Safety Data Sheet according to Regulation (EC) No1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No1907/2006 LOCTITE 5972 known as Loctite 5972 Page 1 of 11 SDS No. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 5972 known as Loctite 5972 Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Solvent based high temperature gasket 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Flammable liquids Category 2 H225 Highly flammable liquid and vapor. Serious eye irritation Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - single exposure Category 3 H336 May cause drowsiness or dizziness. Target organ: Central Nervous System

2 LOCTITE 5972 known as Loctite 5972 Page 2 of 11 Classification (DPD): F - Highly flammable R11 Highly flammable. Xi - Irritant R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness Label elements Label elements (CLP): Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Prevention Precautionary statement: Response Danger H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing vapours. P337+P313 If eye irritation persists: Get medical advice/attention. Label elements (DPD): F - Highly flammable Xi - Irritant Risk phrases: R11 Highly flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas Other hazards None if used properly. General chemical description: Solvent based high temperature gasket SECTION 3: Composition/information on ingredients

3 LOCTITE 5972 known as Loctite 5972 Page 3 of 11 Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification >= 20- < 40 % Flammable liquids 2 H225 Serious eye irritation 2 H319 Specific target organ toxicity - single exposure 3 H336 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: EC Number REACH-Reg No content Classification >= 20 - < 40 % F - Highly flammable; R11 Xi - Irritant; R36 R67 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. Vapors may cause drowsiness and dizziness Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Foam, extinguishing powder, carbon dioxide. SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet

4 LOCTITE 5972 known as Loctite 5972 Page 4 of Special hazards arising from the substance or mixture Do not expose to direct heat. Formation of toxic gases is possible during heating or in fires. Oxides of carbon, oxides of nitrogen, irritating organic vapors Advice for firefighters Wear self-contained breathing apparatus. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. Remove sources of ignition. Ensure adequate ventilation Environmental precautions Do not empty into drains / surface water / ground water s and material for containment and cleaning up Wipe up using absorbent material. Store in a partly filled, closed container until disposal. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section Precautions for safe handling Avoid skin and eye contact. Keep away from sources of ignition - no smoking. Vapours should be extracted to avoid inhalation. See advice in section 8 Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry place. Do not store near sources of heat or ignition, or reactive materials Specific end use(s) Solvent based high temperature gasket

5 LOCTITE 5972 known as Loctite 5972 Page 5 of 11 SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks PROPAN-2-OL Short Term EH40 WEL Limit (STEL): PROPAN-2-OL Time Weighted Average EH40 WEL (TWA): TALC, RESPIRABLE DUST 1 Time Weighted Average EH40 WEL (TWA): GRAPHITE, INHALABLE DUST 10 Time Weighted Average EH40 WEL (TWA): GRAPHITE, RESPIRABLE DUST Time Weighted Average (TWA): EH40 WEL Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) sediment (freshwater) sediment (marine water) soil aqua (intermittent releases) STP oral period Value mg/l ppm mg/kg others 140,9 mg/l 552 mg/kg 552 mg/kg 28 mg/kg 140,9 mg/l 140,9 mg/l 2251 mg/l 160 mg/kg food Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker Dermal Long term exposure - systemic effects worker inhalation Long term exposure - systemic effects general Dermal Long term population exposure - systemic effects general population general population inhalation oral Long term exposure - systemic effects Long term exposure - systemic effects Time Value 888 mg/kg bw/day 500 mg/m3 319 mg/kg bw/day 89 mg/m3 26 mg/kg bw/day Remarks

6 LOCTITE 5972 known as Loctite 5972 Page 6 of 11 Biological Indices: None 8.2. controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. Skin protection: Suitable protective clothing SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor alcohol-like Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure (20 C (68 F)) Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solubility (qualitative) (Solvent: Acetone) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits lower upper 85 C (185 F) 15 C (59 F) < 33 mm hg 1,1-1,2 g/cm3 Partially miscible Partially miscible 2,3 %(V) 12,7 %(V)

7 LOCTITE 5972 known as Loctite 5972 Page 7 of 11 Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Not available Other information SECTION 10: Stability and reactivity Reactivity Strong oxidizing agents. Reaction with strong acids Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Stable under normal conditions of storage and use. Heat, flames, sparks and other sources of ignition Incompatible materials See section reactivity Hazardous decomposition products None if used for intended purpose Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. STOT-single exposure: May cause drowsiness or dizziness. Oral toxicity: This material is considered to have low toxicity if swallowed. Inhalative toxicity: Inhalation of vapors in high concentration may cause irritation of respiratory system Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Causes serious eye irritation. Acute oral toxicity: Value Value Route of Species type application time LD mg/kg oral rat

8 LOCTITE 5972 known as Loctite 5972 Page 8 of 11 Acute inhalative toxicity: Value Value Route of Species type application time LC50 72,6 mg/l inhalation 4 h rat Acute dermal toxicity: Value Value Route of Species type application time LD mg/kg dermal rabbit Skin corrosion/irritation: Result time Species slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Result time Species moderately irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: not sensitising Result Test type Species Buehler test guinea pig Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without Species Repeated dose toxicity Result Route of application time / Frequency of treatment NOAEL=1500 inhalation 13 weeks 6 hours/day, 5 days/week LOAEL=5000 inhalation 13 weeks 6 hours/day, 5 days/week Species mouse mouse SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Do not empty into drains / surface water / ground water.

9 LOCTITE 5972 known as Loctite 5972 Page 9 of 11 Value type Value Acute Toxicity Study time Species LC mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae 96 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) NOEC mg/l Algae 96 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) NOEC 30 mg/l chronic Daphnia OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Result Route of application Degradability readily biodegradable aerobic % EU C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available for the product. LogKow Bioconcentration factor (BCF) time Species Temperature 0,05 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask ) Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods

10 LOCTITE 5972 known as Loctite 5972 Page 10 of 11 Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: Disposal must be made according to official regulations. Waste code other solvents and solvent mixtures waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number ADR 1866 RID 1866 ADNR 1866 IMDG 1866 IATA UN proper shipping name ADR RID ADNR IMDG IATA RESIN SOLUTION RESIN SOLUTION RESIN SOLUTION RESIN SOLUTION Resin solution Transport hazard class(es) ADR 3 RID 3 ADNR 3 IMDG 3 IATA Packaging group ADR RID ADNR IMDG IATA II II II II II Environmental hazards ADR RID ADNR IMDG IATA Special precautions for user ADR Special provision 640D

11 RID ADNR IMDG IATA LOCTITE 5972 known as Loctite 5972 Page 11 of 11 Tunnelcode: (D/E) Special provision 640D Special provision 640D Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 35 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness. H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.