: Abamectin 18g/l EC

Transcription

1 Revision date: : Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name. Product code : Abamectin 18g/l EC : FI Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/preparation : Professional use : Insecticide/Acaricide to be used by professionals for agriculture Uses advised against 1.3. Details of the supplier of the safety data sheet Rotam Agrochemical Company Ltd 7/F. Cheung Tat Centre, No.18, Cheung Lee Street, Chai Wan Hong Kong T , F , msds@rotam.com 1.4. Emergency telephone number Emergency number : (86) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Oral) H302 Acute Tox. 4 (Inhalation) H332 Eye irritant 2 H319 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 GHS09 : Warning : H302 - Harmful if swallowed H332 - Harmful if inhaled. H319 - Cause serious eye irritation. H410 - Very toxic to aquatic life with long lasting effects : P261 Avoid breathing spray. P264 - Wash hands thoroughly after handling. P270 - Do no eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment P301+P312 - If swallowed, call a doctor if you feel unwell. P304+P340 - If inhaled, Remove person to fresh aie and keep comfortable for breathing. P305+P351+P338 - If in eyes, rinse cautiously with water for several minutes. Remove contactleness, if present and easy to do. Continue rinsing. P312 - Call a poision centre if you feel unwell. P330 - Rinse mouth. P391 - Collect spillage P501 - Dispose of contents/container to local regulation Other hazards EN (English) 1/6

2 SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier g/l Classification according to Directive 67/548/EEC abamectin (CAS No.) (EC no) T+; R26/28 N; R50/53 Name Product identifier g/l Classification according to Regulation (EC) No. 1272/2008 [CLP] abamectin (CAS No.) (EC no) Full text of R-, H- and EUH-phrases: see section Acute Tox. 2 (Oral), H300 Acute Tox. 1 (Inhalation), H330 Aquatic Acute 1, H400 (M=10000) Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a physician or poison control center immediately. : When symptoms occur: go into open air and ventilate suspected area. : When symptoms occur: rinse immediately with plenty of water. : Rinse eyes with plenty of water. Get medical attention if needed. : Rinse mouth and then drink plenty of water. DO NOT induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Call a physician or poison control center immediately. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). : high volume water jet Special hazards arising from the substance or mixture Fire hazard : Hazardous decomposition products may be released during prolonged heating like smokes, carbon monoxide and dioxide, nitrogen oxides (NOx). Explosion hazard : Product is not explosive. Reactivity : The product is stable at normal handling- and storage conditions Advice for firefighters Precautionary measures fire : Wear self-contained breathing apparatus and protective suit (see item 8). Firefighting instructions : Prevent runoff from entering drains, sewers or waterways. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment For emergency responders Protective equipment : Wear personal protective equipment. : Wear a self-contained breathing apparatus and appropriate personal protective equipment (PPE) Environmental precautions Do not allow material to contaminate ground water system Methods and material for containment and cleaning up For containment : Sweep or shovel spills into appropriate container for disposal. Methods for cleaning up : Large spills: scoop solid spill into closing containers. Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal Reference to other sections EN (English) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling : Wear proper protective equipment. : Do NOT get in eyes, on skin or on clothing Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Pale yellow. Colour : No data available Odour : Characteristic odour. Odour threshold : No data available ph : % solution Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : 76.5 C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 C : No data available Relative density : C Density : No data available Solubility : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : Product is not explosive. Oxidising Not classified Other information SECTION 10: Stability and reactivity Reactivity The product is stable at normal handling and storage conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid All heat sources, including direct sunlight EN (English) 3/6

4 10.5. Incompatible materials Strong acids, strong bases and oxidation agents Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Abamectin 18g/l EC LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard mg/kg > 2000 mg/kg mg/l/4h : Not irritant to skin : Irritant to eyes : Did not cause sensitisation. SECTION 12: Ecological information Toxicity Abamectin 18g/l EC LC50 fish 5.31 mg/l Brachydanio rerio (Report No. RFD1 07/00) EC50 Daphnia mg/l Daphnia magna (Report No ) ErC50 (algae) 13.2 mg/l Selenastrum capricornutum (Report No. RF-D ) Persistence and degradability Bioaccumulative potential Log Pow Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number UN-No. : UN proper shipping name Proper Shipping Name Transport document description : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (abamectin) : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (abamectin) 9, III, (E) Transport hazard class(es) Class (UN) : EN (English) 4/6

5 Hazard labels (UN) : Packing group Packing group (UN) : III Environmental hazards Dangerous for the environment : Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 90 Classification code (UN) : M6 Orange plates : Tunnel restriction code LQ Excepted quantities (ADR) EAC code : E : LQ07 : E1 : 3Z Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance National regulations Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-phrases:: Acute Tox. 1 (Inhalation) Acute toxicity (inhalation) Category 1 Acute Tox. 2 (Oral) Acute toxicity (oral) Category 2 Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1 H300 Fatal if swallowed H302 Harmful if swallowed H330 Fatal if inhaled H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects R26/28 Very toxic by inhalation and if swallowed EN (English) 5/6

6 R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. N Dangerous for the environment T+ Very toxic SDS EU (REACH Annex II) Disclaimer: The information provided by Rotam Agrochemical Co., Ltd contained herein is given in good faith and correct to the best of our knowledge. However, the information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification EN (English) 6/6