Version: 2. Identification of the Substance/Mixture and of the Company/Undertaking

Transcription

1 Revised edition: Version: 2 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Clove Oil Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Mon-Droguiste.Com Address: 39 Bis Rue Du Moulin Rouge Charmont Sous Barbuise Tel./Fax.: Tel +33 (0) Fax +33 (0) Internet: contact@mon-droguiste.com Emergency No. Emergency No.: ORFILA : SAMU : 15 - Pompiers : 18 - Médecins de garde : 15 Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H304 Cat.: 1 H317 Cat.: 1 H319 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 Irritating (Xi) R43 Harmful (Xn) R65 Aspiration hazard, category 1 Skin sensitization, hazard category 1 Eye irritation, category 2 May be fatal if swallowed and enters airways. May cause an allergic skin reaction. Causes serious eye irritation. May cause sensitization by skin contact. Harmful: May cause lung damage if swallowed. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: GHS07 2

2 Page 2 GHS08-2 Signal word: Hazard designation: Safety designation: H304 H317 H319 P261 P264 P272 P280 P301+P310 P302+P352 P305+P351+P338 P331 P333+P313 P337+P313 P363 P405 P501 Danger May be fatal if swallowed and enters airways. May cause an allergic skin reaction. Causes serious eye irritation. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ clothing/ eye/ face protection. If swallowed: Immediately call a poison center or physician. If on skin: Wash with soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. Do not induce vomiting. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Essential oil. CAS-Nr.: ; EINECS: Hazardous Ingredients: Eugenol (Xn; R22-43; H ) beta-caryophyllene (Xn; R65; H304) ca. 80 % ca. 2% CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: 3

3 Acetyleugenol (Xn; R22-38; H ) < 15 % Page 3 CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Intoxication symptoms may occur after several hours, therefore a 48 hour medical observation is necessary. Supply fresh air and keep patient calm. Get medical help. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immediately get medical help. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. CO2, extinguishing powder, sand or earth Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet Special hazards: Advice for Firefighters Protective equipment: Further information: No special hazards. Wear self-contained respiratory protective device. Cool exposed containers with water spray. 4

4 Page Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Provide adequate ventilation. Keep away from sources of ignition. Wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, diatomaceous earth, acid binder, universal absorbent, saw dust) and dispose accordingly. See Section 13 for information on disposal. Avoid contact with eyes. Avoid the formation of aerosol Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a cool and well ventilated location. Avoid pollution of soil. Keep away from sources of ignition - do not smoke. Do not store together with: foodstuffs and animal feed. Storage class (VCI): Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled None known Parameters to be controlled (DE): 5

5 Parameters to be controlled (EC): Page 5 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Avoid contact with eyes. In case of long-term or higher exposure. Protective gloves Protective glove material: Eye protection: Body protection: Safety glasses with protective shields (EN 166). Protective clothing Environmental precautions: Do not allow entering sewerage system. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: liquid yellowish characteristic not determined not available not available Flash point: 117 C Evaporation rate: 6

6 Flammability (solid, gas): not available Page 6 Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: not determined Vapor density: Density: g/cm3 Solubility in water: insoluble Coefficient of variation (n- Octanol/Water): not determined Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: not available Explosive properties: not available Oxidizing properties: no information available Bulk density: not determined Further Information Solubility in solvents: ethanol Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: No further information. 10. Stability and Reactivity Reactivity Stable if used according to specifications. 7

7 10.2. Chemical Stability Stable if used according to specifications Possibility of Hazardous Reactions Unknown Conditions to Avoid Page Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Avoid heat and sources of ignition. Strong oxidizing agents. None known g/kg (rat) 1.2 g/kg (rabbit) Slight irritant effect. Slight irritant effect No information available Slightly sensitizing. Teratogenicity: 8

8 Specific target organ toxicity (STOT): Page Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number LC50: 10.6 mg/l (48h, Leuciscus idus) EC50: 3.4 mg/l (24h, Daphnia magna) EC20: 3.5 mg/l (0,5h; Photobacterium phosphoreum) Harmful for fish and bacteria. Do not let product enter waterways or sewage system. Dispose of according to official national and local regulations. Dispose of according to official local regulations. ADR, IMDG, IATA 9

9 Page UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: not applicable Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: not applicable Hazard no.: Packaging Group ADR/RID: not applicable IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 2, hazardous for water Local regulations on chemical accidents: Employment restrictions: The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed. The employment restrictions for expectant and nursing mothers in 10

10 Restriction and prohibition of application: Page 10 accordance with the Maternity Protection Guideline (94/85/EEC) are to be observed Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties. This Safety Data Sheet replaces that of