Quebec Quebec Tel : Fax : MSDS: Hydrogen Sulfide in Nitrogen Mixture PRODUCT INFORMATION
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1 Tel: Fax: Internet: support@megs.ca Montreal Ottawa St-Laurent Nepean Tel : Tel : Fax : Fax : Quebec Quebec Tel : Fax : MSDS: Hydrogen Sulfide in Nitrogen Mixture PRODUCT INFORMATION PRODUCT: Hydrogen Sulfide in Nitrogen TRADE NAME: None CHEMICAL NAME: Hydrogen Sulfide in Nitrogen SYNONYMS: None FORMULA: H 2 S in N 2 gas mixture CHEMICAL FAMILY: Gas mixture SUPPLIER'S NAME: MEGS Inc. SUPPLIER'S ADDRESS: 2675 De Miniac Ville St-Laurent, Qc, H4S 1E5 EMERGENCY PHONE NUMBER: (514) MOLECULAR WEIGHT: PRODUCT USE: Various PRODUCT IDENTIFICATION UN 1956, Compressed gases, n.o.s. NUMBER: CHEMICAL ID Hydrogen Sulfide N2 HAZARDOUS INGREDIENTS CONCENTRATION 10 ppm Bal CAS # LD(50) Inhl-Mon 5700mg/kg None LC(50) Inhl-Rat 444 ppm None PHYSICAL DATA PHYSICAL STATE: Gas under pressure APPEARANCE: Colorless gas ODOR: Characteristic "rotten egg " odor ODOR THRESHOLD: 2% SPECIFIC GRAVITY (H 2 O = 1): See Vapor Density (air = 1)
2 VAPOR PRESSURE: Not applicable (gas) VAPOR DENSITY (air = 1): 15 C, kpa EVAPORATION RATE: Not applicable (gas) BOILING POINT: H2S = C; N2 = C FREEZING POINT: H2S = C; N2 = C ph: Not applicable GAS DENSITY: C, kpa COEFFICIENT OF 15 C, Bunsen Coefficient DISTRIBUTION: H2S = 2.95, N2 = CONDITIONS OF FLAMMABILITY: FIRE OR EXPLOSION HAZARD MEANS OF EXTINCTION: FLASHPOINT AND METHOD OF DETERMINATION: UPPER EXPLOSION LIMIT (% BY VOL): LOWER EXPLOSION LIMIT (% BY VOL): AUTO-IGNITION TEMPERATURE: FLAMMABILITY CLASSIFICATION: HAZARDOUS COMBUSTION PRODUCTS: EXPLOSION DATA: SENSITIVITY TO STATIC DISCHARGE: REACTIVITY DATA CHEMICAL STABILITY: Stable INCOMPATIBLE MATERIALS: No appreciable reactivity at the level of 10 ppm H2S in N2 CONDITIONS OF REACTIVITY: No appreciable reactivity at the level of 10 ppm H2S in N2 HAZARDOUS DECOMPOSITION Possibly oxides of sulfur, no PRODUCTS: appreciable concentrations of hazardous products from H2S at 10 ppm in N2 ROUTES OF ENTRY: TOXICOLOGICAL PROPERTIES SKIN CONTACT: No exposure hazard reported at levels below 20 ppm of H2S
3 SKIN ABSORPTION: Unknown EYE: See Skin Contact, above INHALATION: No appreciable effects at levels of 10 ppm H2S in N2, however continued exposure may cause headaches, dizziness or nausea. Continuous inhalation of low concentrations may cause olfactory fatigue or paralysis rendering the detection of its presence by odor ineffective. INGESTION: None ACUTE OVER EXPOSURE EFFECTS: Acts as an irritant to mucous tissue, membranes and the conjunctivae of the eyes. CHRONIC OVER EXPOSURE EFFECTS: None reported EXPOSURE LIMITS: 10 ppm H2S in N2 is nontoxic but the liberation of a large amount in a confined area could displace the amount of oxygen in air necessary to support life. IRRITANCY OF PRODUCT: See Skin and Eyes, above. SENSITIZATION TO MATERIAL: None known CARCINOGENICITY, REPRODUCTIVE EFFECTS: None known TERATOGENICITY, MUTAGENICITY: None known TOXICOLOGICALLY SYNERGISTIC PRODUCTS: None PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Safety goggles or glasses, safety shoes, gloves of any material SPECIFIC ENGINEERING CONTROLS: This mixture can be handled in carbon steel, aluminum, Inconel, Stellite and 304 and 316 stainless steels. Systems must be designed to adequately handle the pressures involved. LEAK AND SPILL PROCEDURES: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. Use appropriate protective equipment. If leak is in user's equipment, be certain to purge piping with an inert gas prior to attempting repairs. If leak is on container or container valve, contact the closest MEGS location.
4 WASTE DISPOSAL: Do not attempt to dispose of waste or unused quantities. Return in the shipping container properly labeled, with any valve outlet plugs or caps secured and valve protection cap in place to MEGS for proper disposal. For emergency disposal, contact the closest MEGS location. HANDLING PROCEDURES AND EQUIPMENT: USE ONLY IN WELL- VENTILATED AREAS. Use a pressure reducing regulator when connecting to lower pressure piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. Close valve after each use and when empty. STORAGE REQUIREMENTS: Protect cylinders from physical damage. Store in cool, dry, well-ventilated area of non combustible construction away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 52 C. Cylinders must be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in - first out" inventory system to prevent full cylinders being stored for excessive periods of time. TDG CLASSIFICATION: 2.2 WHMIS CLASSIFICATION: A SPECIAL SHIPPING INFORMATION: Always secure cylinders before transporting them. NEVER transport cylinders in trunks of vehicles, enclosed vans, truck cabs or in passenger compartments. Transport cylinders secured in open flatbed or in open pick-up type vehicles. FIRST AID MEASURES SPECIFIC FIRST AID PROCEDURES: PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO AN ASPHYXIATING GAS. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF- CONTAINED BREATHING APPARATUS AND RECOGNIZE THE HAZARDS OF OVEREXPOSURE DUE TO OLFACTORY FATIGUE. INHALATION: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given assisted resuscitation and supplemental oxygen. Further treatment should be symptomatic and supportive.
5 EYE CONTACT: WHILE, PERSONS WITH POTENTIAL EXPOSURE TO HYDROGEN SULFIDE SHOULD NOT WEAR CONTACT LENSES, H2S AT THIS CONCENTRATION POSES LIMITED DANGER. SKIN CONTACT: No exposure hazard reported PREPARED BY: Safety Department DATE PREPARED: 03/14/1999 LAST REVISION DATE: 05/21/2002 PREPARATION INFORMATION THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE USED BY PROPERLY TRAINED AND QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION. THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED ARE DERIVED FROM SOURCES WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, MEGS INC. MAKES NO REPRESENTATION AND GIVES NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS AND ASSUMES NO LIABILITY FOR DAMAGES OR LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE, WHETHER PROPER OR IMPROPER.
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