MATERIAL SAFETY DATA SHEET QS-54

Transcription

1 SECTION 1: Company Name: Address: Phone No. Fax No. Emergency Phone No. Date Prepared: Date Revised: ChemWorld.com 885 Woodstock Rd Ste Roswell, GA CHEM-TEL /30/08 9/24/09 IDENTIFICATION SECTION 2: INGREDIENTS MATERIAL CAS NO. % HYDROGEN PEROXIDE SECTION 3: SECTION 4: Overview: Ingestion: Inhalation: Skin Contact: Eye Contact: Other Information: Ingestion: Inhalation: Skin Contact: Eye Contact: Notes to Physician: HEALTH HAZARDS DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE. CAUSES BURNS TO SKIN, EYES, AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED OR INHALED CORROSIVE AND IRRITATING TO THE MOUTH, THROAT, AND ABDOMEN. LARGE DOSES MAY CAUSE SYMPTOMS OF ABDOMINAL PAIN, VOMITING, AND DIARRHEA AS WELL AS BLISTERING OR TISSUE DESTRUCTION. STOMACH DISTENTION (DUE TO RAPID LIBERATION OF OXYGEN), AND RISK OF STOMACH PERFORATION, CONVULSIONS, PULMONARY EDEMA, COMA, POSSIBLE CEREBRAL EDEMA (FLUID ON THE BRAIN), AND DEATH ARE POSSIBLE VAPORS ARE CORROSIVE AND IRRITATING TO THE RESPIRATORY TRACT. INHALATION OF MIST MAY BURN THE MUCOUS MEMBRANE OF THE NOSE AND THROAT. IN SEVERE CASES, EXPOSURES MAY RESULT IN PULMONARY EDEMA AND DEATH. CORROSIVE. SYMPTOMS OF REDNESS, PAIN, AND SEVERE BURN CAN OCCUR. VAPORS ARE VERY CORROSIVE AND IRRITATING TO THE EYES. SYMPTOMS INCLUDE PAIN, REDNESS AND BLURRED VISION. SPLASHES CAN CAUSE PERMANENT TISSUE DESTRUCTION. PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. FIRST AID DRINK SEVERAL GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY WASH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED SHOES AND CLOTHING. GET MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY FLUSH WITH CLEAR WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION IMMEDIATELY. PULMONARY EDEMA MAY BE DELAYED FOR 24 TO 72 HOURS; KEEP UNDER OBSERVATION. GASTRIC LAVAGE MAY BE NECESSARY IF SWALLOWED. ANALYSIS OF BODY FLUIDS (PARTICULARLY GASTRIC ASPIRATES) USING THE TITANIUM CHLORIDE REACTION, IF DONE IMMEDIATELY, WILL REVEAL PEROXIDES.

2 SECTION 5: SECTION 6: Flash Point/Method: Upper/Lower Limit in Air: Extinguishing Media: Procedures: Unusual Hazards: Combustion Products: Personal Precautions: Procedures for Clean-up: Prohibited Materials. FIRE AND EXPLOSION HAZARD DATA NOT COMBUSTIBLE, BUT SUBSTANCE IS A STRONG OXIDIZER AND ITS HEAT OF REACTION WITH REDUCING AGENTS OR COMBUSTIBLES MAY CAUSE IGNITION. INCREASES THE FLAMMABILITY OF COMBUSTIBLE, ORGANIC AND READILY OXIDIZABLE MATERIALS. N.A./N.A. WATER SPRAY MAY BE USED TO EXTINGUISH SURROUNDING FIRE AND COOL EXPOSED CONTAINERS. WATER SPRAY WILL ALSO REDUCE FUME AND IRRITANT GASES. FIREFIGHTERS SHOULD WEAR NORMAL PROTECTIVE EQUIPMENT. SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED IN CONFINED AREAS. CONTACT WITH OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT COMBUSTION. DRYING OF CONCENTRATED HYDROGEN PEROXIDE ON CLOTHING OR OTHER COMBUSTIBLE MATERIALS MAY CAUSE FIRE OR EXPLOSION. SEALED CONTAINERS MAY RUPTURE WHEN HEATED. NOT COMBUSTIBLE ACCIDENTAL RELEASE MEASURES WEAR PERSONAL PROTECTIVE EQUIPMENT AS RECOMMENDED IN SECTION 8. VENTILATE AREA OF LEAK OR SPILL. CONTAIN AND RECOVER LIQUID WHEN POSSIBLE. DO NOT RETURN SPILLED MATERIAL TO ORIGINAL CONTAINER. LARGER SPILLS: DILUTE WITH A LARGE AMOUNT OF WATER AND HOLD IN A POND OR DYKED AREA UNTIL THE PEROXIDE DECOMPOSES FOLLOWED BY DISCHARGE INTO A SUITABLE TREATMENT SYSTEM. MAY BE NEUTRALIZED WITH SODIUM METABISULFITE OR SODIUM SULFITE AFTER DILUTING TO 5-10% PEROXIDE. DO NOT FLUSH UNDILUTED MATERIAL TO SEWER. THIS OXIDIZING MATERIAL CAN INCREASE THE FLAMMABILITY OF ADJACENT COMBUSTIBLE MATERIALS. EMPTY CONTAINERS SHOULD BE RINSED WITH WATER BEFORE DISCARDING. CAUTION! CAUSTIC MATERIAL. CAUSES FIRES WITH ORGANIC MATERIAL. SECTION 7: Handling: Storage: HANDLING AND STORAGE PRACTICE ROUTINE INDUSTRIAL HYGIENE, FOLLOW ANY SPECIFIC INSTRUCTIONS ON PRODUCT DATA SHEET, PRODUCT LABEL, OR SPECIFIC APPLICATION INSTRUCTIONS PROVIDED BY SERVICE PERSONNEL STORE IN A COOL(< 35C), WELL-VENTILATED DARK AREA SEPARATED FROM COMBUSTIBLE SUBSTANCES, REDUCING AGENTS, STRONG BASES, ORGANICS.DO NOT STORE ON WOODEN SHELVES OR FLOORS. SUGGEST ROTATION OF STOCK. CONTAINERS MUST BE VENTED, BUT CHECK PERIODICALLY FOR BULGING CONTAINERS WHICH CAN BURST FROM PRESSURE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE, CONTAMINATION, HEAT AND INCOMPATIBLES. CONTAMINATION FROM ANY SOURCE (DUST, METALS) MAY CAUSE RAPID DECOMPOSITION WITH GENERATION OF LARGE QUANTITIES OF OXYGEN GAS AND HIGH PRESSURES. RINSE EMPTY CONTAINERS THOROUGHLY WITH CLEAN WATER. GLASS, POLYETHYLENE, STAINLESS STEEL AND ALUMINUM ARE RECOMMENDED MATERIALS FOR STORAGE CONTAINERS. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.

3 SECTION 8: Precautionary Measures: SECTION 9: Engineering Controls: Control Limits: Equipment for Personal Protection: Appearance: Odor: ph (undiluted): Specific Gravity: Density: Solubility in Water: Boiling Point: Melting Point: Percent Volatile (70º F): Vapor Pressure (mmhg): Vapor Density: Evaporation Rate: SECTION 10: Stability: Conditions to Avoid: Hazardous Polymerization: Incompatibility: Hazardous Decomposition Products: SECTION 11: SECTION 12: Material & Tests: Aquatic Toxicity: EXPOSURE CONTROLS/PERSONAL PROTECTION STANDARD INDUSTRIAL HANDLING PRECAUTIONS. WASH THOROUGHLY AFTER HANDLING CHEMICALS. USE WITH ADEQUATE VENTILATION TO KEEP EXPOSURES BELOW OCCUPATIONAL EXPOSURE LIMITS. IF THE EXPOSURE LIMIT IS EXCEEDED, WEAR A SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD, OR FULL-FACEPIECE SELF-CONTAINED BREATHING APPARATUS. THIS SUBSTANCE HAS UNKNOWN WARNING PROPERTIES. OSHA PEL = 1 ppm (TWA); ACGIH TLV = 1 ppm (TWA), A3: ANIMAL CARCINOGEN. WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN CONTACT. USE CHEMICAL SAFETY GOGGLES AND/OR A FULL FACE SHIELD WHERE SPLASHING IS POSSIBLE. EYEWASH STATION AND SAFETY SHOWER IN AREA OF USE. PHYSICAL AND CHEMICAL PROPERTIES CLEAR COLORLESS LIQUID SLIGHT ACRID ODOR lbs./gal. COMPLETE 226º F (DECOMPOSES) -13º F (86º F) 1.17 (AIR = 1) <1(BuAc = 1) STABILITY AND REACTIVITY NORMALLY STABLE IF UNCONTAMINATED, BUT SLOWLY DECOMPOSES TO RELEASE OXYGEN. UNSTABLE WITH HEAT, MAY RESULT IN DANGEROUS PRESSURES. A STRONG OXIDIZER, REACTS VIOLENTLY UPON CONTACT WITH MANY ORGANIC SUBSTANCES, PARTICULARLY TEXTILE AND PAPER. AVOID LIGHT AND KEEP IN A CLOSED BUT VENTED CONTAINER TO PREVENT EVAPORATION (CONCENTRATION) AND CONTAMINATION. AVOID EXCESS HEAT AND CONTACT WITH COMBUSTIBLE OR ORGANIC MATERIALS. LIGHT AND INCOMPATIBLES. WILL NOT OCCUR HEAT, REDUCING AGENTS, ORGANIC MATERIALS, DIRT, ALKALIS, RUST, AND MANY METALS. SPONTANEOUS COMBUSTION MAY OCCUR ON STANDING IN CONTACT WITH READILY FLAMMABLE MATERIALS. DECOMPOSES TO WATER AND OXYGEN WITH RAPID HEAT RELEASE. USE VENTED CONTAINERS. THE SOLUTION CAN DECOMPOSE VIOLENTLY UPON HEATING. TOXICOLOGICAL INFORMATION NO LD50/LC50 INFORMATION FOUND RELATING TO NORMAL ROUTES OF OCCUPATIONAL EXPOSURE. INVESTIGATED AS A TUMORIGEN AND MUTAGEN. ECOLOGICAL INFORMATION NO INFORMATION FOUND

4 SECTION 13: General Considerations: SECTION 14: Shipping Name: Primary Hazard Class: Secondary Hazard Class: Identification No.: Packing Group: 2008 NAERG No.: DISPOSAL CONSIDERATIONS WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE AND SENT TO A RCRA APPROVED WASTE FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT MAY CHANGE THE WASTE MANAGEMENT OPTIONS. STATE AND LOCAL DISPOSAL REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. OBEY ALL FEDERAL, STATE OR LOCAL REGULATIONS. TRANSPORT INFORMATION HYDROGEN PEROXIDE, AQUEOUS SOLUTION (20 40%) HYDROGEN PEROXIDE UN2014 II 140 SECTION 15: Regulation CERCLA (40 CFR302.4): SARA 302 (Sect. 355, Appendix A): REGULATORY INFORMATION Material RQ Max. % Material TPQ Max. % SARA 311/312: Categories IMMEDIATE HEALTH, FIRE Hazards EYE/SKIN CORROSIVE, OXIDIZER SARA 313 (40 CFR ): CWA (40 CFR ): RCRA (40 CFR 261): Material Max. % OSHA (29 CFR ): TSCA: ALL COMPONENTS LISTED UNDER THIS STANDARD ARE SHOWN IN SECTION 2 OF THIS MSDS. ALL INGREDIENTS IN THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY. SPECIAL STATE REGULATIONS STATE CA, MN, NJ, PA INGREDIENT HYDROGEN PEROXIDE % 30 REGULATORY DESIGNATION HAZARDOUS MATERIALS LISTS SECTION 16 OTHER INFORMATION NFPA* OX SUGGESTED HAZARD RATINGS HAZARD HEALTH (Blue) FIRE (Red) REACTIVITY (Yellow) PERSONAL PROTECTION SPECIAL HAZARDS HMIS* D *Notes: 0 = Insignificant; 1 = Slight; 2 = Moderate; 3 = High; 4 = Extreme

5 The data contained in this Material Safety Data Sheet has been prepared based upon an evaluation of the ingredients in the product, their concentration in the product and potential interactions. The information is offered in good faith and is believed to be accurate. It is furnished to the customer who is urged to study it carefully to become aware of hazards, if any, in the storage, handling, use and disposal of the product; and to insure his employees are properly informed and advised of all safety precautions required. The information is furnished for compliance with the "Occupational Safety and Health Act" of 1970, the "Hazards Communication Act" of 1983 as well as various other Federal, State and Local regulations. Use or dissemination of all or part of this information for any other purpose is prohibited by law.