no data available Oxidizing properties : Remarks: no data available Vapour pressure : no data available Relative density / Density : 0,8350 g/cm 3,Temperature: 15 C Solubility : Water Remarks: insoluble Viscosity : 10 mm 2 /s, Temparture: 40 C 9.3. Other data Melting point/range : Remarks: no data available Decomposition temperature: no data available 10. STABILITY AND REACTIVITY: Stability Material is stable under normal conditions Conditions to avoid Excessive heat. High energy sources of ignition Materials to avoid Strong oxidizers Hazardous decomposition products Material does not decompose at ambient temperatures. Hazardous decomposition products see section Hazardous Polymerisation: Will not occur.

6 11. TOXICOLOGICAL INFORMATION: 11.1 Toxicological data Acute Toxicity Inhalation Toxicity (Rat): LC 50 Ingestion Toxicity (Rat): LD50 >2000 mg/kg Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Eye Irritation No data available Minimal Toxic. Based on test data for the material. Minimally Toxic. Based on test data for the material May cause mild, short-lasting discomfort to eyes. Based on test data for the material. Chronic/other Effects For the product itself: Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Contains: Low-viscosity branched alkanes: Acute exposures of high aerosol levels are harmful to lungs. Repeated exposure may cause skin dryness or cracking 12. ECOLOGICAL INFORMATION: The information given is based on data available for the material, the components of the material, and similar materials Ecotoxicity effects Acute toxicity - Remarks: no data available Mobility Product does not evaporate from surface soil or water. It is insoluble in water Persistence and degradability Abiotic degradation - Result: no data available Biodegradation - Remarks: no data available Bioaccumulative potential - Result: no data available Other adverse effects Water Hazard Class WGK=1 (Germany) Possible hazards (summary) Ecological injuries are not known or expected under normal use.

7 13. DISPOSAL CONSIDERATIONS: Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, an material characteristics at time of disposal. 14. TRANSPORT INFORMATION: - Sea (IMO/IMDG) - not regulated - Air (ICAO/IATA) - not regulated - European Road/Rail (ADR/RID) - not regulated 15. REGULATORY INFORMATION: EC Label Preparation is classified according to Directive 1999/45/EC. Symbol: Xn harmful may cause lung damage if swallowed Repeated exposure may cause skin dryness or cracking Text of R and S phrases mentioned in Section 3 R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking. S23: Do not breath vapour / spray S24/25: Avoid contact with skin and eyes. S62: If swallowed, do not induce vomiting. Seek medical advice immediately and show this label. 16. OTHER INFORMATION: This information is based on our current knowledge and is intended to describe the product for purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Data sheet responsibility area: research and technical service Contact: Frank Werner