MATERIAL SAFETY DATA SHEET A Colorant Page 1
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1 A Colorant Page 1 Section 01 - Product and company identification Identification of the company: Contact EH&S Manager: CHEMTREC: Domestic North America: International call: Dryvit Systems, Inc. World Headquarters One Energy Way West Warwick, RI Telephone No.: ehs@dryvit.com (collect calls accepted) Trade name: Primary product use: Chemical family: A Colorant Colorant preparation Aqueous dispersion of C.I. Pigment White 6 containing polyglycol Section 02 - Hazards identification Expected Route of entry: Inhalation: Skin contact: Eye contact: Ingestion: Skin absorption: Health effects of exposure: yes yes C.I. Pigment White 006 ( ) May cause slight irritation to skin and irritation to the eyes. Inhalation of dust may cause mild upper respiratory irritation with cough and shortness of breath. Based on suppliers study where titanium dioxide was a potential carcigen to rats via inhalation, it was concluded that titanium dioxide pigment will t cause lung cancer or chronic respiratory disease in humans at concentrations experienced in the workplace. The proprietary ingredient in this product may cause mild to severe eye irritation, mild to moderate skin irritation and mild respiratory irritation. The proprietary ingredient in this product may cause severe eye irritation with the risk of serious eye damage. Kwn effects on other illnesses: Listed carcigen: None kwn. IARC: No NTP: No
2 A Colorant Page 2 HMIS: OSHA: No Other: No Health: 1 Flammability: 1 Reactivity: 0 Personal protection: B Section 03 - Composition/information on ingredients Hazardous ingredients: Component CAS-. (Trade secret Concentration.) C.I. Pigment White % NJTSR# % 7805-P PCP NJTSR# P PCP 2-3 % Section 04 - First aid measures After inhalation: Get victim to fresh air. Give artificial respiration or oxygen if breathing has stopped. Get prompt medical attention. Do t give fluids if victim is unconscious. After contact with skin: Wash thoroughly with soap and water for 15 minutes. If skin irritation occurs, seek medical attention. After contact with eyes: Flush immediately under running water for fifteen minutes. If redness or irritation occurs, seek medical attention. After ingestion: If victim is conscious, give large amounts of water or milk. Consult a physician. Never give anything by mouth to an unconscious person. Advice to doctor / Treatment: None kwn. Section 05 - Fire fighting measures Flashpoint: No flash point upto 100 C. Lower explosion limit: t available Upper explosion limit: t available Self ignition: Ignition temperature: t tested.
3 A Colorant Page 3 Hazardous combustion products: In case of fires, hazardous combustion gases are formed: Carbon moxide (CO) Carbon dioxide (CO2) Nitrogen oxides (NOx) Extinguishing media: Unusual fire and explosion hazards: water spray jet dry powder carbon dioxide alcohol-resistant foam water jet Emits toxic fumes under fire conditions. Section 06 - Accidental release measures Steps to be taken in case of spill or leak: Contain spill. Small spills may be flushed to the sewer or absorbed on suitable absorbants. Larger spills should be collected as liquid or absorbed. Clean-up may be accomplished by flushing with water if appropriate or remove contaminated soils. place in appropriate containers. Section 07 - Handling and storage Advice on safe handling: Wear proper protective equipment. Avoid breathing dust. Avoid contact with skin and eyes. Wash thoroughly after handling. Store in a dry place. Away from excessive heat, in original or similar waterproof containers. Keep containers tightly closed when t in use. Further info on storage conditions: Store in a cool, dry, well-ventilated area. Keep container sealed when t in use. Keep from freezing. Protect from extreme heat and cold Section 08 - Exposure controls / personal protection Occupational exposure limits: Component CAS Regulatory list Type of value Values / Remarks number: Titanium dioxide US OSHA Table Z- 8-hour Time 15 ppm; 15 mg/m3 1 Limits for Air Contaminents [29 CFR ] Weighted Averages Titanium dioxide US ACGIH Threshold Limit Values Threshold Limit Value_Time Weighted Average 10 mg/m3 Marble US OSHA Table Z- 1 Limits for Air Contaminents [29 8-hour Time Weighted Averages 15 ppm; 15 mg/m3
4 A Colorant Page 4 CFR ] Respiratory protection: Hand protection: Eye protection: Other protective equipment: Advice on system design: Use NIOSH/MSHA approved respirators following manufacturer's recommendations where dust or fume may be generated. Butyl Rubber, PVC Or Neoprene. Safety glasses or chemical splash goggles. Clothing suitable to prevent skin contact. Local ventilation recommended - mechanical ventilation may be used. Section 09 - Physical and chemical properties Form: Color: Odor: Odor limit: Liquid white t specified t available ph: Solubility in water: Soluble in... : Density: Melting point : miscible fat t tested g/cm3 t applicable Boiling point : > 212 F Vapor pressure: Bulk density: Relative vapor density: Partitioning coef. octal/water: Viscosity / (dynamic): Viscosity / (kinematic): t tested. t available 1,800 mpa.s (23 C) t tested. Section 10 - Stability and reactivity Thermal decomposition: Chemical stability: Hazardous Polymerization: t tested. Stable. Conditions to avoid: Strong oxidizing agents.
5 A Colorant Page 5 Conditions to avoid: t kwn Section 11 - Toxicological information Product information: Acute oral toxicity: Acute inhalation toxicity: Acute dermal toxicity: Skin irritation: Eye irritation: Sensitization: LD50 > 2,000 mg/kg The product has t been tested. The information is derived from the properties of the individual components. t reasonable t available n-irritant The product has t been tested. The information is derived from the properties of the individual components. n-irritant The product has t been tested. The information is derived from the properties of the individual components. t available Section 12 - Ecological information Product information: Biodegradation: Fish toxicity: Daphnia toxicity: Algae toxicity: Bacteria toxicity: Dissolved organic carbon (DOC): Chemical oxygen demand (COD): Biological oxygen demand (BOD): t tested. t available t available t available t available Remarks: Do t allow to enter soil, waterways or waste water The product has t been tested. The information is derived from the properties of the individual components. Section 13 - Disposal considerations
6 A Colorant Page 6 Waste disposal information: Small quantities may be treated in aerobic wastewater treatment systems. Larger quantities should be incinerated or may be landfilled in approved systems. RCRA hazardous waste: No -- Not as sold. Section 14 - Transport information DOT IATA IMDG t restricted t restricted t restricted Section 15 - Regulatory information TSCA Status: All components of this product are listed on the TSCA Inventory. SARA (section 311/312): Reactive hazard: Pressure hazard: Fire hazard: Immediate/acute: Delayed/chronic: yes SARA 313 information: This product does t contain any toxic chemical listed under Section 313 of the Emergency Planning and Community Right-To-Kw Act of Clean Water Act: Contains kwn priority pollutants at concentrations greater than 0.1%. FDA: This product is t registered with the FDA.
7 A Colorant Page 7 Section 16 - Other information Other precautions: None Kwn Label information: CAUTION! MAY CAUSE IRRITATION TO EYES AND SKIN Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Use ventilation and/or respiratory protection in order to keep exposure below TLV values. Keep container closed when t in use. In case of EYE CONTACT, flush with water for 15 minutes while holding eyelids open. If irritation develops, seek medical attention immediately. In case of SKIN CONTACT, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If IRRITATION develops get immediate medical help. If INHALED, remove individual to fresh air. If BREATHING is difficult, give oxygen and call a physician. INGESTION: do t induce vomiting. Seek medical assistance. Never give anything by mouth to an unconscious person. This information is supplied under the OSHA Hazard Communication Standard, 29 CFR , and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume responsibility for damage or injury from the use of the product described herein. Data provided here are typical and t intended for use as product specifications. (R) and TM indicate trademarks of Dryvit Systems, Inc., its business partners or suppliers.
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