Safety Data Sheet. according to Regulation (EC) No 1907/2006. Renfert Sekundenkleber

Transcription

1 Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Further trade names Concret Liquicol / Sekundenkleber / Sekundenkleber 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Adhesives, sealants 1.3. Details of the supplier of the safety data sheet Company name: Street: Place: Untere Giesswiesen 2 D Hilzingen Telephone: Telefax: info@renfert.com Contact person: Frau Andris Telephone: Internet: Emergency telephone number: Vergiftungs-Zentrale Freiburg SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.2. Label elements Danger symbols: Indications of danger: Xi - Irritant R phrases: Irritating to eyes, respiratory system and skin. Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Xi - Irritant Xi - Irritant R phrases 36/37/38 Irritating to eyes, respiratory system and skin. S phrases 23 Do not breathe Do not breathe vapour.. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 51 Use only in well-ventilated areas. 24/25 Avoid contact with skin and eyes. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Special labelling of certain mixtures Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.

2 Page 2 of 6 Additional advice on labelling The R and S phrases can be omitted if the pack contains no more than 0,125 litres. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Adhesive (Ethyl-2-cyanoacrylat) Hazardous components EC No CAS No Index No REACH No Chemical name Classification GHS classification Quantity ethyl 2-cyanoacrylate Xi - Irritant R36/37/ Eye Irrit. 2, STOT SE 3, Skin Irrit. 2; H319 H335 H315 Full text of R and H phrases: see Section 16. > 10 % SECTION 4: First aid measures 4.1. Description of first aid measures After inhalation Provide fresh air. Seek medical attention if problems persist. After contact with skin After contact with skin, wash immediately with plenty of water and soap. In case of skin irritation, consult a physician. After contact with eyes In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After ingestion Call a physician immediately Most important symptoms and effects, both acute and delayed Lung irritation, Dyspnoea 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media alcohol resistant foam. Extinguishing powder Carbon dioxide (CO2) Water spray jet Unsuitable extinguishing media Full water jet 5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to the escape of irritating gases and vapours. Can be released in case of fire: Carbon dioxide (CO2). Nitrogen oxides (NOx) Advice for firefighters In case of fire and/or explosion do not breathe fumes. In case of fire: Wear self-contained breathing apparatus.

3 Page 3 of 6 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protection equipment. Provide adequate ventilation Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Allow stiffening. Take up mechanically Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Open and handle container with care. Use only in well-ventilated areas. Advice on protection against fire and explosion Keep away from sources of ignition. - No smoking. Further information on handling If handled uncovered, arrangements with local exhaust ventilation have to be used Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep only in the original container in a cool, well-ventilated place. Keep container tightly closed. Advice on storage compatibility Do not store together with: Alkalis (alkalis). Further information on storage conditions Do not store at temperatures over: 10 C Keep the packing dry and well sealed to prevent contamination and absorbtion of humidity. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m³ fibres/ml Category Origin Ethyl cyanoacrylate - - TWA (8 h) WEL 8.2. Exposure controls Appropriate engineering controls Safe handling: see section 7 Protective and hygiene measures Do not breathe vapour. Avoid contact with skin, eyes and clothes. Wash hands before breaks and after work STEL (15 min) WEL

4 Page 4 of 6 Protect skin by using skin protective cream. Eye/face protection Wear eye/face protection. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. (DIN EN 374) Suitable material: NBR (Nitrile rubber) Thickness of glove material: 0,5 mm Breakthrough time: > 30 min For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Respiratory protection Respiratory protection necessary at: insufficient ventilation Environmental exposure controls Do not allow to enter into surface water or drains. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Initial boiling point and boiling range: Flash point: liquid colourless characteristic > 200 C 87 C Explosive properties not explosive. Density (at 20 C): 1,05-1,09 g/cm³ Water solubility: practically insoluble Viscosity / dynamic: (at 25 C) mpa s Test method DIN SECTION 10: Stability and reactivity Reactivity The product is chemically stable under recommended conditions of storage, use and temperature Chemical stability The mixture is chemically stable under recommended conditions of storage, use and temperature Possibility of hazardous reactions Polymerisation with evolution of heat Conditions to avoid See section 7. No additional measures necessary Incompatible materials Violent reaction with: Oxidizing agents, strong. Water. Amines. Alcohols. Alkali (lye) Hazardous decomposition products Gases/vapours, irritant

5 Page 5 of 6 SECTION 11: Toxicological information Information on toxicological effects Irritation and corrosivity Irritating to eyes, respiratory system and skin. Sensitising effects May cause sensitization by inhalation. STOT-single exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Aspiration hazard Practical experience Observations relevant to classification Irritating to eyes, respiratory system and skin. Cyanacrylate! Danger! Skin and eyelids will stick together in seconds. Keep out of the reach of children. Further information The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC). SECTION 12: Ecological information Toxicity Persistence and degradability Due to the consistency along with the low water solubility of the product a bioavailability is unlikely Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Further information Do not allow uncontrolled discharge of product into the environment. The product has not been tested. Due to the consistency along with the low water solubility of the product a bioavailability is unlikely. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Remove according to the regulations. Waste disposal number of waste from residues/unused products

6 Page 6 of WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants containing organic solvents or other dangerous substances Classified as hazardous waste. Contaminated packaging Handle contaminated packages in the same way as the substance itself. SECTION 14: Transport information Land transport (ADR/RID) Other applicable information (land transport) No dangerous good in sense of these transport regulations. Marine transport (IMDG) Other applicable information (marine transport) No dangerous good in sense of these transport regulations. Air transport (ICAO) Other applicable information (air transport) No dangerous good in sense of these transport regulations. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 1999/13/EC (VOC): National regulatory information Water contaminating class (D): 1 - slightly water contaminating SECTION 16: Other information Full text of R phrases referred to under Sections 2 and 3 36/37/38 Irritating to eyes, respiratory system and skin. Full text of H statements referred to under Sections 2 and 3 H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. Restricted to professional users. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)