Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Number: Issue date: 03/15/ PRODUCT AND COMPANY IDENTIFICATION Product name: TURCO 6871 Product type: Cleaner IDH number: Region: United States Company address: Henkel Corporation Stephenson Highway Madison Heights, MI Contact information: Telephone: For Chemical Emergency: Call CHEMTREC at Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 2 Color: Amber FLAMMABILITY: 1 Odor: Surfactant PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: CAUSES EYE AND SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. ASPIRATION HAZARD IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Aspiration may cause lung damage. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. High vapor/aerosol concentrations may be irritating. Contact can cause moderate to severe irritation and possible injury to the eyes. Acute ingestion may result in mild gastrointestinal distress. Small amounts of this product, if aspirated into the lungs, may cause mild to severe pulmonary injury. Eye, skin and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Alcohol (C12-15) poly(1-6) ethoxylates Proprietary Coconut diethanolamide Proprietary Dipropylene glycol monomethyl ether Page 1 of 5

2 4. FIRST AID MEASURES Inhalation: Skin contact: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. In case of adverse health effects seek medical advice. For skin contact flush with large amounts of water. If skin irritation persists, call a physician. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Notes to physician: Seek medical advice. DO NOT induce vomiting unless directed to do so by medical personnel. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: > 200 F (> C) calculated Use media appropriate for surrounding material. Wear full protective clothing. Wear self-contained breathing apparatus. This product is an aqueous mixture and although it will exhibit a flash point, it will not support combustion. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Contain spill. Do not allow product to enter sewer or waterways. Wear appropriate personal protective equipment. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing mists or aerosols of this product. Do not take internally. Use only with adequate ventilation. Wash thoroughly after handling. Do not mix this product with fluids which contain NITRITES/NITRATES. NITROSAMINE may be formed. For safe storage, store between 40 F (4.4 C) and 100 F (37.8 C) Store in a cool, dry, well-ventilated area. Thaw and mix thoroughly if frozen. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 5

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Alcohol (C12-15) poly(1-6) ethoxylates None None None None Coconut diethanolamide None None None None (SKIN) Inhalable fraction and vapor. 1 mg/m3 TWA Inhalable fraction and vapor. None None None 100 ppm TWA 100 ppm (600 Dipropylene glycol monomethyl ether 150 ppm STEL mg/m3) TWA None None (SKIN) (SKIN) Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Wear impervious gloves for prolonged contact. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Amber Odor: Surfactant Odor threshold: Not available ph: Vapor pressure: mm hg Approximately Boiling point/range: > 100 C (> 212 F) calculated Melting point/ range: Specific gravity: at 25 C (77 F) Vapor density: Flash point: > 200 F (> C) calculated Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Complete Partition coefficient (n-octanol/water): VOC content: 3.5 % (calculated) Viscosity: mpa.s Page 3 of 5

4 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable at normal conditions. Will not occur. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. This product may react with strong acids or oxidizing agents. Do not mix this product with nitrites or other nitrosating agents because a carcinogenic nitrosamine may be formed. Avoid excessive heat and ignition sources. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Alcohol (C12-15) poly(1-6) ethoxylates No No No Coconut diethanolamide No No No No No No Dipropylene glycol monomethyl ether No No No Hazardous components Alcohol (C12-15) poly(1-6) ethoxylates Coconut diethanolamide Dipropylene glycol monomethyl ether Health Effects/Target Organs No Target Organs Allergen, Irritant, Kidney, Skin, Some evidence of carcinogenicity, Thyroid Allergen, Blood, Brain, Central nervous system, Corrosive, Heart, Irritant, Kidney, Liver, Respiratory, Spleen Central nervous system, Irritant, Liver 12. ECOLOGICAL INFORMATION Ecological information: Not available 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. 14. TRANSPORT INFORMATION The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging as exceptions may apply. Refer to shipping documents for package specific transportation classification. U.S. Department of Transportation Ground (49 CFR) Environmentally hazardous substances, liquid, n.o.s. DOT Reportable quantity: Exceptions: Unrestricted, (Not more than 450 Liters) Page 4 of 5

5 International Air Transportation (ICAO/IATA) Environmentally hazardous substance, liquid, n.o.s. Water Transportation (IMO/IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12(b) Export Notification: Glycol ether (CAS# ). CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: CERCLA Reportable quantity: California Proposition 65: None above reporting de minimus Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). (CAS# ). Dipropylene glycol monomethyl ether (CAS# ). (CAS# ) 100 lbs. (45.4 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New information added in Section(s): 4, 7 and 10. Prepared by: John DiCerbo, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5