Safety Data Sheet. according to Regulation (EC) No 1907/2006 EGO MS 805

Transcription

1 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product group: MS Polymer 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Sealent / Adhesive 1.3. Details of the supplier of the safety data sheet Company name: Street: Kaltenbrunn 27 Place: D Garmisch-Partenkirchen Telephone: Telefax: raebiger@ego.de Contact person: Kai Räbiger Telephone: Internet: Responsible Department: Labor 1.4. Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture (24h/7d) GIZ-Nord, Göttingen Member of EPECs network Regulation (EC) No. 1272/2008 This mixture is not classified as hazardous according to Regulation (EC) No. 1272/ Label elements Regulation (EC) No. 1272/2008 Special labelling of certain mixtures EUH208 Contains reaction mass Bis-(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate and Methyl 1,2,2,6,6-pentamethyl-4-piperidylsebacate; 3-(2-Aminoethylamino)propyltrimethoxysilane, N-(3-(dimethoxymethylsilyl)propyl)ethylenediamine, Dioctyltinbis(acetylacetonate). May produce an allergic reaction. EUH210 Safety data sheet available on request. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization preparation from MS polymer, fillers and auxiliary agents Mixture of substances listed below with nonhazardous additions. Hazardous components CAS No Chemical name EC No Index No REACH No Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity Vinyltrimethoxysilane 1 - <5 % Flam. Liq. 3, Acute Tox. 4; H226 H332 Full text of H and EUH statements: see section 16.

2 Page 2 of 7 SECTION 4: First aid measures 4.1. Description of first aid measures General information No hazards which require special first aid measures. Change contaminated clothing. In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if possible). After inhalation Move to fresh air. If symptoms persist, call a physician. After contact with skin Remove mechanically (e.g. dab away using wadding or cellulose material) then thoroughly wash the affected skin with a mild cleanser and water. In general the product is not irritant to skin. If skin irritation persists, call a physician. After contact with eyes After contact with eye rinse immediately with lot of water at least 5 minutes with open eyelid. Subsequently consult an opthalmologist. If easy to do, remove contact lens, if worn. After ingestion Rinse mouth thoroughly with water. In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if possible). Possible decomposition products in case of hydrolysis are: Methanol 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Foam. Dry extinguishing powder. Carbon dioxide (CO2). Atomized water. Extinguishing materials should be selected according to the surrounding area. Unsuitable extinguishing media High power water jet Special hazards arising from the substance or mixture In the event of fire the following can be released: Carbon dioxide (CO2), Carbon monoxide Advice for firefighters Protective clothing. In case of fire: Wear self-contained breathing apparatus. Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear suitable protective clothing. Avoid contact with the skin and the eyes. Ensure adequate ventilation Environmental precautions Do not flush into surface water or sanitary sewer system Methods and material for containment and cleaning up Collect mechanically. Cleaning with white-spirit possible.

3 Page 3 of Reference to other sections See protective measures under point 7 and 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling When using do not eat, drink or smoke. Wash hands when done working with material; at breaks, lunch, shift changes, etc. Provide adequate ventilation. Avoid contact with skin, eye and clothing. Advice on protection against fire and explosion No special precautions required Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep containers tightly closed in a dry, cool and well-ventilated place. Advice on storage compatibility Not required Further information on storage conditions Keep containers dry and tightly closed to avoid moisture absorption and contamination Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective and hygiene measures When using, do not eat, drink or smoke. Wash hands when done working with material; at breaks, lunch, shift changes, etc. Handle in accordance with good industrial hygiene and safety practice. Eye/face protection Safety glasses Hand protection Avoid contact with skin. Protective gloves complying with EN 374. Suitable material: butyl-rubber, Nitrile rubber, PVC, Chloroprene, Fluorinated rubber, Natural Rubber. Wearing time >480 minutes Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection Protective suit Respiratory protection No personal respiratory protective equipment normally required. Provide adequate ventilation. In case of insufficient ventilation wear suitable respiratory equipment.

4 Page 4 of 7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Explosive properties The product is: not Explosive. Lower explosion limits: Upper explosion limits: Ignition temperature: Decomposition temperature: Vapour pressure: Density: Water solubility: Viscosity / dynamic: Viscosity / kinematic: 9.2. Other information The product is: not auto-flammable SECTION 10: Stability and reactivity Reactivity polymerisation initiators: moisture Chemical stability The product is chemically stable. No decomposition if used as directed Possibility of hazardous reactions Paste various slight No dangerous reaction known under conditions of normal use Conditions to avoid Incompatible materials Hazardous decomposition products not applicable >100 C not applicable 420 C approx. 1,5 g/cm³ insoluble Test method

5 Page 5 of 7 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Health injuries are not known or expected under normal use. CAS No Chemical name Exposure routes Method Dose Species Source Vinyltrimethoxysilane inhalative vapour ATE 11 mg/l inhalative aerosol ATE 1,5 mg/l Irritation and corrosivity No skin irritation No eye irritation Sensitising effects No known effect. STOT-single exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Aspiration hazard Due to the viscosity, this product does not present an aspiration hazard. Practical experience Observations relevant to classification SECTION 12: Ecological information Toxicity Do not allow uncontrolled leakage of product into the environment Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment not applicable Other adverse effects

6 Page 6 of 7 SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Dispose of waste according to applicable local, state, and federal regulations. Waste disposal number of waste from residues/unused products WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants containing organic solvents or other hazardous substances Classified as hazardous waste. Waste disposal number of used product WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants containing organic solvents or other hazardous substances Classified as hazardous waste. Contaminated packaging Dispose of waste according to applicable local, state, and federal regulations. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine transport (IMDG) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine pollutant: no Air transport (ICAO) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture

7 Page 7 of 7 EU regulatory information 2004/42/EC (VOC): National regulatory information Water contaminating class (D): Chemical safety assessment 2,4 %; 38 g/l 1 - slightly water contaminating Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Changes This data sheet contains changes from the previous version in section(s): 1,2,3,7,8,9,11,15. Relevant H and EUH statements (number and full text) H226 Flammable liquid and vapour. H332 Harmful if inhaled. EUH208 Contains reaction mass Bis-(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate and Methyl 1,2,2,6,6-pentamethyl-4-piperidylsebacate; 3-(2-Aminoethylamino)propyltrimethoxysilane, N-(3-(dimethoxymethylsilyl)propyl)ethylenediamine, Dioctyltinbis(acetylacetonate). May produce an allergic reaction. EUH210 Safety data sheet available on request. Further Information These data describe only the safety requirements for the product(s) and are based on our present knowledge. However, they do not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)