AEKYUNG CHEMICAL CO., LTD.

Transcription

1 AEKYUNG CHEMICAL CO., LTD. Material Safety Data Sheet * Issued Date : Dec PRODUCT AND COMPANY IDENTIFICATION Product name State Manufacturer POLYCOAT LSD-126 Liquid AEKYUNG CHEMICAL CO., LTD. #675, YEOKCHON-RI, JEONGSAN-MYEON, CHEONGYANG-GUN, CHUNGCHEONGNAM-DO, KOREA PHONE : / FAX : Emergency number AEKYUNG CHEMICAL CO., LTD. (R & D Center) #217-2, SINSEONG-DONG, YUSEONG-GU, DAEJEON, KOREA PHONE : / FAX : INFORMATION ON INGREDIENTS Number Chemical Material Content(%) CAS No. 1 Unsaturated polyester Styrene Monomer HAZARDS IDENTIFICATION This health hazard assessment is based on a consideration of the composition of this product

2 4. FIRST-AID MEASURES Inhalation After inhalation, move into fresh air. Remove victim from exposure. If victim is unconscious, administer artificial respiration and/or oxygen as needs. Seek medical aid. Skin contact Immediately remove contaminated clothing. Wash the contaminated skin areas with plenty of soap and water. Eye contact Immediately flush with plenty of water keeping the eyelid well open. Ingestion If ingested, consult a doctor and show him the packing or label. 5. FIRE-FIGHTING MEASURES Extinguishing media Specific hazards To be used : Extinguishers(like powder, alcohol resistant foam, CO2 or B-class), dried sand Not to be used : Water spray By combustion, formation of toxic products : carbon monoxide and carbon dioxide Special fire fighting procedures Unusual fire and explosion hazards Fire fighters and others exposed to vapor or products of combustion should wear self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use. At elevated temperature, such as in fire, polymerization may take place. If polymerization takes place in closed container, there is the possibility of violent rupture of the container. Product vapor may form an explosive mixture in air

3 Further prescriptions In case of fire, fire fighters should wear breathing apparatus with independent air supply. 6. ACCIDENTAL RELEASE MEASURES Personal precaution Environmental Avoid contact with skin and eyes. Avoid inhaling vapors. Wear protective equipment(glove, Goggles, Boots). Do not release to the environment. precautions Steps to be taken when material is released or spilled Remove all sources of ignition. Ventilate area. Absorb spill with an absorbent material such as sawdust, vermiculite or sand and place in a closed container. If large spill, dike the area to prevent this material from entering water systems or sewers. In case of washing : Acetone Methods for cleaning Absorb spillages in sand, earth or any suitable absorbent material. Transfer to a container for disposal. 7. HANDLING AND STORAGE Handling Avoid opening cans and/or drums in unventilated areas to avoid concentrated vapors. Avoid breathing vapors. Avoid contact with skin and eyes. Storage It should be kept in a closed container, and store at a well ventilated place. Avoid storage temperature above 30. Keep away from heat sources of ignition or direct sunlight

4 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limit (TLV/-TWA, TLV-STEL) 8 hours (TLV-TWA) Short period (TLV-STEL) REMARK ppm mg / mm3 ppm mg / mm FR DE(MAK) (30 Minutes) UK (10Minutes) USA (15 Minutes) 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling point (760mmHg) Freezing point Explosive or Flammable limits in air Vapor pressure (20 ) Specific gravity 145 (293 ) : Based on Styrene Monomer (-23 ) : Based on Styrene Monomer Lower 1.1% : Based on Styrene Monomer Upper 6.1% : Based on Styrene Monomer 6 hpa : Based on Styrene Monomer ABT (25, H 2 O=1) Vapor density (air=1) Solubility in water, Heavier than air Insolubility % by weight Appearance and odor Blue liquid, Pungent odor - 4 -

5 Viscosity (25 ) Flash point cps 31 (87 ) : Based on Styrene Monomer Closed cup method Auto-ignition temperature 490 (914 ) : Based on Styrene Monomer 10. STABILITY AND REACTIVITY Stability Incompatibility (Materials to avoid) Hazardous decomposition products Effects of overexposure Dangerous reaction Stable Type of peroxide (MEKPO, BPO, TBPB, etc.) Strong acids and oxidizing agents. Heating of this material to decomposition may cause the emission of irritating acrid fumes. Disintegration by rays of light and solar heat. Catalyst reaction induces an ionic or radical 11. TOXICOLOGICAL INFORMATION polymerization. Inhalation May be irritating to respiratory system. Skin contact May cause skin irritation. Eye contact May cause eye irritation. Ingestion May be harmful if swallowed. Long term exposure No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity No information available - 5 -

6 13. DISPOSAL CONSIDERATIONS Waste disposal method Incineration or landfill. Observe all federal, state, and local laws concerning health and environment. 14. TRANSPORT INFORMATION Dispose in accordance with local and state regulations. International regulation ⑴ Sea (IMO/IMDG) Proper shipping name : Resin Solution UN No. : 1866 Class : 3 Packing group : Ⅲ Label : EmS Guide : F-E, S-E ⑵ Air (ICAO / IATA) UN / ID No. : 1866 Class : 3 Packing group : Ⅲ Label : ⑶ Land (ADR/RID, RTMDR/RTMDF) Transport name : Resin Solution UN No. : 1866 Class : 3 Packing group : Ⅲ Label : - 6 -

7 15. REGULATORY INFORMATION Substance Identification No. : 1866 EEC Regulation ⑴ EEC Labeling Contains Styrene Monomer ⑵ R Phrases R 10 : Flammable. R 20 : Harmful by inhalation. R 36/38 : Irritating to eyes and skin. ⑶ S Phrases S 23 : Do not breathe gas / fumes / vapor / spray. S 26 : In case of eye contact, immediately rinse with plenty of water and seek medical advice. S 37/39 : Wear suitable gloves and eyes/face protection. ⑷ SYMBOLS Xn Harmful 16. OTHER INFORMATION The data given here is based on our current knowledge and experience. The data does not signify any warranty with regard to the products' properties. This information only describes safety measures and no liability may arise from the use of application of the product described herein