MATERIAL SAFETY DATA SHEET EXOLIT OP 1230 Page 1

Transcription

1 EXOLIT OP 1230 Page 1 Section 01 - Product Information Identification of the company: Clariant Corporation 4000 Monroe Road Charlotte, NC, Telephone No.: Information of the substance/preparation: Product Safety Emergency tel. number: CHEMTREC Trade name: EXOLIT OP 1230 Material number: Primary product use: Chemical family: flameproofing agents Orgaphosphorus salt Section 02 - Composition information on hazardous ingredients Hazardous ingredients: Component Particulates Not Otherwise Regulated (PNOR) CAS-. (Trade secret.) Concentration 100 % Section 03 - Hazards identification Expected Route of entry: Inhalation: Skin contact: Eye contact: Ingestion: Health effects of exposure: Particulates Not Otherwise Regulated (PNOR) This product is considered as Particulates Not Otherwise Regulated (PNOR). May cause local irritation of e, se, throat, and lungs. Kwn effects on other illnesses: Listed carcigen: Preexisting skin, eye, and respiratory conditions may be aggravated. IARC: No NTP: No OSHA: No Other: No

2 EXOLIT OP 1230 Page 2 HMIS: Health: 1 Flammability: 0 Reactivity: 0 Personal protection: F Section 04 - First aid measures After inhalation: Remove from exposure to fresh air immediately. If t breathing give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. After contact with skin: Immediately remove contaminated clothing and wash affected area thoroughly with soap and water. Consult physician if irritation occurs or if irritation is extensive. After contact with e: Flush immediately under running water for fifteen minutes. If redness or irritation occurs, seek medical attention. After ingestion: Get immediate medical help. Advice to doctor / Treatment: Treat symptomatically. Section 05 - Fire fighting measures Flashpoint: Self ignition: > 752 F Method: 92/69/EEC, A.16 Ignition temperature: Hazardous combustion products: In case of fires, hazardous combustion gases are formed: Carbon moxide (CO) Carbon dioxide (CO2) Phosphorus oxides (eg Phosphorus pentoxide) Extinguishing media: extinguishing measures to suit surroundings Special fire fighting procedure: Wear self-contained breathing apparatus (SCBA) and full protective clothing. Section 06 - Accidental release measures Steps to be taken in case of spill or leak: Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent, and place in a suitable container. Section 07 - Handling and storage

3 EXOLIT OP 1230 Page 3 Advice on safe handling: Avoid breathing dust and contact with skin, e,and clothing. Use good housekeeping practices to keep formation of dusts to a minimum. Take precautionary measures against electrostatic loading - grounding of equipment may be required in some operations to prevent dust explosion hazard. Store in a clean, dry area. Further info on storage conditions: Store in original container. Keep tightly sealed. Section 08 - Exposure controls / personal protection Respiratory protection: Hand protection: Eye protection: Other protective equipment: If airborne concentrations pose a health hazard, become irritating, or exceed recommended limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements under 29CFR Butyl Rubber, PVC Or Neoprene. Safety glasses with side shields. Clothing suitable to prevent skin contact. Section 09 - Physical and chemical properties Form: Color: Odor: ph: Solubility in water: Density: Powder white t specified approx. 5 (20 C, 10 g/l) Suspension in water = 2 g/l 1.2 g/cm3 (23 C) Method: 92/69/EEC, A.3. Decomposition point : from 572 F Method: DTA Vapor pressure: Bulk density: Partitioning coef. octal/water: Viscosity / (dynamic): kg/m3 (20 C) Section 10 - Stability and reactivity

4 EXOLIT OP 1230 Page 4 Thermal decomposition: Conditions to avoid: > 300 C (Heating rate:5 K/min) Decomposes before melting. Temperatures exceeding thermal stability of the masterbatch. High concentration of powders. Electrostatic charges. Section 11 - Toxicological information Product information: Acute oral toxicity: Acute dermal toxicity: LD50 > 2,000 mg/kg (rat) Method: OECD 401 LD50 > 2,000 mg/kg (rat (female)) Method: OECD 402 Section 12 - Ecological information Product information: Biodegradation: Fish toxicity: Daphnia toxicity: Algae toxicity: Bacteria toxicity: t degradable Method: OECD 302B / ISO 9888 / EEC 88/302C Data refer to the organic component. LC50 > 100 mg/l (96 h, zebra fish) Method: OECD 203 EC50 > 100 mg/l (48 h, Daphnia magna) Method: OECD 202 NOEC > 180 mg/l (Scenedesmus subspicatus) Method: 92/69/EEC, C.3 EC50 = 1,968 mg/l (3 h, activated sludge) Method: OECD 209 Section 13 - Disposal considerations Waste disposal information: Dispose of spilled or waste product, contaminated soil and other contaminated materials in licensed landfill or treatment facility in accordance with all local, state, and federal regulations. RCRA hazardous waste: No -- Not as sold. Section 14 - Transport information

5 EXOLIT OP 1230 Page 5 DOT IATA IMDG t restricted t restricted t restricted Section 15 - Regulatory information TSCA Status: All components of this product are listed on the TSCA Inventory. SARA (section 311/312): Reactive hazard: Pressure hazard: Fire hazard: Immediate/acute: Delayed/chronic: SARA 313 information: This product does t contain any toxic chemical listed under Section 313 of the Emergency Planning and Community Right-To-Kw Act of Clean Water Act: Contains kwn priority pollutants at concentrations greater than 0.1%. FDA: This product is t registered with the FDA.

6 EXOLIT OP 1230 Page 6 Section 16 - Other information Other precautions: Avoid breathing dust and avoid contact with skin and e. Wear proper protective equipment. Keep container closed when t in use. Observe all necessary precautions for handling powders as fine powder. May present dust explosion hazard. Label information: CAUTION! "NUISANCE DUST" MAY CAUSE SKIN, EYE OR RESPIRATORY TRACT IRRITATION Avoid contact with skin and e. Avoid breathing dust or vapor. Keep container closed when t in use. Wash thoroughly after handling. Keep away from heat and flame. Use ventilation and/or respiratory protection in order to keep exposure at a minimum. If INHALED, remove individual to fresh air. If NOT BREATHING, give artificial respiration. If breathing is difficult, give oxygen. Call a Physician. SKIN CONTACT: Wash thoroughly with soap and water. Call a physician if IRRITATION persists. In case of contact with e, rinse thoroughly with water. Get medical attention if IRRITATION persists. In case of FIRE, use water spray, foam, dry chemical or CO2. MADE IN GERMANY. This information is supplied under the OSHA Hazard Communication Standard, 29 CFR , and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume responsibility for damage or injury from the use of the product described herein. Data provided here are typical and t intended for use as product specifications. (R) and TM indicate trademarks of Clariant AG, its business partners or suppliers.