67380 Plexigum PQ 611

Transcription

1 Revised edition: Version: 4.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Plexigum PQ 611 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Binding agent for aliphates soluble varnishes Uses advised against: Details of the Supplier of the (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Contains Isobutylmethacrylate, 2-Ethylhexyl methacrylate. Can cause allergic reactions. 2

2 Composition/Information on Ingredients Substance Mixture Page 2 Organic substances in powder form may have the potential to cause dust explosions. Chemical Characterization: Isobutyl methacrylate solution of an acrylic polymer. Acrylic copolymer: > 97 % Information on Components / Hazardous Ingredients: 2-Ethylhexyl methacrylate (Xi; 36/37/38; H ); REACH Isobutylmethacrylate (Xi, N; R10-36/37/ ; H ); REACH Dodecanethiol (C,N; R34-50/53; H ); M-Factor: % % % CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air and seek medical advice in case of complaints. Wash off with plenty of water. In case of skin irritation consult physician. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed If symptoms persist consult physician. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: 3

3 Treat symptomatically. 5. Fire-Fighting Measures Extinguishing Media Page 3 Suitable extinguishing media: Foam, carbon dioxide (CO2), extinguishing powder, water spray jet Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon oxides and organic decomposition products. Dust can form explosive mixtures with air. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. Respiratory protection in case of formation of vapors/dust/aerosol. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically. Dispopse of contaminated material as waste according to section 13. Protective clothing, see Section 8. Provide good ventilation and/or exhaust at the workplace. Ensure adequate ventilation. Handle and open container with care. Avoid formation of dust. Hygienic measures: Avoid contact with eyes and skin. 4

4 Page Conditions for Safe Storage, including any Incompatibilities Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in a cool and dry place. Store the product in the original container. Keep container tightly closed. Dust may form an explosive mixture with air. Take measures to prevent electrostatic discharge. Cool exposed containers with water. Storage class (VCI): Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TRGS 900 Name/Value: 10 mg/m3 (8h) general dust limit inhalable fraction. Name/Value: 3 mg/m3 (8h) general dust limit air-borne fraction. Peak limit Category: 2 (II) Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): No values available. No values available. Additional Information: Exposure Controls Technical protective measures: Adequate ventilation to control airborne concentrations below the exposure limits. Personal Protection General protective measures: The usual precautionary measures are to be adhered to when handling chemicals. Do not inhale dust/fumes/mist. Avoid contact with eyes and skin. Preventive skin protection by applying protective cream. 5

5 Respiratory protection: Dust mask (particle filter P1; EN 143). Page 5 Hand protection: Protective glove material: Eye protection: Body protection: Protective gloves (EN 388). Protective gloves should be changed regularly, especially after intensive contact with the product. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Safety glasses (EN 166) Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: granules clear weak, characteristic not available Melting temperature: ca. 40 C Boiling temperature: not determined Flash point: > 250 C Evaporation rate: Flammability (solid, gas): > 400 C Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: Vapor density: Density: 1.04 g/cm3 (20 C) 6

6 Solubility in water: insoluble Page Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials No decomposition if used according to specifications. Depolymerization begins at 250 C. The risk of dust explosion is generally possible with organic solids. no information available not determined Soluble in esters, ketones and chlorinated hydrocarbons. Not sensitive to impact. Stable if used according to specifications. No decomposition if used according to specifications. None if handled and stored according to specifications. Avoid formation of dust. Depolymerisation starts at 250 C. Oxidizing agents. 7

7 Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Page 7 Thermal decomposition may yield combustible vapors (mainly consisting of isobutyl methacrylate and 2-ethylhexyl methacrylate) which irritate the eyes and respiratory organs. Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: No information available No information available No sensitizing effects known. No mutagenic effects observed. No relevant data found. No negative effects. Repeated exposure: no information available. Single exposure: no information available. When used and handled according to specifications, the product does not have any harmful effects. The product is not subject to classification according to latest version of the General EU Classification Guidelines for Preparations. The fine dust particles contained by the product may irritate skin, eyes and mucous membrane. 8

8 12. Ecological Information Aquatic Toxicity No toxicity expected. Page Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number No data available. Not hazardous. Do not let product contaminate ground water, waterways or sewage system. No ecological problems expected. The waste is not hazardous. Dispose of according to official national and local regulations Wastes from the manufacture, formulation, supply and use (MFSU) of coatings (paints, varnishes and vitreous enamels), sealants and printing inks. Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. Packaging may be disposed of in the same manner as the product. ADR, IMDG, IATA 9

9 Page UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Not classified as a dangerous good under transport regulations Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous (German Regulation, Assessment by list) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality:

10 Chemical Safety Assessment Further Information Other Information Page 10 A Chemical Safety Assessment has not been carried out for this product. Listed in the following inventories: EINECS (EU), TSCA (USA), ECL (KR), IECSC (CN), ESC (TW) This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.