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Transcription:

SECTION 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product name: LOCTITE 518 GASKET ELIMINATOR FLANGE SEALANT Product-Code: 135482 Intended use: Anaerobic Adhesive Supplier: Henkel Australia Pty. Ltd. 135-141 Canterbury Road 3137 Kilsyth, Victoria Australia Phone: +61 (3) 9724 6444 Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER 03 9724 6556 SECTION 2. HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE: Hazardous according to the criteria of ASCC. Classification of material Xi - Irritant Risk phrases: R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. Safety phrases: S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S37/39 Wear suitable gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show this container or label. Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Page 1 of 5 LOCTITE 518 GASKET ELIMINATOR FLANGE SEALANT

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Identity of ingredients: Chemical ingredients CAS-No. Proportion Toluene diisocyanate, hydroxyethyl methacrylate, > 70 % poly(alkyl ether derivative) resin Polyethylene glycol 200 dimethacrylate 25852-47-5 1-10 % Acrylic acid 79-10-7 < 5 % Cumene hydroperoxide 80-15-9 < 3 % Ethane-1,2-diol 107-21-1 < 2 % 2-Hydroxyethyl methacrylate 868-77-9 < 1 % SECTION 4. FIRST AID MEASURES Ingestion: Skin: Eyes: Inhalation: Medical attention and special treatment: First Aid facilities: Rinse mouth, do not induce vomiting, consult a doctor. Immediately wash skin thoroughly with soap and water. If skin irritation persists, call a physician. Immediately flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. Move to fresh air, consult doctor if complaint persists. Treat symptomatically. Eye wash Normal washroom facilities SECTION 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Foam, dry chemical or carbon dioxide. Decomposition products in case of fire: Special protective equipment for fire-fighters: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions and emergency procedures: Environmental precautions: Clean-up methods: Avoid skin and eye contact. Do not empty into drains / surface water / ground water. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of contaminated material as waste according to Section 13. SECTION 7. HANDLING AND STORAGE Page 2 of 5 LOCTITE 518 GASKET ELIMINATOR FLANGE SEALANT

Precautions for safe handling: See advice in section 8 Use only in well-ventilated areas. Conditions for safe storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Store below 100 F (38 C). SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National exposure standards: Ingredient form of exposure TWA (ppm) TWA (mg/m3) Peak Limit. (mg/m3) STEL (ppm) STEL (mg/m3) ACRYLIC ACID 79-10-7 (VAPOUR) 107-21-1 (VAPOUR) (PARTICULATE) 2 5.9 - - - Vapor. 20 52 - - - Vapor. - - - 40 104 Particulate. 10 - - - Engineering controls: Hygienic measures: Eye protection: Skin protection: Respiratory protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. Good industrial hygiene practices should be observed. Safety goggles or safety glasses with side shields. Use of an impervious apron is recommended. Recommended gloves include butyl rubber and neoprene. If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS 1716. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Specific gravity: 1.1 Flash point: > 100.00 C (> 212 F) Density: 1.1 g/cm3 Solubility: Solvent: Water, Slight SECTION 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Stable under normal conditions of temperature and pressure. Excessive heat. Page 3 of 5 LOCTITE 518 GASKET ELIMINATOR FLANGE SEALANT

Incompatible materials: Oxidizing agents. Aldehydes. Reducing agents. Hazardous decomposition products: In case of fire toxic gases can be released. Oxides of carbon. SECTION 11. TOXICOLOGICAL INFORMATION HEALTH EFFECTS: Ingestion: Skin: Eyes: Inhalation: May cause gastrointestinal disturbances. May be harmful if swallowed. Causes skin irritation. May cause sensitization by skin contact. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Causes serious eye irritation. Inhalation of vapors or mists of the product may be irritating to the respiratory system. Aggravated medical condition: Pre-existing skin, eye and respiratory allergies. Toxicity data: Acute oral toxicity: Acrylic acid 79-10-7 Cumene hydroperoxide 80-15-9 Ethanediol 107-21-1 Hydroxyethyl methacrylate-2 868-77-9 LD 50 (Rat) = 33.5 mg/kg LD 50 (Mouse) = 2,400 mg/kg LD 50 (Rat) = 2.5 g/kg LD 50 (Rat) = 193 mg/kg LD 50 (Rat) = 1,250 mg/kg LD Lo (Mouse) = 5,000 mg/kg LD 50 (Cat) = 1,650 mg/kg LD 50 (Dog) = 5,500 mg/kg LD 50 (Rat) = 5.89 g/kg LD 50 (Mouse) = 14.6 g/kg LD 50 (Guinea pig) = 8.20 g/kg LD 50 (Dog) = > 8.81 g/kg LD 50 (Mouse) = 3,275 mg/kg LD 50 (Rat) = 11.2 g/kg LD 50 (Rat) = 5,050 mg/kg SECTION 12. ECOLOGICAL INFORMATION General ecological information: Do not empty into drains / surface water / ground water. SECTION 13. DISPOSAL CONSIDERATIONS Waste disposal of product: Disposal for uncleaned package: Waste incineration or disposal with the approval of the responsible local authority. Collection and delivery to recycling enterprise or other registered elimination institution. Page 4 of 5 LOCTITE 518 GASKET ELIMINATOR FLANGE SEALANT

SECTION 14. TRANSPORT INFORMATION Road and Rail Transport: Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. SECTION 15. REGULATORY INFORMATION SUSDP Poisons Schedule: AICS: None All components are listed or are exempt from listing on the Australian Inventory of Chemical Substances (AICS). SECTION 16. OTHER INFORMATION Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code ASCC - Australian Safety and Compensation Council SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons STEL - Short term exposure limit TWA - Time weighted average Reason of change: New Material Safety Data Sheet format. involved chapters: 1-16 Date of previous issue: 21.07.2009 Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in this Material Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Material Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material's characteristics and, where appropriate, to conduct their own tests in the specific context of the material's intended use. Page 5 of 5 LOCTITE 518 GASKET ELIMINATOR FLANGE SEALANT