: Zipper 200 Herbicide

Transcription

1 SECTION 1: Identification 1.1. Product identifier Trade name Material according to NOHSC and ADG requirements Date of issue: 02/03/2016 Revision date: : Version: 2.0 : 1.2. Recommended use of the chemical and restrictions on use Recommended use Industrial/Professional use spec Use of the substance/mixture Restrictions on use 1.3. Details of the importer Rotam AgroSolutions Australia Pty Ltd Unit 129,9 Hall Street, Port Melbourne, Vic 3207 Australia T msds@rotam.com 1.4. Emergency telephone number : For professional use only : Agriculture Herbicide Emergency number : SECTION 2: Hazards identification 2.1. Classification of the hazardous chemical Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Reproductive toxicity, Category 1B H360 Specific target organ toxicity Repeated exposure, Category 2 H373 CLP information only Full text of H-phrases: see section 2.2 Adverse physicochemical, human health and environmental effects 2.2. Label elements, including precautionary statements Hazard pictograms : GHS07 Exclamation Mark Signal word : Danger GHS08 Health Hazard Hazard statements : H315 - Causes skin irritation H319 - Causes serious eye irritation H360 - May damage fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure Precautionary statements : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe mist P264 - Wash hands thoroughly after handling P280 - Wear protective clothing, protective gloves P302+P352 - IF ON SKIN: Wash with plenty of water P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see the instruction on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P405 - Store locked up P501 - Dispose of contents/container according to local regulation 2.3. Other hazards Adverse physicochemical, human health and environmental effects : May cause drowsiness or dizziness. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May be fatal if swallowed and enters airways. 02/03/2016 EN (English) 1/5

2 Material according to NOHSC and ADG requirements SECTION 3: Composition and information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier Content glufosinate ammonium (ISO), ammonium 2-amino-4- (hydroxymethylphosphinyl)butyrate (CAS No) (EC no) (EC index no) X 15-20% (200g/L) propylene glycol monomethyl ether - mixture of isomers % ingredients determined not to be hazardous, including Not available >60% Water SECTION 4: First aid measures 4.1. Description of necessary first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON INFORMATION CENTER (Australia) on or doctor/physician. Specific treatment is urgent. : Remove affected clothing and wash all exposed skin area with plenty of mild soap and water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain emergency medical attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Symptoms caused by exposure Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Irritation. : Eye irritation Medical attention and special treatment SECTION 5: Firefighting measures 5.1. Suitable extinguishing equipment Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Specific hazards arising from the chemical 5.3. Special protective equipment and precautions for firefighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering drains or water bodies. : Do not enter fire area without proper protective equipment, including respiratory protection. Breathable air apparatus must be worn when fighting a fire in which this product is involved For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Equip cleanup crew with proper protection. See Section 8 Emergency procedures 6.2. Environmental precautions : Ventilate area. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and materials for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Section 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay, sand, soil, vermiculite or diatomaceous earth as soon as possible. Collect spillage in sealable open-top type containers for disposal. If large liquid spills occur, attempt to recover as much spilt material from sumps and bunded areas, as possible, before absorbing remaining material into vermiculite or other absorbent. 02/03/2016 EN (English) 2/5

3 Material according to NOHSC and ADG requirements SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe mist/spray. Use only outdoors or in a well-ventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place out of direct sunlight. Store in a locked enclosure. Keep container tightly closed. Do not store with seed, fertilisers or foodstuffs. : Strong bases. Strong acids. : Sources of ignition. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Engineering Controls : Handle in well ventilated areas, generally natural ventilation is adequate Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection Other information : Avoid all unnecessary exposure. When opening the container, preparing spray and using the prepared spray wear cotton overalls buttoned to the neck and wrist and a washable hat, elbowlength PVC gloves and goggles and appropriate respiratory protection. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. After each day's use, wash contaminated clothing and safety equipment. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear respiratory protection. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Blue to bluish-green Odour : slightly pungent odour Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point : Not Applicable Freezing point Boiling point Flash point : >61 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density : 1.11 at 20 C Solubility : Miscible Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information 02/03/2016 EN (English) 3/5

4 Material according to NOHSC and ADG requirements SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. Keep away from strong oxidising agents Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat 2170 mg/kg LD50 dermal rat 1380 mg/kg glufosinate ammonium (ISO), ammonium 2-amino-4-(hydroxymethylphosphinyl)butyrate ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) 1620 mg/kg for female rats, and 2000mg/l for male rats 4000 mg/kg for female rats, and >4000mg/l for male rats 1.26 mg/l/4h for female rats, and 2.60 for male rats(dust) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard : Causes skin irritation. : Causes serious eye irritation. : May damage fertility or the unborn child. : May cause damage to organs through prolonged or repeated exposure. SECTION 12: Ecological information Ecotoxicity Ecology - water : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. glufosinate ammonium (ISO), ammonium 2-amino-4-(hydroxymethylphosphinyl)butyrate ( ) LC50 fish mg/l EC50 Daphnia mg/l 560~1000 ErC50 (algae) 37 mg/l (Selenastrum capricornutum) Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Other information : Avoid release to the environment 02/03/2016 EN (English) 4/5

5 Material according to NOHSC and ADG requirements SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials Disposal of Containers : Dispose in a safe manner in accordance with local/national regulations. : Hazardous waste due to toxicity. Avoid release to the environment. : Do not use this container for any other purpose. Triple or preferably pressure rinse containers before disposal. Add rinsings to the spray tank. If recycling, replace cap and return clean containers to recycler or designated collection point. If not recycling, puncture or shred and bury containers in local authority landfill. If no landfill is available, bury the containers below 500mm in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots. Empty containers and product should not be burnt. Returnable containers: empty contents fully into application equipment. SECTION 14: Transport information Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Replace cap, close all valves and return to the point of supply for refill or storage. Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS SECTION 15: Regulatory information Poisons Schedule Packaging &Labelling Other Information : S5 : CAUTION KEEP OUT OF REACH OF CHILDREN READ SAFETY DIRECTIONS BEFORE OPENING OR USING : This product is registered with the Australian Pesticides and Veterinary Medicines Authority (APVMA). APVMA product number: SECTION 16: Other information Date of issue: 02/03/2016 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 02/03/2016 EN (English) 5/5